IP Library Granted Patent US 7,507,461
Granted Patent B2
US 7,507,461 · App. 10/932,510 · Granted Mar 24, 2009

Edge coating for honeycomb used in panels with composite face sheets

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Quick Facts
Patent No.
US 7,507,461
App. No.
10/932,510
Granted
Mar 24, 2009
Kind
B2
Abstract

Core-skin bonding is improved between honeycomb and composite face sheets by applying a nylon-based (polyamide) adhesive to the edge of the honeycomb prior to bonding. Edge coating of honeycomb with polyamide adhesives is useful in further increasing the bond strength between honeycomb and prepreg face sheets, especially when the matrix resin of the prepreg is designed to adhere the prepreg to the honeycomb.

Claims (37)

1. A method for bonding a face sheet to a honeycomb, said method comprising the steps of:

providing an uncured face sheet comprising an interior surface for bonding to said honeycomb and an exterior surface, said face sheet comprising at least one fiber layer and an uncured thermosetting resin matrix;

providing a honeycomb having walls that define a plurality of honeycomb cells wherein said walls have at least one edge for bonding to the interior surface of said face sheet;

applying a polyamide adhesive solution to said at least one edge to form an edge-coated honeycomb; and

bonding said uncured face sheet to said edge-coated honeycomb.

2. A method for bonding a face sheet to a honeycomb according to claim 1 wherein said polyamide adhesive solution comprises polyamide and a thermosetting resin.

3. A method for bonding a face sheet to a honeycomb according to claim 2 wherein said thermosetting resin is selected from the group consisting of epoxy and phenolic.

4. A method for bonding a face sheet to a honeycomb according to claim 1 wherein said polyamide adhesive solution comprises from 40 to 90 weight percent polyamide.

5. A method for bonding a face sheet to a honeycomb according to claim 1 wherein said honeycomb comprises a composite material selected from the group consisting of resin impregnated paper, resin impregnated glass fibers, and resin impregnated carbon fibers.

6. A method for bonding a face sheet to a honeycomb according to claim 1 wherein said face sheet comprises a prepreg.

7. A method for bonding a face sheet to a honeycomb according to claim 6 wherein said prepreg is self-adhesive.

8. A method for bonding a face sheet to a honeycomb according to claim 1 wherein said uncured thermosetting resin matrix comprises an uncured thermosetting resin selected from the group consisting of epoxy and phenolic.

9. A method for bonding a face sheet to a honeycomb according to claim 7 wherein said uncured thermosetting resin matrix comprises an uncured thermosetting resin selected from the group consisting of epoxy and phenolic.

10. In a method for bonding a prepreg face sheet to a honeycomb wherein said prepreg face sheet comprises an uncured thermosetting resin matrix and an interior surface for bonding to said honeycomb and an exterior surface and wherein said honeycomb comprises walls that define a plurality of honeycomb cells, said walls having at least one edge for bonding to the interior surface of said prepreg face sheet, the improvement comprising applying a polyamide adhesive solution to said at least one edge to form an edge-coated honeycomb and then bonding said uncured face sheet to said edge-coated honeycomb.

11. An improved method for bonding a prepreg face sheet to a honeycomb according to claim 10 wherein said polyamide adhesive solution comprises polyamide and a thermosetting resin.

12. An improved method for bonding a prepreg face sheet to a honeycomb according to claim 11 wherein said thermosetting resin is selected from the group consisting of epoxy and phenolic.

13. An improved method for bonding a prepreg face sheet to a honeycomb according to claim 11 wherein said polyamide adhesive solution comprises from 40 to 90 weight percent polyamide.

14. An improved method for bonding a prepreg face sheet to a honeycomb according to claim 10 wherein said honeycomb comprises a composite material selected from the group consisting of resin-impregnated paper, resin-impregnated glass fibers, and resin-impregnated carbon fibers.

15. An improved method for bonding a prepreg face sheet to a honeycomb according to claim 10 wherein said prepreg is self-adhesive.

16. An improved method for bonding a prepreg face sheet to a honeycomb according to claim 10 wherein said prepreg face sheet comprises at least one fiber layer and a matrix resin wherein said matrix resin comprises an uncured thermosetting resin.

17. An improved method for bonding a prepreg face sheet to a honeycomb according to claim 10 wherein said matrix resin comprises an uncured thermosetting resin selected from the group consisting of epoxy and phenolic.

