The present spin finish composition comprises at least about 10 percent by weight based on the spin finish composition of components (a) and (b) having the formula R 1 —(CO) x —O—(CH(R 2 )—CH 2 —O) y —(CO) z —R 3 wherein each of R 1 and R 3 is selected from the group consisting of hydrogen or an alkyl group having from one to 22 carbon atoms or an alkylene hydroxy group having from one to 22 carbon atoms, x is zero or one, R 2 may vary within component (a) or component (b) and is selected from the group consisting of hydrogen or an alkyl group having from one to four carbon atoms, y is zero, or from one to 25, and z is zero or one, in component (a), x and z are equal to zero and the average molecular weight of component (a) is less than or equal to 1,900 and if R 2 varies, component (a) is a random copolymer; and in component (b), at least x or z is equal to one or component (b) is a complex polyoxyethylene glyceride-containing compound having greater than 10 polyoxyethylene units; up to about five percent by weight based on the spin finish composition of component (c) of an ethoxylated silicone; and at least about one percent by weight based on the spin finish composition of component (d) having the formula R 4 (CH 2 O(CO) a R 5 ) b wherein R 4 is —C— or —COC—; a is 0 or 1; R 5 is —H; from —CH 3 to —C 18 H 37 ; or —CH(R 6 )—CH 2 O; b is 4 or 6; and R 6 is —H or —CH 3 or —H and —CH 3 in a ratio of 10:90 to 90:10. The present spin finish composition may be used on industrial yarn.
1. A tire cord comprising a yarn, said yarn having a spin finish composition thereon, said spin finish composition comprising at least about 10 percent by weight based on said spin finish composition of components (a) and (b) having the formula
R 1 —(CO) x —O—(CH(R 2 )—CH 2 —O) y —(CO) 2 —R 3
wherein each of said R 1 and said R 3 is selected from the group consisting of hydrogen or an alkyl group having from one to 22 carbon atoms or an alkylene hydroxy group having from one to 22 carbon atoms,
said x is zero or one,
said R 2 may vary within said component (a) or said component (b) and is selected from the group consisting of hydrogen or an alkyl group having from one to four carbon atoms,
said y is zero, or from one to 25, and
said z is zero or one,
in said component (a), said x and z are equal to zero and the average molecular weight of said component (a) is less than or equal to 1,900 and if R 2 varies, component (a) is a random copolymer; and
in said component (b), at least one of said x or said z is equal to one or said component (b) is a complex polyoxyethylene glyceride-containing compound having greater than 10 polyoxyethylene units;
up to about five percent by weight based on said spin finish composition of component (c) of an ethoxylated silicone; and
at least about one percent by weight based on said spin finish composition of component (d) having the formula
R 4 (CH 2 O(CO) a R 5 ) b
wherein R 4 is —C— or —COC—; a is 0 or 1; R 5 is —H; from —CH 3 to —C 18 H 37 ; or —CH(R 6 )—CH 2 O); b is 4 or 6; and R 6 is —H or —CH 3 or —H and —CH 3 in a ratio of 10:90 to 90:10.
2. The tire cord of claim 1 wherein said component (a) is present in an amount of at least about 20 percent by weight based on said spin finish composition.
3. The tire cord of claim 2 wherein in said component (a), each of said R 1 and R 3 is selected from the group consisting of hydrogen or an alkyl group having from one to 22 carbon atoms.
4. The tire cord of claim 3 wherein in said component (a), each of said R 1 and R 3 is selected from the group consisting of hydrogen or an alkyl group having from one to ten carbon atoms, said R 2 varies and is selected from the group consisting of hydrogen and an alkyl group having one or two carbon atoms, and said y is zero or from one to 20.
5. The tire cord of claim 4 wherein the average molecular weight of said component (a) is less than about 1,500.
6. The tire cord of claim 5 wherein said component (a) is a random copolymer.
7. The tire cord of claim 1 wherein said component (b) is present in an amount of at least about 10 percent by weight based on said spin finish composition.
8. The tire cord of claim 1 wherein in said component (b), each of said R 1 and R 3 is selected from the group consisting of hydrogen or an alkyl group having from one to 22 carbon atoms or an alkylene hydroxy group having from one to 22 carbon atom, said R 2 may vary and is selected from the group consisting of hydrogen or an alkyl group having from one to four carbon atoms, and at least said x or z is equal to one.
9. The tire cord of claim 1 wherein said component (b) is a complex polyoxyethylene glyceride-containing compound having greater than 10 polyoxyethylene units.
10. The tire cord of claim 9 wherein said complex polyoxyethylene glyceride-containing compound is ethoxylated castor oil.
11. The tire cord of claim 1 wherein said component (d) is dipentaerythritol hexapelargonate or pentaerythritol tetrapelargonate.
12. The tire cord of claim 1 wherein said yarn comprises a polyamide.
13. The tire cord of claim 1 wherein said spin finish is applied to said yarn in an amount of about 0.2 to about 1.5 percent by weight based on the weight of said yarn.
14. The tire cord of claim 1 wherein in said component (a), each of said R 1 and R 3 is selected from the group consisting of hydrogen or an alkyl group having from one to 22 carbon atoms, said x and z are zero, said R 2 may vary and is selected from the group consisting of hydrogen or an alkyl group having from one to four carbon atoms, and said y is zero, or between one to 25.