Granted Patent B2

US 8,063,141 · App. 10/935,142 · Granted Nov 22, 2011

Abstract

Claims (33)

1. A hot melt pressure sensitive adhesive composition for adhering roofing sheets to a roof area comprising: a) a thermoplastic block copolymer selected from the group consisting of styrene-butadiene-styrene, styrene-isoprene-styrene, styrene-ethylene-propylene-styrene, a styrene-ethylene-propylene block copolymer and combinations thereof; b) from about 1 to 8% by weight of polyisobutylene having a viscosity average molecular weight from 750,000 to 2,340,000; c) a compatible tackifier; d) an amorphous polyolefin; e) a filler; and f) a flame retardant.

2. The adhesive composition as claimed in claim 1 wherein said tackifier is selected from the group consisting of hydrogenated polyalicyclic resins, aliphatic hydrocarbon resins, aromatic hydrocarbon resins, coumarone indene resins, esters of hydrogenated rosins, acrylic resins, and combinations thereof.

3. The adhesive composition as claimed in claim 1 wherein said amorphous polyolefin is selected from the group consisting of amorphous polypropylene-ethylene copolymers, amorphous polypropylene/polypropylene-ethylene copolymers, amorphous polypropylene homopolymers, amorphous polyethylene homopolymers and combinations thereof.

4. The adhesive composition as claimed in claim 1 further comprising an antioxidant.

5. The adhesive composition as claimed in claim 1 further comprising a compatible plasticizer.

6. The adhesive composition as claimed in claim 5 wherein said plasticizer is selected from the group consisting of polybutene, chlorinated paraffin, adipate esters, phthalate esters, epoxidized esters, oleate esters, phosphate esters, sebacate esters, stearate esters, aromatic process oils, naphthenic process oils, paraffinic process oils, and combinations thereof.

7. The adhesive composition as claimed in claim 1 further comprising a reinforcing agent selected from a group consisting of hydrophilic fumed silica, hydrophobic fumed silica, and hydrated amorphous precipitated silica.

8. An adhesive roofing article having a composition for adhering the roofing article to a roof area comprising: a roofing article having first and second major surfaces; and an adhesive composition applied to said first major surface of said roofing article, wherein said adhesive composition comprises: a) thermoplastic block copolymer selected from the group consisting of styrene-butadiene-styrene, styrene-isoprene-styrene, styrene-ethylene-propylene-styrene, a styrene-ethylene-propylene block copolymer and combinations thereof; b) from about 1 to 8% by weight of polyisobutylene having a viscosity average molecular weight from 750,000 to 2,340,000; c) a compatible tackifier; and d) a flame retardant.

9. The article as claimed in claim 8 further comprising a release liner adhered to said adhesive composition.

10. The article as claimed in claim 8 wherein said paraffinic hydrocarbon polymer is polyisobutylene.

11. The article as claimed in claim 8 wherein said tackifier is selected from the group consisting of hydrogenated polyalicyclic resins, aliphatic hydrocarbon resins, aromatic hydrocarbon resins, coumarone indene resins, esters of hydrogenated rosins, acrylic resins, and combinations thereof.

12. The article as claimed in claim 8 further comprising an amorphous polyolefin.

13. The article as claimed in claim 12 wherein said amorphous polyolefin is selected from the group consisting of amorphous polypropylene-ethylene copolymers, amorphous polypropylene/polypropylene-ethylene copolymers, amorphous polypropylene homopolymers, amorphous polyethylene homopolymers and combinations thereof.

14. The article as claimed in claim 8 wherein said adhesive composition further comprises an antioxidant.

15. The article as claimed in claim 8 wherein said adhesive composition further comprises a compatible plasticizer.

16. The article as claimed in claim 15 wherein said plasticizer is selected from the group consisting of polybutene, chlorinated paraffin, adipate esters, phthalate esters, epoxidized esters, oleate esters, phosphate esters, sebacate esters, stearate esters, aromatic process oils, naphthenic process oils, paraffinic process oils, and combinations thereof.

17. The article as claimed in claim 8 wherein said adhesive composition further comprises a reinforcing agent.

18. The adhesive composition as claimed in claim 17 wherein said reinforcing agent is selected from a group consisting of hydrophilic fumed silica, hydrophobic fumed silica, and hydrated amorphous precipitated silica.

