Carboxylic esters based on limonene alcohol [3-(4′-methylcyclohexyl)butanol] and having a low melting point
View Patent ↗A carboxylic ester of the formula in which A is —(CH 2 ) x — where x=1–10, a process for its preparation which esters are useful lubricated and plasticizers for high molecular polymeric thermoplastics.
1. A carboxylic ester of the formula
in which A is —(CH 2 ) x — where x=1–10.
2. A carboxylic ester as claimed in claim 1 , wherein x is 1, 2, 3, 4, 7, 8 or 10.
3. A process for preparing a carboxylic ester as claimed in claim 1 , by reacting 3,4′-(methylcycloexyl)butanol with dicarboxylic acids of the formula
or their anhydrides of the formula
where A is as defined in claim 1 , in the presence of an azeotroping agent to remove the water formed in the course of the reaction as an azeotropic mixture, and optionally in the presence of a catalyst selected from the group consisting of sulfuric acid, phosphoric acid, polyphosphoric acid or its acidic salts, trialkyl or triaryl phosphates, formic acid, methanesulfonic acid and p-toluenesulfonic acid, removing excess and unreacted starting materials, treating the product with an alkaline reagent to remove acidic constituents, optionally subsequent steam distillation, and finally drying or fractional distillation.
4. In a high molecular weight polymeric thermoplastic, the improvement comprising containing an ester of claim 1 as a lubricant.
5. In a high molecular weight polymeric thermoplastic, the improvement comprising containing an ester of claim 1 as a plasticizer.