Post-reformer treatment of reformate gas
View Patent ↗A method of modifying reformate gas composition downstream of the reformer so that it remains in a carbon-free region, i.e. above the critical oxygen/carbon ratio even at the desired minimum operating temperature. This is accomplished by using staged partial oxidation in a partial oxidation chamber downstream of the reformer. A small amount of air (or oxygen) is added. The net result is an increase in the oxygen/carbon ratio and, thus, a lowering of the required temperature for soot-free operation. Immediately downstream of this partial oxidation chamber, heat can be removed to cool the gas prior to a second stage of partial oxidation. A second stage partial oxidation chamber produces additional water and further increases the oxygen/carbon ratio and further lowers the required gas temperature for soot-free operation. Further stages of partial oxidation followed by cooling of the gas can be repeated until the oxygen/carbon ratio is sufficiently high to allow soot-free operation at the lowest required operating temperature.
1. A method of treating reformate gas from a reformer to prevent soot formation, comprising the steps:
a. establishing a relationship characterizing soot formation in a treated reformate gas as a function of a temperature and an oxygen/carbon ratio of the treated reformate gas, the relationship defining a minimum temperature as a function of the oxygen/carbon ratio at which no soot will form in the treated reformate gas;
b. directing the reformate gas into a partial oxidation chamber;
c. directing a predetermined amount of air into the partial oxidation chamber;
d. cooling the treated reformate gas to, but not lower than, a temperature at or above the minimum temperature at the oxygen/carbon ratio of the treated reformate gas.
2. The method of claim 1 , further comprising repeating steps b, c and d for the treated reformate gas.
3. The method of claim 1 , further comprising purging the anode of a fuel cell with the treated reformate gas during startup of the fuel cell.
4. The method of claim 1 , further comprising receiving the reformate gas from the reformer prior to performing said directing the reformate gas into said first stage partial oxidation chamber.
5. A method of treating reformate gas from a reformer to prevent soot formation, comprising the steps:
a. defining for a treated reformate gas a minimum temperature as a function of an oxygen/carbon ratio at which no soot will form in the treated reformate gas;
b. receiving the reformate gas from the reformer;
c. directing the reformate gas into a first stage partial oxidation chamber;
d. directing a predetermined amount of air into the first stage partial oxidation chamber;
e. cooling the treated reformate gas from the first stage partial oxidation chamber to, but not lower than, a temperature at or above a minimum temperature at the oxygen/carbon ratio of the treated reformate gas as output from the first stage partial oxidation chamber;
f. directing the cooled reformate gas from the first stage partial oxidation chamber into a second stage partial oxidation chamber;
g. directing a predetermined amount of air into the second stage partial oxidation chamber; and
h. cooling the treated reformate gas from the second stage partial oxidation chamber to, but not lower than, a temperature at or above the minimum temperature at the oxygen/carbon ratio of the treated reformate gas as output from the second stage partial oxidation chamber.
6. The method of claim 5 , further comprising repeating steps f, g and h using a third stage partial oxidation chamber.
7. The method of claim 5 , further comprising purging the anode of a fuel cell with the treated reformate gas during startup of the fuel cell.
8. A method of treating reformate gas from a catalytic partial oxidation reformer to raise the oxygen/carbon ratio in the reformate gas in order to prevent soot formation, comprising the steps:
a. defining for a treated reformate gas a minimum temperature at which no soot will form in the treated reformate gas;
b. receiving the reformate gas from the reformer;
c. directing the reformate gas into a first stage partial oxidation chamber;
d. directing a predetermined amount of air into the first stage partial oxidation chamber;
e. cooling the treated reformate gas from the first stage partial oxidation chamber to, but not lower than, a temperature at or above the minimum temperature;
f. directing the cooled reformate gas from the first stage partial oxidation chamber into a second stage partial oxidation chamber;
g. directing a predetermined amount of air into the second stage partial oxidation chamber;
h. cooling the treated gas from the second stage partial oxidation chamber to, but not lower than, the temperature at or above the minimum temperature; and
i. repeating steps f, g and h using at least a third stage partial oxidation chamber as necessary to achieve a desired oxygen/carbon ratio.
9. The method of claim 8 , further comprising purging the anode of a fuel cell with the treated reformate gas during startup of the fuel cell.
10. A method of treating reformate gas from a reformer for use in purging an anode of a fuel cell, comprising:
a. using the reformer to reform a fuel into a reformate gas having a first oxygen/carbon ratio;
b. receiving the reformate gas from the reformer;
c. treating the reformate gas by partially oxidizing the reformate gas to lower a minimum temperature at which no soot will form in the treated reformate gas and to yield a second oxygen/carbon ratio in the treated reformate gas that is greater than the first oxygen/carbon ratio;
d. cooling the treated reformate gas to, but not lower than, a temperature that is at or above the minimum temperature at the second oxygen/carbon ratio at which no soot will form in the treated reformate gas; and
e. purging the anode using the treated reformate gas.
11. The method of claim 10 , further comprising repeating steps c and d to successively lower the minimum temperature at which no soot will form in the treated reformate gas and to yield a final oxygen/carbon ratio that is greater than the second oxygen/carbon ratio, the repeating of steps c and d being performed until the minimum temperature at which no soot will form in the treated reformate gas is below a predetermined temperature at which purging of the anode using the treated reformate gas is to be performed.
12. The method of claim 11 , wherein the predetermined temperature at which purging of the anode is to be performed is approximately 400 degrees Celsius.
13. The method of claim 11 , wherein steps c and d are repeated until the final oxygen/carbon ratio is approximately 1.2.
14. The method of claim 11 , further comprising employing a catalytic partial oxidation reformer as the reformer.