Autoxidisable architectural coating compositions
View Patent ↗An autoxidisable architectural coating composition suitable for application to surfaces found in and around buildings at ambient temperatures and in natural daylight by unsophisticated users having no respiratory protection wherein surface autoxidation of the composition is promoted by a combination of low concentrations of metal ions (especially manganese or vanadium) and at least one photoinitiator. The composition avoids the need to use more than trace amounts cobalt ions which are rumoured to be carcinogenic yet achieves adequately fast rates of autoxidation. Preferably the use of cobalt is avoided altogether. The use of the low concentrations of the other metal ions reduces discolouration of the compositions often to levels below what is achieved using conventional cobalt promoters. It also improves gloss. Also a modification in which surface autoxidation is promoted by a combination of a photoinitiator and trace amounts of cobalt ions in the absence of other surface autoxidation promoting metal ions. Finally, a method for applying the autoxidisable coatings to surfaces under ambient temperatures in which they are subjected to natural daylight or similar low energy irradiation.
1. An autoxidisable architectural coating composition which composition includes an autoxidisable binder polymer and a promoter system for promoting autoxidation of the autoxidisable binder polymer wherein the system comprises: a) metal ions which promote surface autoxidation present in an amount up to 0.04 wt % based on the weight of autoxidisable binder polymer in the coating composition; b) at least one photoinitiator activateable by natural daylight present in amounts of from 0.3 to 2.0 wt % based on the weight of the autoxidisable binder polymer in the composition for the system to promote surface autooxidation of the autoxidisable binder polymer at ambient temperatures; and c) sufficient through promoter for the through promoter to provide to the coating composition from 0.03 to 02 wt % of metal ions from the through promoter based on the weight of the binder polymer in the composition, wherein the composition comprises no cobalt ions.
2. A coating composition according to claim 1 wherein the composition comprises manganese ion, vanadium ion or combinations thereof as surface autoxidation promoters.
3. A coating composition according to claim 1 wherein the composition comprises metal ions selected from nickel, iron, chromium, copper, tin, and cerium as surface autoxidation promoters.
4. A coating composition according to claim 1 wherein the composition contains a benzoyl phenyl phosphine oxide as a photoinitiator.
5. A coating composition according to claim 1 wherein the composition contains camphorquinone as a photoinitiator.
6. A coating composition according to claim 1 wherein a combination of two or more photoinitiators are present in the composition.
7. An autoxidisable architectural coating composition which composition includes an autoxidisable binder polymer and a promoter system for promoting autoxidation of the autoxidisable binder polymer wherein the system comprises: a) metal ions other than cobalt ions being metal ions which promote surface autoxidation present in an amount up to 0.04 wt % based on the weight of autoxidisable binder polymer in the coating composition; b) less than 0.01 wt % of cobalt ions based on the weight of the autoxidisable binder polymer in the coating composition, wherein when the cobalt ions are 0 weight percent the weight percent of the metal ions other than cobalt is from 0.001 to 0.04; c) at least one photoinitiator activateable by natural daylight present in amounts of from 0.3 to 2.0 wt % based on the weight of the autoxidisable binder polymer in the composition for the system to promote surface autooxidation of the autoxidisable binder polymer at ambient temperatures; and d) sufficient through promoter for the through promoter to provide to the coating composition from 0.03 to 0.2 wt % of metal ions from the through promoter based on the weight of the binder polymer in the composition.
8. A coating composition according to claim 7 wherein a combination of two or more photoinitiators are present in the composition.
9. A coating composition according to claim 8 wherein the composition contains camphorquinone as a photoinitiator.
10. A coating composition according to claim 8 wherein the promoter system contains from 0.001 to 0.007 wt % of cobalt ions based on the weight of autoxidisable binder polymer in the coating composition as the only surface autoxidation promoting metal ions.
11. A coating composition according to claim 7 wherein the photoinitiator is a benzoyl phenyl phosphine oxide.
12. A coating composition according to claim 7 wherein the composition comprises manganese ion, vanadium ion or combinations thereof as surface autoxidation promoters.
13. A coating composition according to claim 7 wherein the composition comprises metal ions selected from nickel, iron, chromium, copper, tin, and cerium as surface autoxidation promoters.