Low temperature Li/FeS
View Patent ↗The invention is a 1.5 volt primary electrochemical battery cell with an alkali metal lithium negative electrode (such as lithium), a positive electrode (comprising iron disulfide for example) and a nonaqueous electrolyte. The electrolyte has a solute including lithium iodide dissolved in an ether-containing solvent including a 1,2-dimethoxypropane based solvent component and no more than 30 volume percent 1,2-dimethoxyethane. When 1,2-dimethoxypropane is used to replace at least most 1,2-dimethoxyethane in the solvent, the cell provides good discharge capacity at low temperature while maintaining excellent discharge capacity at room temperature.
1. A primary electrochemical battery cell, wherein the cell is a primary cell comprising a housing, a negative electrode comprising metallic lithium, a positive electrode, a separator disposed between the negative and positive electrodes, and an electrolyte, and wherein:
the positive electrode comprises FeS 2 and, optionally, one or more members selected from the group consisting of FeS, Bi 2 O 3 , CuO, Cu 2 O, CuS and CuS 2 ;
the electrolyte consists essentially of at least one solute and an organic solvent;
wherein the solute comprises lithium iodide;
wherein the organic solvent consists essentially of: (i) a 1,2-dimethoxypropane based solvent, (ii) 1,2-dimethoxyethane, (iii) an optional ether based cosolvent, and (iv) an optional non-ether based cosolvent that, when present, is less than 10 vol. % of the organic solvent and contains no dialkyl carbonates or cyclic carbonates; and
wherein the volume ratio of the 1,2-dimethoxypropane based solvent to the 1,2-dimethoxyethane is at least 2 to 1.
2. The cell defined in claim 1 , wherein the volume ratio of the 1,2-dimethoxypropane based component to the 1,2-dimethoxyethane is at least 5 to 1.
3. The cell defined in claim 1 , wherein the 1,2-dimethoxypropane based component is 1,2-dimethoxypropane.
4. The cell defined in claim 1 , wherein, when present, the optional ether based solvent is a 1,3-dioxolane based component.
5. The cell defined in claim 4 , wherein the 1,3-dioxolane based component is no greater than 75 percent of the total volume of the solvent.
6. The cell defined in claim 4 , wherein the 1,3-dioxolane based component is at least 20 percent of the total volume of the solvent.
7. The cell defined in claim 4 , wherein the 1,3-dioxolane based component is 20 to 75 percent of the total volume of the solvent.
8. The cell defined in claim 4 , wherein the 1,3-dioxolane based component is 1,3-dioxolane.
9. The cell defined in claim 1 , wherein the optional non-ether based solvent is 3,5-dimethylisoxazole.
10. The cell defined in claim 1 , wherein the electrolyte comprises 0.5 to 2 moles of solute per liter of solvent.
11. The cell defined in claim 1 ,wherein the solute further comprises at least one additional salt selected from the group consisting of: LiCIO 4 , Li(CF 3 SO 2 ) 2 N, Li(CF 3 CF 2 SO 2 ) 2 N, Li(CF 3 SO 2 ) 3 C and lithium bis(oxalate)borate.
12. The cell defined in claim 11 , wherein the solute comprises at least 5 weight percent lithium iodide.
13. The cell defined in claim 1 , wherein the metallic lithium comprises an alloy of lithium.
14. The cell defined in claim 13 , wherein the alloy comprises aluminum.
15. The cell defined in claim 1 , wherein the positive electrode further comprises a mixture of FeS 2 and carbon.
16. The cell defined in claim 15 , wherein the mixture further comprises a binder and said mixture is coated onto a metal current collector.
17. A primary electrochemical battery cell comprising:
a housing;
a negative electrode consisting essentially of lithium or a lithium alloy;
a positive electrode having a cathode coating disposed on a metallic current collector, said cathode coating comprising FeS 2 and, optionally, one or more members selected from the group consisting of: carbon, a binder, FeS, Bi 2 O 3 , CuO, Cu 2 O, CuS and CuS 2 ;
a separator disposed between the negative electrode and the positive electrode;
an electrolyte consisting essentially of at least one solute and a blend of organic solvents, said solute being at least one selected from the group consisting of: lithium iodide, LiCIO 4 , Li(CF 3 SO 2 ) 2 N, Li(CF 3 CF 2 SO 2 ) 2 N, Li(CF 3 SO 2 ) 3 C and lithium bis(oxalate)borate and said blend of organic solvents consisting essentially of: (i) 1,2-dimethoxypropane, (ii) 1,2-dimethoxyethane, (iii) an optional ether based cosolvent, and (iv) an optional non-ether based cosolvent that, when present, is less than 10 vol. % of the organic solvent and contains no dialkyl carbonates or cyclic carbonates; and
wherein the volume ratio of the 1,2-dimethoxypropane to the 1,2-dimethoxyethane is at least 2 to 1.