18. An uncured honeycomb sandwich panel comprising:

a face sheet comprising an interior surface that is bonded to said honeycomb and an exterior surface, said face sheet comprising at least one fiber layer and an uncured thermosetting resin matrix;

a honeycomb having walls that define a plurality of honeycomb cells wherein said walls have at least one edge that is bonded to the interior surface of said face sheet; and

a polyamide adhesive solution located at said one edge to form a bond between said face sheet and said honeycomb.

19. An uncured honeycomb sandwich panel according to claim 18 wherein said face sheet is a prepreg.

20. An uncured honeycomb sandwich panel according to claim 19 wherein said prepreg is self-adhesive.

21. An uncured honeycomb sandwich panel according to claim 19 wherein said uncured thermosetting resin matrix comprises an uncured thermosetting resin selected from the group consisting of epoxy and phenolic.

22. An uncured honeycomb sandwich panel according to claim 20 wherein said uncured thermosetting resin matrix comprises an uncured thermosetting resin selected from the group consisting of epoxy and phenolic.

23. A honeycomb sandwich panel according to claim 19 wherein said uncured thermosetting resin matrix in said prepreg has been cured to provide a cured honeycomb sandwich panel.

24. A cured honeycomb sandwich panel according to claim 23 wherein a sufficient amount of said polyamide adhesive solution is located at said one edge such that said honeycomb wall is torn apart and said bond remains in tact when said face sheet is forcibly removed from said cured honeycomb sandwich panel.

25. An uncured honeycomb sandwich panel according to claim 18 wherein said polyamide adhesive solution comprises polyamide and a thermosetting resin.

26. An uncured honeycomb sandwich panel according to claim 25 wherein said uncured thermosetting resin is selected from the group consisting of epoxy and phenolic resins.

27. An uncured honeycomb sandwich panel according to claim 18 wherein said polyamide adhesive solution comprises from 40 to 90 weight percent polyamide.

28. An uncured honeycomb sandwich panel according to claim 18 wherein said honeycomb comprises a composite material selected from the group consisting of resin impregnated paper, resin impregnated glass fibers and resin impregnated carbon fibers.

29. A honeycomb sandwich panel according to claim 18 wherein said uncured thermosetting resin matrix is cured to form a cured honeycomb sandwich panel.

30. An improved method for bonding a prepreg face sheet to a honeycomb according to claim 10 wherein the amount of said polyamide adhesive solution that is applied said at least one edge of said honeycomb is less than 10 grams per square foot.

Assignments (10)
RELEASE OF SECURITY INTEREST Recorded Oct 2, 2014
From: CITIZENS BANK, NATIONAL ASSOCIATION
To: HEXCEL CORPORATION; HEXCEL HOLDINGS LUXEMBOURG S.À.R.L.
Reel/Frame 033887/0199 →
TERMINATION OF SECURITY INTEREST IN PATENTS Recorded Sep 24, 2014
From: CITIZENS BANK, NATIONAL ASSOCIATION (F/K/A RBS CITIZENS, N.A.)
To: HEXCEL CORPORATION
Reel/Frame 033813/0565 →
RELEASE OF SECURITY INTEREST Recorded Sep 3, 2013
From: BANK OF AMERICA, N.A.
To: HEXCEL CORPORATION
Reel/Frame 031140/0729 →
SECURITY AGREEMENT Recorded Jul 1, 2013
From: HEXCEL CORPORATION; HEXCEL HOLDINGS LUXEMBOURG S.A.R.L.
To: RBS CITIZENS, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 030724/0287 →
RELEASE OF SECURITY INTEREST Recorded Aug 20, 2010
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: HEXCEL CORPORATION
Reel/Frame 024864/0040 →
SECURITY AGREEMENT Recorded Aug 20, 2010
From: HEXCEL CORPORATION
To: BANK OF AMERICA, N.A.
Reel/Frame 024864/0016 →
GRANT OF PATENT SECURITY INTEREST Recorded May 21, 2009
From: HEXCEL CORPORATION
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS ADMINISTRATIVE AGENT
Reel/Frame 022722/0240 →
RELEASE OF PATENT SECURITY INTEREST Recorded May 21, 2009
From: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS ADMINISTRATIVE AGENT
To: HEXCEL CORPORATION; HEXCEL REINFORCEMENTS CORP.
Reel/Frame 022722/0301 →
SECURITY AGREEMENT Recorded Mar 1, 2005
From: HEXCEL CORPORATION; HEXCEL REINFORCEMENT CORPORATION
To: DEUTSCHE BANK TRUST COMPANY AMERICAS
Reel/Frame 015810/0600 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 9, 2004
From: WANG, YEN-SEINE; MORRISON, ROBERT; SMITH, CLARK
To: HEXCEL CORPORATION
Reel/Frame 015356/0670 →