Nonoriented stiff packaging film with superior tear properties
View Patent ↗A nonoriented film containing highly crystalline polypropylene, standard polypropylene and nucleating agents. The film has physical properties that are desirable for applications such as food wrappers and tampon overwrap, including good tearability, stiffness and memory. In addition, the nonoriented film is cost effective because the film achieves these physical properties without the step of stretching or orienting the film, as required for conventional polypropylene films used in food wrappers and tampon overwrap.
1. A nonoriented film comprising:
a core layer containing highly-crystalline polypropylene, polypropylene, and a nucleating agent, wherein said highly-crystalline polypropylene has a melt flow of at least about 20 g/10 minutes; and
two skin layers containing polypropylene having a melt flow of up to about 20 g/10 minutes, and highly-crystalline polypropylene having a melt flow of at least about 20 g/10 minutes.
2. The film of claim 1 , wherein said highly-crystalline polypropylene comprises at least about 15% by weight of said film.
3. The film of claim 1 , wherein said nucleating agent comprises from about 0.1% to about 5% by weight of said film.
4. The film of claim 1 , wherein at least one of said skin layers further comprises highly-crystalline polypropylene having a melt flow of at least 30 g/10 minutes.
5. The film of claim 1 , wherein said core layer further comprises a colorant.
6. The film of claim 1 , wherein said highly-crystalline polypropylene comprises from about 30% to about 90% by weight of said film.
7. The film of claim 6 , wherein said highly-crystalline polypropylene comprises from about 40% to about 50% by weight of said film.
8. The film of claim 1 , wherein said highly-crystalline polypropylene has a melt flow of from about 30 g/10 minutes to about 50 g/10 minutes.
9. The film of claim 8 , wherein said highly-crystalline polypropylene has a melt flow of about 40 g/10 minutes.
10. The film of claim 1 , wherein said nucleating agent comprises less than 5% by weight of said film.
11. The film of claim 1 , wherein said polypropylene is a homopolymer polypropylene having a melt flow of from about 8 g/10 minutes to about 20 g/10 minutes.
12. The film of claim 1 , wherein said film breaks at an elongation of less than 350% as measured by ASTM D 882.
13. The film of claim 1 , wherein said film breaks at an elongation of less than about 100% as measured by ASTM D 882.
14. The film of claim 1 , wherein said film breaks at an elongation of less than about 200% as measured by ASTM D 882.
15. The film of claim 1 , wherein said film breaks at an elongation of less than 15% as measured by ASTM D 882.
16. The film of claim 1 , wherein said film further comprises a trouser tear of less than about 100 grams.
17. The film of claim 1 , wherein said film has a secant modulus value of greater than or equal to about 200,000 psi.
18. The film of claim 1 , wherein said highly-crystalline polypropylene comprises from about 35% to about 65% by weight of said film.
19. The film of claim 1 , wherein said highly-crystalline polypropylene has a xylene-soluble content of from about 0.5% to about 1% by weight.
20. The film of claim 1 , wherein said polypropylene has a xylene-soluble content of from about 2% to about 4% by weight.
21. The film of claim 1 , wherein said polypropylene has a melt flow of from about 2 g/10 minutes to about 20 g/10 minutes.
22. The film of claim 21 , wherein said polypropylene has a melt flow of from about 8 g/10 minutes to about 18 g/10 minutes.
23. The film of claim 1 , wherein said polypropylene comprises up to about 85% by weight of said film.
24. The film of claim 23 , wherein said polypropylene comprises from about 15% to about 70% by weight of said film.
25. The film of claim 1 wherein said polypropylene is a polypropylene copolymer.
26. The film of claim 25 wherein said polypropylene copolymer is a random copolymer polypropylene.
27. The film of claim 1 further comprising at least one additive selected from the group consisting of antiblock compounds, antistatics, lubricants, stabilizers and mixtures thereof.
28. The film of claim 10 , said nucleating agent comprising from about 0.1% to about 4% by weight of said film.
29. The film of claim 1 , wherein said nucleating agent is selected from the group consisting of talc, silica, carbon black, kaolin, salts of aliphatic monobasic acids and free acids thereof, salts of aliphatic dibasic acids and free acids thereof, salts of arylalkyl acids and free acids thereof, alkali metals of aromatic carboxylic acids, alkali metals of alicyclic carboxylic acids, aluminum salts of aromatic carboxylic acids and free acids thereof, aluminum salts of alicyclic carboxylic acids and free acids thereof, bis-benzylidene sorbitol, benzoate salts and free acids thereof, sodium salts of organic phosphates and free acids thereof, and mixtures thereof.
30. The film of claim 1 wherein said nucleating agent is in a form selected from the group consisting of powders, powder mixtures, suspensions, solutions, master batches, or mixtures thereof.
31. The film of claim 30 wherein said nucleating agent is predispersed.
32. The film of claim 1 further comprising up to about 30% by weight of a CaCO 3 additive.
33. The film of claim 32 wherein said CaCO 3 additive is a 60% calcium carbonate/propylene blend.
34. The film of claim 27 , wherein said antiblock compounds are selected from the group consisting of silicon dioxide, calcium carbonate, magnesium silicate, aluminum silicate, calcium phosphate, polyamides, polyesters, polycarbonates, and mixtures thereof.
35. The film of claim 34 , wherein said film comprises from about 0.1% to about 5% by weight of said antiblock compound.
36. The film of claim 27 , wherein said lubricants are selected from the group consisting of polyethylene wax, erucamide, ethylene bis-oleamide, stearic acid, calcium/zinc heat-stabilizer soaps, slip compounds, and mixtures thereof.
37. The film of claim 5 , wherein said colorants is selected from the group consisting of titanium dioxide, calcium carbonate, and mixtures thereof.
38. The film of claim 37 , wherein said film comprises up to about 30% by weight of said colorants.
39. The film of claim 1 wherein said highly-crystalline polypropylene is a homopolymer.
40. The film of claim 1 wherein said highly-crystalline polypropylene is a copolymer.
41. The film of claim 40 wherein said copolymer comprises propylene and an α-olefin.
42. The film of claim 41 wherein said α-olefin is ethylene.
43. The film of claim 1 wherein said film has a thickness of from about 0.4 mils to about 2.0 mils.
44. The film of claim 1 wherein said film has a thickness of from about 1.0 mils to about 2.0 mils.