Biguanide bleaching agent for a thermal-imaging receptor element
View Patent ↗The present invention provides a receptor element for use in thermal transfer imaging. The receptor element includes a coating having a polymeric binder and a biguanide bleaching agent. The biguanide bleaching agent is capable of bleaching an infrared-absorbing dye when the biguanide bleaching agent and the infrared-absorbing dye are in contact. A particularly suitable biguanide bleaching agent is 1-(o-tolyl)biguanide. The invention also provides compositions and methods for manufacturing a receptor element. Also provided by the invention is an imaging system for thermal transfer imaging. The imaging system includes a color-bearing element and a bleaching element, wherein the bleaching element includes a coating having a polymeric binder and a biguanide bleaching agent. The invention further provides methods useful in the production of integral proofs.
1. A receptor element for use in thermal transfer imaging, comprising:
a) a sheet support having an image-receiving side; and
b) disposed on the image-receiving side of the support, a coating comprising a polymeric binder and a non-polymeric biguanide agent for bleaching an infrared-absorbing dye transferred to the image-receiving side of the receptor element during thermal transfer imaging.
2. The receptor element of claim 1 , wherein the biguanide agent is a biguanide compound in free base form.
3. The receptor element of claim 2 , wherein the biguanide compound is an aryl biguanide compound.
4. The receptor element of claim 3 , wherein the aryl biguanide compound is phenylbiguanide.
5. The receptor element of claim 3 , wherein the aryl biguanide compound is an alkylphenyl biguanide compound.
6. The receptor element of claim 5 , wherein the alkylphenyl biguanide compound comprises a phenyl ring having at least one C 1 –C 6 alkyl group as a substituent.
7. The receptor element of claim 5 , wherein the alkylphenyl biguanide compound is 1-(o-tolyl)biguanide.
8. The receptor element of claim 1 , wherein the support comprises a polyester film.
9. The receptor element of claim 1 , wherein the support comprises a textured polyester film.
10. The receptor element of claim 1 , wherein the binder includes a hydroxylic polymer.
11. The receptor element of claim 1 , wherein the binder comprises polyvinyl butyral.
12. The receptor element of claim 1 , wherein the binder comprises a styrene/allyl alcohol copolymer.
13. The receptor element of claim 1 , wherein the coating comprises about 5 to about 20 parts binder to one part biguanide agent, by weight.
14. The receptor element of claim 1 , wherein the coating further comprises a particulate material characterized by an average particle size in the range from about 3 to about 50 μm.
15. The receptor element of claim 14 , wherein the coating comprises about 20 to about 80 parts binder to one part particulate material, by weight.
16. The receptor element of claim 14 , wherein the particulate material comprises polymeric beads having an average diameter in the range from about 3 to about 50 μm.
17. The receptor element of claim 16 , wherein the particulate material comprises polymeric beads having an average diameter in the range from about 5 to about 25 μm.
18. The receptor element of claim 16 , wherein the polymeric beads comprise poly(methyl methacrylate) beads.
19. The receptor element of claim 16 , wherein the polymeric beads comprise poly(methyl methacrylate) beads having an average diameter of about 10 μm.
20. The receptor element of claim 1 , wherein the coating has a thickness of about 2 μm to about 20 μm.
21. The receptor element of claim 1 , wherein the coating comprises:
40 to 90 wt.-%, based on the solids content of the coating, of the polymeric binder;
0.1 to 35 wt.-%, based on the solids content of the coating, of poly(methyl methacrylate) beads; and
2 to 25 wt.-%, based on the solids content of the coating, of the biguanide agent.
22. The receptor element of claim 1 , wherein the coating comprises:
40 to 90 wt.-%, based on the solids content of the coating, of a polyvinyl butyral as the polymeric binder;
0.1 to 35 wt.-%, based on the solids content of the coating, of poly(methyl methacrylate) beads; and
2 to 25 wt.-%, based on the solids content of the coating, of 1-o-tolyl)biguanide as the biguanide agent.
23. The receptor element of claim 1 , further comprising a release layer disposed between the sheet support and the coating.
24. The receptor element of claim 23 , wherein the release layer comprises a styrene/butadiene copolymer.
25. The receptor element of claim 1 , wherein the receptor element is a proof substrate.
26. The receptor element of claim 25 , wherein the sheet support is paper or card stock.
27. A bleaching agent transfer element, comprising
a sheet support; and
disposed on the support, a transferable coating comprising a polymeric binder and a biguanide bleaching agent for bleaching an infrared-absorbing dye contacted by the transferable coating during thermal transfer imaging.
28. The bleaching agent transfer element of claim 27 , further comprising a release layer disposed between the sheet support and the transferable coating.
29. A method for making a receptor element for thermal transfer imaging, comprising:
providing a sheet support having an image-receiving side; and
applying a coating to the image-receiving side of the sheet support, the coating comprising a polymeric binder and a non-polymeric biguanide agent for bleaching an infrared-absorbing dye transferred to the image-receiving side of the receptor element during thermal transfer imaging.
