Translucent PCA ceramic, ceramic discharge vessel, and method of making
View Patent ↗A translucent polycrystalline material suitable for use in ceramic discharge vessels for metal halide lamps is produced by sintering an alumina powder doped with a MgO sintering aid in a nitrogen atmosphere containing a partial pressure of a vapor phase carbon-containing species. The sintered polycrystalline alumina has a grain boundary phase containing aluminum, oxygen and nitrogen. The formation of the AL—O—N grain boundary phase is believed to facilitate the transport of nitrogen from entrapped pores during sintering. Preferably, the PCA is sintered in a carbon-element furnace under flowing ultra-high-purity nitrogen.
1. A sintered translucent ceramic article comprised of polycrystalline alumina containing an amount of MgO and having a grain boundary phase containing aluminum, oxygen and nitrogen.
2. The ceramic article of claim 1 wherein the grain boundary phase is aluminum oxynitride.
3. The ceramic article of claim 1 wherein the amount of MgO in the polycrystalline alumina is from about 100 ppm to about 1000 ppm.
4. A ceramic discharge vessel comprising a ceramic body comprised of translucent polycrystalline alumina containing an amount of MgO and having a grain boundary phase containing aluminum, oxygen and nitrogen.
5. The ceramic discharge vessel of claim 4 wherein the grain boundary phase is aluminum oxynitride.
6. The ceramic discharge vessel claim 4 wherein the amount of MgO in the polycrystalline alumina is from about 100 ppm to about 1000 ppm.
7. The ceramic discharge vessel of claim 4 wherein the discharge vessel has a total transmittance of at least 95%.