Coated article with low-E coating including IR reflecting layer(s) and corresponding method
View Patent ↗A coated article is provided with a low-emissivity (low-E) layer stack for use in a window unit or the like. The layer stack, or coating, may permit the coated article to achieve one or more of a low solar factor (SF) value, a high selectivity (T vis /SF) value, substantially neutral color at normal and/or off-axis viewing angles, and/or low emissivity. When high selectivity values are achieved, there is provided a high ratio of visible transmission to SF, which is a desirable feature in certain example instances. In certain example embodiments, a sub-oxide layer (e.g., NiCrO x ) may be used as a contact layer under an infrared (IR) reflecting layer in order to permit low SF values, high selectivity, and good coloration to be achieved.
1. An insulating glass (IG) window unit comprising:
first and second glass substrates, and a coating supported by one of the substrates, the coating comprising:
at least a first layer comprising silver sandwiched between and contacting first and second contact layers, wherein the first contact layer is located below said layer comprising silver and is oxided to a lesser extent than is the second contact layer located above said layer comprising silver, so that moving away from the one glass substrate that supports the coating the coating comprises the first contact layer, the first layer comprising silver, and then the second contact layer;
wherein said first contact layer comprises an oxide of Ni and/or Cr and is located between and contacting said layer comprising silver which is above said first contact layer and a layer comprising zinc oxide which is below said first contact layer, so that the layer comprising zinc oxide is located between at least the first contact layer and the one glass substrate that supports the coating; and
wherein the IG window unit has a visible transmission of from 40 to 60%, a selectivity (T vis /SF) of at least 1.75, and a solar factor (SF) of no greater than 27.5.
2. The IG window unit of claim 1 , wherein the coating further comprises a second layer comprising silver and a third contact layer that is located below and contacting said second layer comprising silver, and wherein said third contact layer which is under said second layer comprising silver is of a different material than is said first contact layer which is under said first layer comprising silver.
3. The IG window unit of claim 2 , wherein the second contact layer which is above the first layer comprising silver comprises an oxide of Ni and/or Cr, and wherein said third contact layer which is located below and contacting the second layer comprising silver comprises zinc oxide.
4. The IG window unit of claim 1 , wherein the coating includes only two infrared (IR) reflecting layers comprising silver.
5. The IG window unit of claim 1 , wherein each of the first and second contact layers comprise an oxide of NiCr.
6. The IG window unit of claim 1 , wherein the IG window unit has a selectivity of at least 1.80.
7. The IG window unit of claim 1 , wherein the IG window unit has a selectivity of at least 1.85.
8. The IG window unit of claim 1 , wherein the IG window unit has a SF of no greater than 27.0.
9. The IG window unit of claim 1 , wherein the IG window unit has an outside reflective a* value, at a normal viewing angle, of from −3 to +2.
10. The IG window unit of claim 1 , wherein the IG window unit has an outside reflective a* value, at a normal viewing angle, of from −2.5 to +1.
11. The IG window unit of claim 1 , wherein the coating has a sheet resistance (R s ) of no greater than 3.0 ohms/square.
12. The IG window unit of claim 1 , wherein the coating has a sheet resistance (R s ) of no greater than 2.0 ohms/square.
13. The IG window unit of claim 1 , wherein the glass substrate supporting the coating is not heat treated with the coating thereon.
14. The IG window unit of claim 1 , wherein the IG window unit has a visible transmission of from about 45 to 55%.
15. The IG window unit of claim 1 , wherein the IG unit has an outside a* value which does not change by more than 3.5 given a viewing angle shift from 0 to 45 degrees.
16. The IG window unit of claim 1 , wherein the IG unit has an outside a* value which does not change by more than 2.5 given a viewing angle shift from 0 to 45 degrees.
17. The IG window unit of claim 1 , wherein outside reflective a* and b* of the IG window unit do not change by more than 3.5 given a viewing angle shift from 0 to 45 degrees.
18. The IG window unit of claim 1 , wherein the coating comprises at least the following layers from the substrate which supports the coating outwardly:
a first dielectric layer;
another layer comprising zinc oxide;
a layer comprising silver;
a contact layer comprising an oxide of Ni and/or Cr;
a second dielectric layer;
said layer comprising zinc oxide;
said first contact layer;
said first layer comprising silver;
said second contact layer;
a third dielectric layer; and
an overcoat layer.
