Method of removing spectator ions from aqueous suspension of solid particles
View Patent ↗The present invention provides a method of removing spectator ions and contaminants from aqueous suspensions of solid particles. In accordance with the method of the invention, the solid particles are transported across a phase boundary into a non-polar organic solvent, leaving the spectator ions and contaminants in the aqueous phase. To facilitate the efficient transportation of the solid particles across the phase boundary, the surface of the solid particles is coated with an amphiphilic polyelectrolyte. If desired, the solid particles can be recovered from the organic phase by evaporating the organic solvent.
1. A method for removing spectator ions from an aqueous barium titanyl oxalate suspension comprising:
contacting an aqueous suspension comprising barium titanyl oxalate particles and spectator ions with a water immiscible non-polar organic solvent and an amphiphilic polyelectrolyte under conditions suitable to form an unstable emulsion;
allowing the unstable emulsion to phase separate into an aqueous phase and an organic phase, wherein the organic phase comprises amphiphilic polyelectrolyte coated barium titanyl oxalate particles and less than about 500 ppm of the spectator ions by weight of the barium titanyl oxalate particles; and
separating the aqueous phase from the organic phase.
2. The method according to claim 1 wherein the amphiphilic polyelectrolyte is an organoamine compound selected from the group consisting of octylamine and N,N-dimethyloctylamine.
3. The method according to claim 1 wherein the organic solvent is selected from the group consisting of toluene and octane.
4. The method according to claim 1 wherein the amount of amphiphilic polyelectrolyte is greater than 0.1% and less than 80% by weight of the barium titanyl oxalate particles.
5. The method according to claim 1 further comprising evaporating the organic solvent from the separated organic phase to obtain amphiphilic polyelectrolyte-coated barium titanyl oxalate particles.
6. The method according to claim 1 wherein the aqueous suspension comprising barium titanyl oxalate particles and spectator ions is formed by injecting a first stream comprising an aqueous mixture of barium chloride and titanium chloride into a rapid mixing chamber of a rapid mixing reactor into contact with a second stream comprising an aqueous solution of oxalic acid.
7. The method according to claim 1 wherein the barium titanyl oxalate particles have a geometric mean diameter within the range of from about 1 to about 25 nm.
8. The method according to claim 1 wherein the spectator ions comprise chlorine ions.
9. A method for removing spectator ions from an aqueous suspension of solid particles comprising:
contacting an aqueous suspension comprising solid particles and dissolved spectator ions with a water immiscible non-polar organic solvent and an amphiphilic polyelectrolyte under conditions suitable to form an unstable emulsion;
allowing the unstable emulsion to phase separate into an aqueous phase and an organic phase, wherein the organic phase comprises amphiphilic polyelectrolyte coated solid particles and less than about 500 ppm of the dissolved spectator ions by weight of the solid particles; and
separating the aqueous phase from the organic phase.
10. The method according to claim 9 wherein the solid particles comprise aluminum hydroxide.
11. The method according to claim 1 , wherein the amphiphilic polyelectrolyte comprises octylamine, wherein the amount of amphiphilic polyelectrolyte is about 16% to about 36% by weight of the barium titanyl oxalate particles, and wherein the organic solvent comprises toluene.