19. The article as claimed in claim 8 wherein said adhesive composition exhibits 180° peel strength at room temperature of at least 254 grams/in when adhered to a substrate.

20. The article as claimed in claim 8 wherein said adhesive composition supports a static load of at least 50 grams/in 2 at 70° C. for at least 96 hours when adhered to a substrate.

21. The hot melt pressure sensitive adhesive composition of claim 1 wherein the flame retardant is selected from the group consisting of antimony oxide, decabromodiphenyl oxide, tetradecabromodiphenoxybenzene, hexabromocyclododecane, ethane-1,2-bis(pentabromophenyl), ethylenebistetrabromophthalimide, and mixtures thereof.

22. The adhesive roofing article of claim 8 wherein the flame retardant is selected from the group consisting of antimony oxide, decabromodiphenyl oxide, tetradecabromodiphenoxybenzene, hexabromocyclododecane, ethane-1,2-bis(pentabromophenyl), ethylenebistetrabromophthalimide, and mixtures thereof.

23. A hot melt pressure sensitive adhesive composition for adhering roofing sheets to a roof area comprising: a) a thermoplastic block copolymer selected from the group consisting of styrene-butadiene-styrene, styrene-isoprene-styrene, styrene-ethylene-propylene-styrene, a styrene-ethylene-propylene block copolymer and combinations thereof; b) from about 1 to 8% by weight of polyisobutylene having a viscosity average molecular weight from 750,000 to 2,340,000; c) from 31 to 38% by weight of a compatible tackifier; d) from 6 to 8% by weight of an amorphous polyolefin; e) from 6 to 7% by weight of a reinforcing agent selected from a group consisting of hydrophilic fumed silica, hydrophobic fumed silica, and hydrated amorphous precipitated silica; f) from 6 to 7% by weight of an antioxidant; g) from 31 to 41% by weight of a plasticizer; h) from 0.01 to 0.1% by weight of a pigment; and i) a flame retardant.

24. The hot melt pressure sensitive adhesive composition of claim 23 further comprising a filler selected from a group consisting of aluminum silicate, barium sulfate, calcium carbonate, calcium sulfate, cellulose fiber, solid glass microspheres, hollow glass microspheres, hydrous aluminum silicate, hydrated magnesium silicate, metallic oxide silica, ground mica, powdered coal, peanut shell flour, wollastonite and wood flour.

25. The adhesive composition as claimed in claim 23 wherein said tackifier is selected from the group consisting of hydrogenated polyalicyclic resins, aliphatic hydrocarbon resins, aromatic hydrocarbon resins, coumarone indene resins, esters of hydrogenated rosins, acrylic resins, and combinations thereof.

26. The adhesive composition as claimed in claim 23 wherein said amorphous polyolefin is selected from the group consisting of amorphous polypropylene-ethylene copolymers, amorphous polypropylene/polypropylene-ethylene copolymers, amorphous polypropylene homopolymers, amorphous polyethylene homopolymers and combinations thereof.

27. The adhesive composition as claimed in claim 23 wherein said plasticizer is selected from the group consisting of polybutene, chlorinated paraffin, adipate esters, phthalate esters, epoxidized esters, oleate esters, phosphate esters, sebacate esters, stearate esters, aromatic process oils, naphthenic process oils, paraffinic process oils, and combinations thereof.

28. The hot melt pressure sensitive adhesive composition of claim 1 comprising less than about 20% by weight of the thermoplastic block copolymer.

29. The hot melt pressure sensitive adhesive composition of claim 1 comprising about 10-15% by weight of the thermoplastic block copolymer.

30. The adhesive roofing article of claim 8 comprising less than about 20% by weight of the thermoplastic block copolymer.

31. The adhesive roofing article of claim 8 comprising about 10-15% by weight of the thermoplastic block copolymer.

32. The adhesive roofing article of claim 23 comprising less than about 20% by weight of the thermoplastic block copolymer.

33. The adhesive roofing article of claim 23 comprising about 10-15% by weight of the thermoplastic block copolymer.

Assignments (16)