19. The IG window unit of claim 1 , wherein the first and second contact layers each comprise an oxide of the same metal(s).
20. The IG window unit of claim 1 , wherein reflective/outside color of the IG window unit does not significantly change as a function of polarization state of incident light.
21. An insulating glass (IG) window unit comprising:
first and second glass substrates, and a coating supported by one of the substrates, the coating comprising:
first and second infrared (IR) reflecting layers, each of the IR reflecting layers being sandwiched between and contacting a pair of contact layers,
wherein the contact layer located under and contacting the first IR reflecting layer comprises zinc oxide, and wherein the contact layer located under and contacting the second IR reflecting layer comprises an oxide of Ni and/or Cr and is oxided to a lesser extent than is the contact layer located over and contacting the second IR reflecting layer, so that moving away from the one glass substrate that supports the coating the coating comprises the contact layer comprising zinc oxide, the first IR reflecting layer, the contact layer comprising an oxide of Ni and/or Cr, and then the second IR reflecting layer; and
wherein the IG window unit has a selectivity (T vis /SF) of at least 1.75, and a solar factor (SF) of no greater than 27.5.
22. The IG window unit of claim 21 , wherein the contact layer located under and contacting the second IR reflecting layer comprises an oxide of NiCr.
23. The IG window unit of claim 21 , wherein each of the IR reflecting layers comprise silver.
24. The IG window unit of claim 21 , wherein the coating includes only two infrared (IR) reflecting layers.
25. The IG window unit of claim 19 , wherein the IG window unit has a selectivity of at least 1.80.
26. The IG window unit of claim 19 , wherein the IG window unit has a selectivity of at least 1.85.
27. The IG window unit of claim 19 , wherein the IG window unit has a SF of no greater than 27.0.
28. The IG window unit of claim 19 , wherein the IG window unit has a visible transmission of from 40 to 60%.
29. The IG window unit of claim 19 , wherein the IG window unit has an outside reflective a* value, at a normal viewing angle, of from −3 to +2.
30. The IG window unit of claim 19 , wherein the IG window unit has an outside reflective a* value, at a normal viewing angle, of from −2.5 to +1.
31. The IG window unit of claim 19 , wherein the coating has a sheet resistance (R s ) of no greater than 3.0 ohms/square.
32. The IG window unit of claim 19 , wherein the glass substrate supporting the coating is not heat treated with the coating thereon.
33. The IG window unit of claim 19 , wherein the IG unit has an outside a* value which does not change by more than 3.5 given a viewing angle shift from 0 to 45 degrees.
34. The IG window unit of claim 19 , wherein the IG unit has an outside a* value which does not change by more than 2.5 given a viewing angle shift from 0 to 45 degrees.
35. The IG window unit of claim 19 , wherein outside reflective a* and b* of the IG window unit do not change by more than 3.5 given a viewing angle shift from 0 to 45 degrees.
36. The IG window unit of claim 21 , wherein each of the contact layers contacting the second IR reflecting layer comprise an oxide of the same metal(s).
37. The IG window unit of claim 21 , wherein reflective/outside color of the IG window unit does not significantly change as a function of polarization state of incident light.
38. A coated article including a coating supported by a glass substrate, the coating comprising:
at least one layer comprising silver sandwiched between and contacting first and second contact layers, wherein the first contact layer is located below said layer comprising silver and is oxided to a lesser extent than is the second contact layer located above said layer comprising silver, so that moving away from the glass substrate the coating comprises the first contact layer, the layer comprising silver, and then the second contact layer;
wherein said first contact layer comprises an oxide of Ni and/or Cr and is located between and contacting said layer comprising silver which is above said first contact layer and a layer comprising zinc oxide which is below and contacting said first contact layer, so that the layer comprising zinc oxide is located between at least the first contact layer and the glass substrate; and
wherein the coated article has a selectivity (T vis /SF) of at least 1.75.
39. The coated article of claim 38 , wherein the article has a selectivity of at least 1.80.
40. The coated article of claim 38 , wherein the article has a selectivity of at least 1.85.
41. The coated article of claim 38 , wherein reflective/outside color of the coated article does not significantly change as a function of polarization state of incident light.