Flexible semiaromatic polyamides with a low moisture uptake
View Patent ↗The present invention relates to a flexible semiaromatic polyamide composition with a low moisture uptake comprising, by weight, the total being 100: 60 to 99.5% (preferably 70 to 93%) of at least one copolyamide of formula X/Y,Ar in which: Y denotes the residues of an aliphatic diamine having from 8 to 20 carbon atoms, Ar denotes the residues of an aromatic dicarboxylic acid, X denotes either the residues of aminoundecanoic acid NH 2 —(CH 2 ) 10 —COOH, of lactam-12 or of the corresponding amino acid, or X denotes the unit Y,x, residue from the condensation of the diamine with an aliphatic diacid (x) having between 8 and 20 carbon atoms, or X denotes the unit Y,I, residue from the condensation of the diamine with isophthalic acid, −0.5 to 40% (preferably 7 to 30%) of at least one product chosen from plasticizers, nanofillers, polyolefins, crosslinked polyolefins and additives.
1. Composition comprising, by weight, the total being 100:
-60 to 99.5% of at least one copolyamide of formula X/Y,Ar in which there is between 0.5 and 0.7 mol of ×per 1 mol of Y, and in which:
Y denotes the residues of 1,10-decanediamine,
Ar denotes the residues of terephthalic acid,
X denotes
a) the residue of aminoundecanoic acid NH 2 —(CH 2 ) 10 —COOH,
b) the unit Y,I, residue from the condensation of the diamine (Y) with isophthalic acid,
wherein said composition is a flexible semiaromatic copolyamide; and
−0.5 to 40% of at least one product chosen from plasticizers,
wherein said composition has a low water uptake of 3% or less.
2. Composition according to claim 1 , in which the proportion of the copolyamide is from 70 to 93% for 7 to 30% of at least one product chosen from plasticizers.
3. Composition according to claim 1 , in which the intrinsic viscosity of the copolyamide is between 0.5 and 2.
4. Composition according to claim 3 , in which the intrinsic viscosity of the copolyamide is between 0.8 and 1.8.
5. Composition according to claim 1 , in which Y and Ar are in about stoichiometric proportions.
6. Composition according to claim 1 in which X/Y,Ar denotes 11/10,T, which results from the condensation of aminoundecanoic acid, 1,10-decanediamine and terephthalic acid.
7. Structure comprising a layer composed of the composition according to claim 1 .
8. Formulation comprising fillers and binder wherein said binder comprises the composition according to claim 1 .