Methods for purifying p,p-bisphenol-A
View Patent ↗Methods for purifying a p,p-bisphenol A generally include distilling a feed stream comprising p,p-BPA in a distillation column at a pressure less than or equal to 20 millibars. The distillation column separates the bisphenol feed stream to produce a light fraction, an intermediate fraction and a heavy fraction. The intermediate fraction comprising the purified bisphenol contains lesser impurities that the p,p-BPA in the feed stream. In one embodiment, the intermediate stream is recovered using a side-draw. The side-draw is located between a first zone and a third zone in the distillation column.
1. A method for purifying p,p-bisphenol A, said method comprising:
distilling a feedstream comprising p,p-bisphenol A in a distillation column at a pressure less than or equal to 20 millibars;
producing a light fraction, an intermediate fraction, and a heavy fraction from the distillation column;
feeding the heavy fraction to a second reactor and isomerizing impurities in the heavy fraction to produce additional p,p-bisphenol A;
feeding a portion of the light fraction to a first reactor and purging a remaining portion of the light fraction in a third reactor, wherein feeding the portion to the first reactor converts impurities in the light fraction to produce additional p,p-bisphenol A, and wherein feeding the remaining portion to the third reactor removes impurities from the remaining portion; and
recovering the intermediate fraction as a side draw of the distillation column, wherein the p,p-bisphenol A in the intermediate fraction contains less impurities than the p,p-bisphenol A in the feedstream.
2. The method of claim 1 , wherein said feedstream comprises greater than or equal to 80% p,p-bisphenol A.
3. The method of claim 1 , wherein the light fraction is a vapor, a liquid or a vapor-liquid.
4. The method of claim 1 , wherein the intermediate and heavy fractions are liquids.
5. The method of claim 1 , wherein the first reactor comprises an acid catalyst.
6. The method of claim 1 , further comprising introducing phenol into the first reactor.
7. The method of claim 1 , further comprising feeding a feedstream containing the additional p,p-bisphenol A produced in the first reactor to the distillation column.
8. The method of claim 1 , wherein the third reactor produces an effluent comprising phenol or phenol and isopropenyl phenol.
9. The method of claim 1 , wherein the second reactor comprises an acid catalyst.
10. The method of claim 1 , further comprising simultaneously feeding a solvent into the second reactor.
11. The method of claim 1 , further comprising introducing phenol into the second reactor.
12. The method of claim 1 , further comprising feeding a feedstream containing the additional p,p-bisphenol A produced in the second reactor to the distillation column.
13. The method of claim 1 , wherein the distillation column comprises 4 to 30 theoretical stages.
14. A method for purifying a feedstream comprising p,p-bisphenol A, comprising:
flowing the feedstream comprising p,p-bisphenol A into a distillation column, wherein the distillation column comprises a first zone, a third zone, and a second zone intermediate the first and third zones; wherein flowing the feedstream comprises introducing the feedstream into the second zone;
distilling the feedstream into three fractions, wherein a light fraction is produced from the first zone, an intermediate fraction is produced from the second zone and a heavy fraction is produced from the third zone, wherein the intermediate fraction is withdrawn from the distillation column as a side draw and comprises p,p-bisphenol A at a purity greater than 90% and at a purity greater than the p,p-bisphenol A in the feedstream.
15. The method of claim 14 , further comprising:
flowing the light fraction to a first reactor, wherein the light fraction comprises o,p-bisphenol A and/or isopropenyl phenol; and
converting the o,p-bisphenol A to form additional p,p-bisphenol A, and/or reacting the isopropenyl phenol with phenol to form the additional p,p-bisphenol A.
16. The method of claim 15 , further comprising:
feeding the additional p,p, bisphenol A to the distillation column.
17. The method of claim 14 , further comprising:
flowing the heavy fraction to a second reactor; and
isomerizing o,p-bisphenol A, and/or 2,4-bis[2-(4-hydroxyphenyl)propyl]phenol, and/or 4-[1-methyl-1-{2,2,4-trimethyl-4-(p-hydroxyphenyl)-chroman-6-yl}-ethyl]-phenol to form additional p,p-bisphenol A.
18. The method of claim 17 , further comprising feeding the additional p,p-bisphenol A to the distillation column.
19. The method of claim 17 , further comprising diluting the heavy fraction with a solvent.
20. The method of claim 14 , wherein the distillation column is at a pressure less than or equal to 20 millibars, the first zone is at a temperature of 150 to 230° C., the second zone is at a temperature of 210 to 230° C., and the third zone is at a temperature of 200 to 300° C.