Polymer powder with phosphonate-based flame retardant, process for its production, and moldings produced from this polymer powder
View Patent ↗The present invention relates to a polymer powder composed of polyamide or of copolyamides, which also comprises flame retardant, in particular phosphonates, to a layer-by-layer process which selectively melts regions or selectively binds them, and also to moldings produced from this polymer powder. Compared with conventional products, the moldings constructed using the powder of the invention exhibit marked advantages in flammability and combustibility and drop behavior, particularly with respect to UL® (Underwriters Laboratories) classification. Furthermore, moldings produced from polymer powder of the invention have adequately good mechanical properties when compared with moldings based on polymer powders without flame retardant, in particular in terms of modulus of elasticity and tensile strain at break. In addition, these moldings also have a density close to that of injection moldings.
1. A polymer powder for processing in a layer-by-layer process which selectively melts regions or selectively binds them to one another, which comprises:
at least one polymer powder comprising a polyamide which has at least 8 carbon atoms per carbonamide group and
at least one flame retardant having a phosphonate-containing flame retardant;
wherein the phosphonate-containing flame retardant is present in an amount of from 5 to 30 wt. %, which is based on the entirety of the components present in the polymer powder, and
wherein the grains of said polymer powder comprising a polyamide is encapsulated by said flame retardant.
2. A polymer powder as claimed in claim 1 , wherein the at least one polymer powder comprises nylon-6,12, nylon-11, or nylon-12, or copolyamides based on the abovementioned polyamides.
3. A polymer powder as claimed in claim 1 , wherein the phosphonate-containing flame retardant is present in an amount of from 5 to 20 wt. %, which is based on the entirety of the components present in the polymer powder.
4. A polymer powder as claimed in claim 1 , wherein the phosphonate-containing flame retardant is present in an amount of from 8 to 15 wt. %, which is based on the entirety of the components present in the polymer powder.
5. A polymer powder as claimed in claim 1 , wherein the phosphonate-containing flame retardant comprises cyclic esters.
6. A polymer powder as claimed in claim 1 , which further comprises auxiliaries and/or filler.
7. A polymer powder as claimed in claim 6 , wherein at least one auxiliary is a flow aid.
8. A polymer powder as claimed in claim 6 , wherein the filler comprises glass particles.
9. A process for producing polymer powder as claimed in claim 1 , which comprises:
encapsulating the grains of said at least one polymer powder with a phosphonate-containing flame retardant.
10. A method, which comprises:
producing a molding by a layer-by-layer process which comprises selectively melting regions or selectively binding regions to one another; wherein the regions comprise the polymer powder as claimed in claim 1 .
11. A molding produced by a layer-by-layer process which comprises selectively melting regions or selectively binding regions to one another; wherein the regions comprises:
at least one polymer comprising a polyamide which has at least 8 carbon atoms per carbonamide group and
at least one flame retardant having a phosphonate-containing flame retardant;
wherein the phosphonate-containing flame retardant is present in an amount of from 5 to 20 wt. %, which is based on the entirety of the components present in the polymer powder, and
wherein the grains of said polymer powder comprising a polyamide is encapsulated by said flame retardant.
12. A molding as claimed in claim 11 , wherein the polymer is nylon-6,12, nylon-11, and/or nylon-12, or copolyamides based on the abovementioned polyamides.
13. A molding as claim in claim 11 , wherein the phosphonate-containing flame retardant is present in an amount of from 8 to 15 wt. %, which is based on the entirety of the components present in the polymer powder.
14. A molding as claimed in claim 13 , wherein the phosphonate-containing flame retardant is present in an amount of from 10 to 12 wt. %, which is based on the entirety of the components present in the polymer powder.
15. A molding as claimed in 11 , which further comprises fillers.
16. A molding as claimed in claim 15 , wherein at least one of the fillers comprises glass particles.