Hardeners for water-based epoxy resin systems and processes for using the same
View Patent ↗Hardeners for water-based epoxy resin systems, the hardeners being obtainable by reacting a mixture of: (A) at least one epoxidized polyalkylene oxide selected from the group of epoxidized polyethylene oxides, epoxidized polypropylene oxides and polyethylene propylene oxides, (B) at least one epoxidized aromatic hydroxy compound selected from the group of bisphenol A epoxides and bisphenol F epoxides and (C) at least one aromatic hydroxy compound selected from the group of bisphenol A and bisphenol F, to form an intermediate product and subsequently reacting this intermediate product with a polyamine (E), are disclosed.
1. A hardener for water-based epoxy resin systems, the hardener prepared by a process comprising:
(a) reacting a mixture comprised of: (A) at least one epoxidized polyalkylene oxide selected from the group of epoxidized polyethylene oxides, epoxidized polypropylene oxides, epoxidized polyethylene propylene oxides and mixtures thereof; (B) at least one epoxidized aromatic hydroxy compound selected from the group of bisphenol A epoxides, bisphenol F epoxides and mixtures thereof; and (C) at least one aromatic hydroxy compound selected from the group of bisphenol A, bisphenol F and mixtures thereof, to form an intermediate product; and
(b) introducing an excess amount of polyamine (E) sufficient for the reaction of 1 molecule of polyamine with each epoxy group in the intermediate product, and reacting the intermediate product with the polyamine.
2. The hardener according to claim 1 , wherein the mixture further comprises (D) at least one compound selected from the group consisting of triglycidyl ethers of triols, diglycidyl ethers of diols and mixtures thereof.
3. The hardener according to claim 1 , wherein the at least one polyamine comprises diethylene triamine.
4. The hardener according to claim 2 , wherein the at least one polyamine comprises diethylene triamine.
5. The hardener according to claim 1 , wherein the at least one epoxidized polyalkylene oxide comprises an epoxidized polypropylene oxide.
6. The hardener according to claim 2 , wherein the at least one epoxidized polyalkylene oxide comprises an epoxidized polypropylene oxide.
7. The hardener according to claim 3 , wherein the at least one epoxidized polyalkylene oxide comprises an epoxidized polypropylene oxide.
8. The hardener according to claim 4 , wherein the at least one epoxidized polyalkylene oxide comprises an epoxidized polypropylene oxide.
9. The hardener according to claim 1 , wherein the at least one epoxidized aromatic hydroxy compound comprises a bisphenol A epoxide.
10. The hardener according to claim 2 , wherein the at least one epoxidized aromatic hydroxy compound comprises a bisphenol A epoxide.
11. The hardener according to claim 3 , wherein the at least one epoxidized aromatic hydroxy compound comprises a bisphenol A epoxide.
12. The hardener according to claim 5 , wherein the at least one epoxidized aromatic hydroxy compound comprises a bisphenol A epoxide.
13. The hardener according to claim 6 , wherein the at least one epoxidized aromatic hydroxy compound comprises a bisphenol A epoxide.
14. The hardener according to claim 1 , wherein the at least one aromatic hydroxy compound comprises bisphenol A.
15. The hardener according to claim 2 , wherein the at least one aromatic hydroxy compound comprises bisphenol A.
16. The hardener according to claim 3 , wherein the at least one aromatic hydroxy compound comprises bisphenol A.
17. The hardener according to claim 9 , wherein the at least one aromatic hydroxy compound comprises bisphenol A.
18. A hardener for water-based epoxy resin systems, the hardener prepared by a process comprising:
(a) reacting a mixture comprised of: (A) an epoxidized polypropylene oxides; (B) a bisphenol A epoxide; (C) bisphenol A; and (D) at least one compound selected from the group consisting of triglycidyl ethers of triols, diglycidyl ethers of diols and mixtures thereof, to form an intermediate product; and
(b) introducing an excess amount of polyamine (E) sufficient for the reaction of 1 molecule of polyamine with each epoxy group in the intermediate product, and reacting the intermediate product with the polyamine.
19. A process for producing a coating composition, said process comprising:
(a) providing a hardener prepared by a process comprising: (i) reacting a mixture comprised of: (A) at least one epoxidized polyalkylene oxide selected from the group of epoxidized polyethylene oxides, epoxidized polypropylene oxides, epoxidized polyethylene propylene oxides and mixtures thereof; (B) at least one epoxidized aromatic hydroxy compound selected from the group of bisphenol A epoxides, bisphenol F epoxides and mixtures thereof; and (C) at least one aromatic hydroxy compound selected from the group of bisphenol A, bisphenol F and mixtures thereof, to form an intermediate product; and (ii) reacting the intermediate product with (E) at least one polyamine; and
(b) introducing an excess amount of polyamine (E) sufficient for the reaction of 1 molecule of polyamine with each epoxy group in the intermediate product, and reacting the intermediate product with the polyamine.
20. A cured coating composition prepared by a process comprising: (a) providing a coating composition prepared by the process according to claim 19 on a substrate; and (b) curing the composition; wherein the cured coating composition has a longitudinal shrinkage of less than 3% in a layer thickness of more than 0.4 mm, as measured at 23° C./50% relative air humidity.