IP Library Granted Patent US 7,194,315
Granted Patent B1
US 7,194,315 · App. 10/918,858 · Granted Mar 20, 2007

Coated electrode and method of making a coated electrode

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Quick Facts
Patent No.
US 7,194,315
App. No.
10/918,858
Granted
Mar 20, 2007
Kind
B1
Abstract

An electrode having a substrate with a first layer covering at least a portion of the substrate, and a second layer covering at least a portion of the first layer is disclosed. The first layer includes a porous layer consisting of a carbide, nitride or carbonitride of at least one of the metals titanium, vanadium, zirconium, niobium, molybdenum, hafnium, tantalum or tungsten. The second layer includes iridium. In a method according to the present invention, a substrate is provided. A first layer is provided over at least a portion of the substrate, and a second layer is provided over at least a portion of the first layer. The first layer includes a layer consisting of a carbide, nitride or carbonitride of at least one of the metals titanium, vanadium, zirconium, niobium, molybdenum, hafnium, tantalum or tungsten. The second layer includes iridium.

Claims (43)

1. An electrode, comprising:

a) a substrate;

b) a first layer having a porous morphology adapted for transmission of an electrical pulse to tissue and covering at least a portion of the substrate, wherein the first layer includes a material selected from the group consisting of a carbide, nitride, and carbonitride of the group consisting of titanium, vanadium, zirconium, niobium, molybdenum, hafnium, tantalum, tungsten, and mixtures thereof; and

c) a second layer comprising iridium covering at least a portion of the first layer to thereby provide long term electrical stability to the material of the first layer.

2. The electrode of claim 1 wherein the second layer includes iridium oxide.

3. The electrode of claim 1 wherein the second layer is an outer surface of the electrode.

4. The electrode of claim 1 wherein the second layer covering the first layer are disposed at a first end of the substrate with an electrical conductor being electrically connected to a second end of the electrode.

5. The electrode of claim 1 wherein the substrate includes platinum.

6. The electrode of claim 1 wherein the substrate includes iridium.

7. The electrode of claim 1 wherein the first layer contacts the substrate.

8. The electrode of claim 1 wherein the second layer contacts the first layer.

9. A cardiac pacing lead assembly, comprising:

a) an electrode comprising a substrate having a first end and a second end, and comprising a first layer of a material having a porous morphology adapted for transmission of an electrical pulse to fibrotic tissue and covering at least a portion of the first end of the substrate, and a second layer comprising iridium covering at least a portion of the first layer to thereby provide long term electrical stability to the first layer, wherein the material of the first layer is selected from the group consisting of a carbide, nitride, and carbonitride of the group consisting of titanium, vanadium, zirconium, niobium, molybdenum, hafnium, tantalum, tungsten, and mixtures thereof; and

b) an electrical conductor electrically connected to the second end.

10. The lead assembly of claim 9 wherein the second layer includes iridium oxide.

11. The lead assembly of claim 9 wherein the second layer is an outer surface of the electrode.

12. The lead assembly of claim 9 further comprising an electrical conductor electrically connected to the second end of the electrode.

13. The lead assembly of claim 9 wherein the substrate includes platinum.

14. The lead assembly of claim 9 wherein the substrate includes iridium.

15. The lead assembly of claim 9 wherein the first layer contacts the substrate.

16. The lead assembly of claim 9 wherein the second layer contacts the first layer.

17. A cardiac pacemaker, comprising:

a) an electrical pulse generator; and

b) an electrode electrically connected to the pulse generator, the electrode comprising a substrate having a first end and a second end, and comprising a first layer of a material having a porous morphology adapted for transmission of an electrical pulse to tissue and covering at least a portion of the first end, and a second layer comprising iridium covering at least a portion of the first layer to thereby provide long term electrical stability to the first layer, wherein the material of the first layer-is selected from the group consisting of a carbide, nitride, and carbonitride of the group consisting of titanium, vanadium, zirconium, niobium, molybdenum, hafnium, tantalum, tungsten, and mixtures thereto.

18. The cardiac pacemaker of claim 17 wherein the second layer includes iridium oxide.

19. The cardiac pacemaker of claim 17 wherein the second layer is an outer surface of the electrode.

20. The cardiac pacemaker of claim 17 further comprising an electrical conductor electrically connected to the second end of the electrode and the pulse generator.

