Organic light-emitting device and method of fabricating the same
View Patent ↗An organic light-emitting device is constructed with an anode provided with a reflective metal layer, a transparent conductive layer, and a reflective metal oxide layer interposed therebetween, a cathode, and an organic functional layer interposed between the transparent conductive layer of the anode and the cathode, and provided with at least an organic emission layer. With this configuration, the reflective anode has high reflectivity, the reflectivity thereof is not substantially changed depending on wavelengths, and the reflective anode is free from defects caused by a galvanic phenomenon.
1. An organic light-emitting device, comprising:
an anode comprising a reflective metal layer, a transparent conductive layer, and a reflective metal oxide layer interposed between the reflective metal layer and the transparent conductive layer, with the reflective metal oxide layer having a thickness of approximately 10 Å to approximately 50 Å and being an oxide layer of the reflective metal layer, and the reflective metal layer being formed of one material selected from a group consisting of aluminum (Al), aluminum alloy, silver (Ag), and silver alloy;
a cathode;
an organic functional layer interposed between the transparent conductive layer of the anode and the cathode, the organic functional layer comprising at least an organic emission layer; and
a substrate on which one of the anode and the cathode is placed.
2. The organic light-emitting device as claimed in claim 1 , wherein the reflective metal layer is formed of aluminum-neodymium (AlNd).
3. The organic light-emitting device as claimed in claim 1 , wherein the reflective metal oxide layer is formed of one selected from a group consisting of an aluminum oxide layer, an aluminum-alloy oxide layer, a silver oxide layer, and a silver-alloy oxide layer.
4. The organic light-emitting device as claimed in claim 1 , wherein the reflective metal oxide layer is a native oxide layer or a sputtered oxide layer.
5. The organic light-emitting device as claimed in claim 1 , wherein the transparent conductive layer is one of an indium tin oxide (ITO) layer and an indium zinc oxide (IZO) layer.
6. The organic light-emitting device as claimed in claim 1 , wherein the cathode is formed of one selected from a group consisting of magnesium (Mg), calcium (Ca), aluminum (Al), silver (Ag), and barium (Ba).
7. The organic light-emitting device as claimed in claim 1 , wherein the anode is placed on the substrate, and the cathode is placed on the organic functional layer.
8. The organic light-emitting device as claimed in claim 1 , wherein the cathode is placed on the substrate, and the anode is placed on the organic functional layer.
9. A method of fabricating an organic light-emitting device, the method comprising the steps of:
providing a substrate;
forming a reflective metal layer on the substrate;
exposing the reflective metal layer to air to form a reflective metal oxide layer with a
thickness of approximately 10 Å to approximately 50 Å;
forming a transparent conductive layer on the reflective metal oxide layer; providing a cathode; and
forming an organic functional layer having at least an organic emission layer between the transparent conductive layer and the cathode, and the reflective metal layer being formed of one material selected from a group consisting of aluminum (Al), aluminum alloy, silver (Ag), and silver alloy.
10. An organic light-emitting device fabricated by the method of claim 9 .
11. An organic light-emitting device fabricated by the process of claim 9 , comprised of the anode placed on the substrate, and a cathode placed on the organic functional layer.
12. A method of fabricating an organic light-emitting device, the method comprising the steps of:
providing a substrate;
forming a cathode on the substrate;
forming an organic functional layer provided with at least an organic emission layer on the cathode; and
forming an anode on the organic functional layer, wherein the step of forming the anode comprises forming a transparent conductive layer on the organic functional layer, forming a reflective metal oxide layer having a thickness of approximately 10 Å to approximately 50 Å and being an oxide of the reflective metal layer on the transparent conductive layer, and forming a reflective metal layer of one material selected from a group consisting of aluminum, aluminum alloy, silver, and silver alloy on the reflective metal oxide layer.
13. The method as claimed in claim 12 , wherein the step of forming the reflective metal oxide layer is performed by a sputtering method.
14. The method as claimed in claim 12 , wherein the steps of forming the reflective metal layer and the reflective metal oxide layer is performed in situ by the sputtering method.
15. An organic light-emitting device fabricated by the method of claim 12 .
16. A method of fabricating an organic light-emitting device, the method comprising the steps of:
providing a substrate;
forming a reflective metal layer on the substrate;
sputtering reflective metal material at an oxygen atmosphere on the reflective metal layer to form a reflective metal oxide layer with a thickness of approximately 10 Å to approximately 50 Å;
forming a transparent conductive layer on the reflective metal oxide layer;
forming an organic functional layer having at least an organic emission layer on the transparent conductive layer; and
providing a cathode on the organic functional layer, and the reflective metal layer being formed of one material selected from a group consisting of aluminum (Al), aluminum alloy, silver (Ag), and silver alloy.
17. An organic light-emitting device fabricated by the method of claim 16 .