Radiation image storage panel
View Patent ↗A radiation image storage panel has a phosphor layer formed by a gas phase-accumulation method, in which the phosphor layer is composed of a lower sub-layer of a spherical crystal structure and an upper sub-layer of a columnar crystal structure.
1. A radiation image storage panel having a phosphor layer formed by a gas phase-accumulation method, wherein the phosphor layer comprises a lower sub-layer of a spherical crystal structure, the lower sub-layer comprising two or more spherical crystalline particles fused to form a string of beads extending vertically to the phosphor layer; and an upper sub-layer of a columnar crystal structure.
2. The radiation image storage panel of claim 1 , wherein a ratio in thickness of the lower sub-layer per the upper sub-layer is in the range of 0.01 to 0.5.
3. The radiation image storage panel of claim 1 , wherein the spherical crystalline particles have a mean size in the range of 1 to 10 μm.
4. The radiation image storage panel of claim 1 , wherein a support is provided to the phosphor layer on the side of the lower sub-layer and the lower sub-layer has a thickness in the range of 10 to 100 μm.
5. The radiation image storage panel of claim 1 , wherein the phosphor is an energy-storable phosphor.
6. The radiation image storage panel of claim 5 , wherein the energy-storable phosphor is a stimulable alkali metal halide phosphor represented by the formula (I):
M I X·aM II X′ 2 ·bM III X″ 3 :zA (I)
in which M I is at least one alkali metal selected from the group consisting of Li, Na, K, Rb and Cs; M II is at least one alkaline earth metal or divalent metal selected from the group consisting of Be, Mg, Ca, Sr, Ba, Ni, Cu, Zn and Cd; M III is at least one rare earth element or trivalent metal selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Al, Ga and ln; each of X, X′ and X″ is independently at least one halogen selected from the group consisting of F, Cl, Br and I; A is at least one rare earth element or metal selected from the group consisting of Y, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Mg, Cu and Bi; and a, b and z are numbers satisfying the conditions of 0≦a<0.5, 0≦b<0.5 and 0<z<1.0, respectively.
7. The radiation image storage panel of claim 6 , wherein M I is Cs, X is Br, A is Eu, and z is a number satisfying the condition of 1×10 −4 ≦z≦0.1.