Gel laundry detergent composition
View Patent ↗The present invention provides a shear thinning, transparent gel laundry detergent composition, comprising a surfactant system containing surfactant material selected from an anionic surfactant, a nonionic surfactant or a mixture thereof, and from 0.1 to 10% by weight of a clarity improving agent being a glycol dialkyl ether selected from a mono-or polyethylene glycol dialkyl ether having the formula (C p H 2p+1 )O—(CH 2 CH 2 O) n —(C q H 2q+1 ), (I) a mono- or polypropylene glycol dialkyl ether having the formula (C p H 2p+1 )O—(CH 2 CH (CH 3 )O) n —(C q H 2q+1 ), (II) and mixtures thereof, wherein p and q independently are integers in the range of from 1 to 5, and n is an integer in the range of from 1 to 50, preferably 1 to 10. It has been found that this gel laundry composition is highly transparent, such that particles can be suspended therein for improving visual appearance.
1. A shear thinning, transparent lamellar-phase gel laundry detergent composition, comprising a surfactant system containing surfactant material selected from an anionic surfactant, a nonionic surfactant or a mixture thereof, and from 0.5 to 5% by weight of a clarity improving agent being a glycol dialkyl ether selected from a mono- or polyethylene glycol dialkyl ether having the formula
(C p H 2p+1 )O—(CH 2 CH 2 O) n —(C q H 2q+1 ) (I)
a mono- or polypropylene glycol dialkyl ether having the formula
(C p H 2p+1 )O—(CH 2 CH(CH 3 )O) n —(C q H 2q+1 ) (II),
and mixtures thereof,
wherein p and q independently are integers in the range of from 1 to 5, and n is an integer in the range of from 1 to 50, preferably 1 to 10.
2. A composition according to claim 1 , wherein the clarity improving agent is selected from the group consisting of polyethylene glycol dibutyl ether and polypropylene glycol dibutyl ether.
3. A composition according to claim 1 , wherein the composition further comprises from 1 to 8% by weight of a gelling agent.
4. A composition according to claim 3 , wherein the gelling agent is a fatty alcohol having the formula
R 1 —(CHOH)— 2 (III),
wherein:
R 1 , R 2 are independently selected from hydrogen and saturated or unsaturated, linear or branched, C 1 —C 16 alkyl groups, wherey the total number of carbon atoms in the fatty alcohol is between 8 and 17.
5. A composition according to claim 4 , wherein the fatty alcohol gelling agent is selected from 1-decanol, 1-dodecanol, 2-decanol, 2-dodecanol, 2-methyl-1-decanol, 2-methyl-1-dodecanol, 2-ethyl-1-decanol, and mixtures thereof.
6. A composition according to claim 3 , wherein the gelling agent is a non-neutralised fatty acid having the formula
R 3 —(COOH)—R 4 (IV),
wherein:
R3 and R4 are independently selected from hydrogen and saturated or unsaturated, linear or branched C 1 -C 22 alkyl groups, whereby the total number of carbon atoms in the fatty acid is between 10 and 23.
7. A composition according to claim 6 , wherein the fatty acid gelling agent is selected from oleic acid, lauric acid, myristic acid, palmitic acid, stearic acid, linoleic acid, linolenic acid and mixtures thereof.
8. A composition according to claim 3 , wherein the gelling agent is a naturally obtainable fatty acid selected from tallow, coconut, and palm kernel fatty acids.
9. A composition according to claim 1 , wherein the surfactant system contains an anionic surfactant selected from the group consisting of linear alkyl benzene sulphonate, alkyl polyether sulphate, alkyl sulphate, alkyl sulphonate and mixtures thereof.
10. A composition according to claim 1 , wherein the anionic surfactant is present at a concentration of from 5 to 50% by weight, preferably from 5 to 25% by weight.
11. A composition according to claim 1 , wherein the nonionic surfactant is an ethoxylated alcohol having 3 to 11 ethylene oxide groups.
12. A composition according to claim 1 , wherein the nonionic surfactant is present at a concentration of from 5 to 50% by weight, preferably from 5 to 30% by weight.
13. A composition according to claim 1 , wherein the composition additionally comprises a detergency builder selected from the group consisting of carboxylates, polycarboxylates, aminocarboxylates, carbonates, bicarbonates, phosphates, phosphonates, silicates, borates, and mixtures thereof.
14. A composition according to claim 1 , wherein the composition has at least 50%, preferably at least 70%, transmittance of light using a 1 centimeter cuvette at a wavelength of 410-800 nm, preferably 570-690 nm, whereby the composition is measured in the absence of dyes.
15. Method of improving the clarity and transparency of a shear thinning, transparent, lamellar-phase gel laundry detergent composition, said method comprising the steps of (a) preparing said composition by mixing the ingredients thereof, said composition comprising a surfactant system containing surfactant material selected from an anionic surfactant, a nonionic surfactant or a mixture thereof, and (b) adding from 0.5-5 by weight of a glycol dialkyl ether, as specified in claim 1 , to said composition.