21. The cardiac pacemaker of claim 17 wherein the substrate includes platinum.

22. The cardiac pacemaker of claim 17 wherein the substrate includes iridium.

23. The cardiac pacemaker of claim 17 wherein the first layer contacts the substrate.

24. The cardiac pacemaker of claim 17 wherein the second layer contacts the first layer.

25. An electrode, comprising:

a) a substrate comprising 90% platinum/10% iridium;

b) a first layer comprising titanium nitride having a porous morphology adapted for transmission of an electrical pulse to tissue and covering at least a portion of the substrate; and

c) a second layer comprising iridium oxide covering at least a portion of the first layer to thereby provide long term electrical stability to the titanium nitride.

26. An electrode, comprising:

a) a substrate comprising a conductive material selected from the group consisting of platinum, iridium, tantalum, and mixtures thereof;

b) a first layer comprising titanium nitride having a porous morphology adapted for transmission of an electrical pulse to tissue and covering at least a portion of the substrate; and

c) a second layer comprising iridium oxide covering at least a portion of the first layer to thereby provide long term electrical stability to the titanium nitride.

27. An electrode, comprising:

a) a substrate comprising a conductive material selected from the group consisting of platinum, iridium, tantalum, and mixtures thereof;

b) a first layer having a porous morphology adapted for transmission of an electrical pulse to tissue and covering at least a portion of the substrate, wherein the first layer includes a material selected from the group consisting of titanium carbide, titanium nitride, zirconium carbide, tantalum nitride, and mixtures thereof; and

c) a second layer comprising iridium oxide covering at least a portion of the first layer to thereby provide long term electrical stability to the material of the first layer.

Assignments (10)
RELEASE OF SECURITY INTEREST Recorded Oct 12, 2022
From: MANUFACTURERS AND TRADERS TRUST COMPANY (AS ADMINISTRATIVE AGENT)
To: GREATBATCH, INC.; GREATBATCH LTD.; ELECTROCHEM SOLUTIONS, INC.; NEURONEXUS TECHNOLOGIES, INC.; GREATBATCH-GLOBE TOOL, INC.; PRECIMED INC.; MICRO POWER ELECTRONICS, INC.
Reel/Frame 061659/0858 →
RELEASE OF SECURITY INTEREST Recorded Jan 6, 2022
From: MANUFACTURERS AND TRADERS TRUST COMPANY (AS ADMINISTRATIVE AGENT)
To: GREATBATCH, INC.; GREATBATCH LTD.; ELECTROCHEM SOLUTIONS, INC.; NEURONEXUS TECHNOLOGIES, INC.; GREATBATCH-GLOBE TOOL, INC.; PRECIMED INC.; MICRO POWER ELECTRONICS, INC.
Reel/Frame 060938/0069 →
RELEASE OF SECURITY INTEREST Recorded Jan 6, 2022
From: MANUFACTURERS AND TRADERS TRUST COMPANY (AS ADMINISTRATIVE AGENT)
To: GREATBATCH LTD.
Reel/Frame 058574/0437 →
RELEASE OF SECURITY INTEREST Recorded Nov 22, 2021
From: MANUFACTURERS AND TRADERS TRUST COMPANY
To: GREATBATCH LTD.
Reel/Frame 058224/0204 →
SECURITY INTEREST Recorded Sep 10, 2021
From: GREATBATCH LTD.; ELECTROCHEM SOLUTIONS, INC.; LAKE REGION MEDICAL, INC.; LAKE REGION MANUFACTURING, INC.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 057468/0056 →
SECURITY INTEREST Recorded Oct 27, 2015
From: GREATBATCH, INC.; GREATBATCH LTD.; ELECTROCHEM SOLUTIONS, INC.; NEURONEXUS TECHNOLOGIES, INC.; GREATBATCH-GLOBE TOOL, INC.; PRECIMED INC.; MICRO POWER ELECTRONICS, INC.
To: MANUFACTURERS AND TRADERS TRUST COMPANY
Reel/Frame 036980/0482 →
SECURITY AGREEMENT Recorded Jul 1, 2011
From: GREATBATCH LTD.
To: MANUFACTURERS AND TRADERS TRUST COMPANY, AS ADMINISTRATIVE AGENT
Reel/Frame 026539/0217 →
SECURITY INTEREST Recorded Nov 22, 2007
From: GREATBATCH LTD.
To: MANUFACTURERS AND TRADERS TRUST COMPANY
Reel/Frame 020571/0205 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 27, 2007
From: WILSON GREATBATCH TECHNOLOGIES, INC.
To: GREATBATCH, LTD. (NEW YORK CORPORATION)
Reel/Frame 019668/0811 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 16, 2004
From: PLATT, BRUCE; GELB, ALLAN S.
To: WILSON GREATBATCH TECHNOLOGIES, INC.
Reel/Frame 015705/0464 →