Peroxide curable butyl formulations
View Patent ↗The present invention relates to a peroxide curable rubber compound containing at least one elastomeric polymer comprising repeating units derived from at least one C 4 to C 7 isomonoolefin monomer, at least one C 4 to C 14 multiolefin monomer, at least one p- or m-alkylstyrene monomer and at least one co-agent.
1. A compound comprising:
a. at least one elastomeric polymer comprising repeating units derived from at least one C 4 to C 7 isomonoolefin monomer, at least one C 4 to C 14 multiolefin and at least one p- or m-alkylstyrene monomer in an amount of from 10% to 20% by weight of the total of all monomers;
b. at least one co-agent selected from dienephiles and allylic type co-agents; and
c. a peroxide curing system.
2. The compound according to claim 1 , wherein the C 4 to C 7 isomonoolefin monomer(s) are selected from the group consisting of isobutylene, 2-methyl-1-butene, 3-methyl-1-butene, 2-methyl-2-butene, 4-methyl-1-pentene and mixtures thereof.
3. The compound according to claim 1 , wherein the C 4 to C 14 multiolefin monomer(s) are selected from the group consisting of isoprene, butadiene, 2-methylbutadiene, 2,4-dimethylbutadiene, piperyline, 3-methyl-1,3-pentadiene, 2,4-hexadiene, 2-neopentylbutadiene, 2-methyl-1,5-hexadiene, 2,5-dimethyl-2,4-hexadiene, 2-methyl-1,4-pentadiene, 2-methyl-1,6-heptadiene, cyclopentadiene, methylcyclopentadiene, cyclohexadiene, 1-vinyl-cyclohexadiene and mixtures thereof.
4. The compound according to claim 1 , wherein the alkylstyrene monomer(s) are selected from the group consisting of p- or m-methylstyrene, p- or m-ethylstyrene and 4- or 3-n-propylstyrene.
5. The compound according to claim 1 , wherein the co-agent(s) are selected from the group consisting of m-phenylene-bis-maleimide, 1,3-bis(citraconimidomethyl)benzene, triallyl cyanurate and triallyl isocyanurate and mixtures thereof.
6. The compound according to claim 1 , wherein the peroxide system is an organic peroxide.
7. The compound according to claim 1 , further comprising at least one filler.
8. A shaped article comprising a compound according to claim 1 .
9. The article according to claim 8 in the form of a medical device or a condenser cap.
10. A medical device comprising an article comprising a compound according to claim 1 .
11. A fuel cell comprising an article according to claim 8 .