Microporous high density polyethylene film
View Patent ↗Disclosed is a microporous high density polyethylene film for a battery separator and a method of producing the same. The microporous high density polyethylene film includes high density polyethylene with a weight average molecular weight of 2×10 5 -5×10 5 , containing 5 wt % or less molecule with a molecular weight of 1×10 4 or less. The microporous high density polyethylene film has tensile strengths of 1,100 kg/cm 2 or more in transverse and machine directions respectively, a puncture strength of 0.22 N/μm or more, a gas permeability (Darcy's permeability constant) of 1.3×10 −5 Darcy or more, and shrinkages of 5% or less in machine and transverse directions, respectively. Particularly, the microporous high density polyethylene film has an excellent extrusion-compoundabiliy and stretchability and a high productivity, and can improve the performances and stability of a battery produced using the same.
1. A microporous high density polyethylene film prepared from a composition, comprising:
20-50 wt % high density polyethylene with a weight average molecular weight of 2×10 5 -5×10 5 (component I), containing 5 wt % or less molecule with a molecular weight of 1×10 4 or less; and
80-50 wt % diluent (component II),
wherein, tensile strengths are 1,100 kg/cm 2 or more in transverse and machine directions respectively, a puncture strength is 0.22 N/μm or more, a gas permeability (Darcy's permeability constant) is 1.3×10 −5 Darcy or more, and shrinkages are 5% or less in transverse and machine directions, respectively, by heat setting the film at a temperature range where 10-30 wt % of a crystalline portion of the film is molten.
2. The microporous high density polyethylene film as set forth in claim 1 , wherein the component I contains 2 wt % or less comonomer, the comonomer being selected from the group consisting of propylene, butene-1, hexene-1, and 4-methylpentene-1.
3. The microporous high density polyethylene film as set forth in claim 1 , wherein the component II includes a paraffin oil with a kinetic viscosity of 20-200 cSt at 40° C.