Polymer alloy including polylactic acid
View Patent ↗The object of the present invention is to provide a polymer alloy including polylactic acid which can be used in the same manner as conventional commodity plastics even in an environment of high temperature and high humidity. According to the present invention, there is provided a polymer alloy including polylactic acid comprising (A) a polylactic acid, (B) a polyalkylacrylic ester and/or a polyvinyl ester, (C) a polyolefin and (D) a block copolymer of a polyalkylacrylic ester and polyolefin and/or a block copolymer of a polyvinyl ester and a polyolefin.
1. A polymer alloy including polylactic acid comprising (A) a polylactic acid, (B) a polyalkylacrylic ester and/or a polyvinyl ester, (C) polyolefin and (D) a block copolymer containing blocks of an alkylacrylic ester and an olefin and/or a block copolymer containing blocks of a vinyl ester and an olefin.
2. A polymer alloy including polylactic acid according to claim 1 , wherein the polylactic acid is represented by the following formula (1), the polyalkylacrylic ester is represented by the following formula (2), the polyvinyl ester is represented by the following formula (3), and the polyolefin is represented by the following formula (4), wherein each n is a natural number, R and R 1 are each a hydrogen or alkyl group and R 2 is an alkyl group
3. A polymer alloy including polylactic acid according to claim 1 , wherein the block copolymer containing blocks of the alkylacrylic ester and the olefin is represented by the following formula (5) or (6), and the block copolymer containing blocks of the vinyl ester and the olefin is represented by one of the following formulas (7)–(10), wherein for(5) and (6) R 1 and R 3 are each hydrogen or alkyl and R 2 is alkyl and for (7)–(10) R 1 , R 2 , R 3 are each hydrogen or alkyl, and m, n, and k are each a natural number:
4. A polymer alloy including polylactic acid according to claim 3 , wherein n in the formula (1) is 10 2 –10 4 , n in the formula (2) is 10 1 –10 5 , n in the formula (3) is 10 1 –10 5 , and n in the formula (4) is 10 1 –10 6 .
5. A polymer alloy including polylactic acid according to claim 3 , wherein m is 10 1 –10 5 and n is 10 0 –10 6 in the formulas (5)–(7), and k is 10 0 –10 6 , m is 10 1 –10 5 and n is 10 0 –10 6 in the formulas (8)–(10).
6. A polymer alloy including polylactic acid according to claim 1 , wherein the polyvinyl ester is polyvinyl acetate.
7. A polymer alloy including polylactic acid according to claim 1 , wherein the polyolefin is polypropylene or polystyrene.
8. A polymer alloy including polylactic acid according to claim 1 , wherein the block copolymer containing blocks of a vinyl ester and an olefin is a block copolymer containing blocks of vinyl acetate and propylene, and these blocks are present at both terminals of the block copolymer.
9. A polymer alloy including polylactic acid according to claim 1 , wherein the block copolymer containing blocks of an alkylacrylic ester and an olefin is a copolymer of methyl methacrylate and styrene and the polyalkylacrylic ester block and the polyolefin block are present at both terminals of the copolymer.
10. A polymer alloy including polylactic acid according to claim 8 , wherein the block copolymer containing blocks of a vinyl ester and an olefin is a block copolymer containing blocks of vinyl acetate and styrene.
11. A polymer alloy including polylactic acid according to claim 9 , wherein the block copolymer containing blocks of an alkylacrylic ester and an olefin is a block copolymer containing blocks of methyl methacrylate and propylene, and these blocks are present at both terminals of the block copolymer.
12. A polymer alloy including polylactic acid according to claim 8 , wherein the block copolymer has propylene block and polyvinyl acetate block at both terminals and contains at least one block of ethylene, styrene, isoprene and butadiene between the above terminal blocks.