30. The method of claim 29 , wherein the step of applying a coating includes:
dissolving or dispersing the polymeric binder and the biguanide agent in a suitable solvent or solvent mixture to make a coating composition;
contacting the coating composition to the image-receiving side of the sheet support to produce a layer of the coating composition on the sheet support; and
drying the coating composition to remove at least some of the solvent, to leave the coating on the sheet support.
31. The method of claim 29 , wherein the step of applying a coating further includes applying a release layer to the image-receiving side of the sheet support.
32. A coating composition for manufacturing a receptor element, comprising:
40 to 90 wt.-%, based on the solids content of the composition, of a polymeric binder;
2 to 25 wt.-%, based on the solids content of the composition, of a non-polymeric biguanide bleaching agent; and
0.1 to 35 wt.-%, based on the solids content of the composition, of a particulate material characterized by an average particle size in the range from about 3 to about 50 μm;
dissolved or dispersed in a suitable solvent.
33. The coating composition of claim 32 , wherein the biguanide bleaching agent is a biguanide compound in free base from.
34. The coating composition of claim 33 , wherein the biguanide compound is an aryl biguanide compound.
35. The coating composition of claim 34 , wherein the aryl biguanide compound is phenylbiguanide.
36. The coating composition of claim 34 , wherein the aryl biguanide compound is an alkylphenyl biguanide compound.
37. The coating composition of claim 36 , wherein the alkylphenyl biguanide compound comprises a phenyl ring having at least one C 1 –C 6 alkyl group as a substituent.
38. The coating composition of claim 36 , wherein the alkylphenyl biguanide compound is 1-(o-tolyl)biguanide.
39. The coating composition of claim 32 , wherein the binder comprises a hydroxylic polymer.
40. The coating composition of claim 32 , wherein the binder comprises polyvinyl butyral.
41. The coating composition of claim 32 , wherein the binder comprises a styrene/allyl alcohol copolymer.
42. The coating composition of claim 32 , wherein the particulate material comprises poly(methyl methacrylate) beads.
43. An imaging system for thermal transfer imaging, comprising:
a color-bearing element comprising a colorant and an infrared-absorbing dye; and
a bleaching element comprising a sheet support having an imaging side and a coating disposed on the imaging side, the coating comprising a polymeric binder and a biguanide bleaching agent;
wherein the biguanide bleaching agent is capable of bleaching the infrared-absorbing dye when the biguanide bleaching agent and the infrared-absorbing dye are in contact.
44. The imaging system of claim 43 , wherein the color-bearing element is a donor element having a transferable colorant.
45. The imaging system of claim 44 , wherein the sheet support of the proof substrate is paper or card stock.
46. The imaging system of claim 43 , wherein the bleaching element is a proof substrate.
47. The imaging system of claim 43 , wherein the bleaching element includes a transferable coating comprising the biguanide bleaching agent.
48. A method for use in the production of an integral proof, comprising:
providing a color-bearing element comprising a transferable colorant and an infrared-absorbing dye;
providing a bleaching element comprising a sheet support having an image-receiving side and a coating on the image-receiving side, the coating comprising a polymeric binder and a biguanide bleaching agent;
assembling the color-bearing element and the bleaching element in close proximity, with the image-receiving side of the bleaching element adjacent to the color-bearing element; and
imagewise transferring colorant from the color-bearing element to the image-receiving side of the bleaching element.
49. The method of claim 48 , wherein the color-bearing element is a donor element, and the bleaching element is a receptor element.
50. The method of claim 48 wherein the step of imagewise transferring colorant comprises:
imagewise exposing the assembly of the donor and receptor elements using infrared radiation, to cause imagewise transfer of colorant from the donor element to the receptor element.
51. The method of claim 50 wherein an infrared laser is used for imagewise exposure.
52. The method of claim 50 further comprising:
providing a second donor element comprising a second transferable colorant and an second infrared-absorbing dye;
assembling the second donor element and the receptor element in close proximity, with the image-receiving side of the receptor sheet support adjacent to the second donor element;
imagewise exposing in register the assembly of the second donor and receptor elements using infrared radiation, to cause imagewise transfer of colorant from the second donor element to the receptor element; and
imagewise transferring colorant from the receptor element to a proof substrate.
53. The method of claim 52 , further comprising:
providing a third donor element comprising a third transferable colorant and a third infrared-absorbing dye;
assembling the third donor element and the receptor element in close proximity, with the image-receiving side of the receptor sheet support adjacent to the third donor element; and
imagewise exposing in register the assembly of the third donor and receptor elements using infrared radiation, to cause imagewise transfer of colorant from the third donor element to the receptor element.
54. The method of claim 48 , wherein the color-bearing element is an image-bearing element, and the step of imagewise transferring colorant comprises transferring colorant under action of pressure or overall heating of the assembly of the color-bearing and bleaching elements.
55. The method of claim 54 , wherein the bleaching element is a proof substrate.
56. The method of claim 55 , wherein the sheet support is paper or card stock.
57. The method of claim 48 , wherein a portion of the infrared-absorbing dye is transferred to the image-receiving side of the bleaching element during imagewise transfer of colorant, and wherein the biguanide bleaching agent bleaches the transferred infrared-absorbing dye.