An earplug comprising a foam composition containing a polyvinyl chloride resin and less than about 5 wt % monomeric phthalate, based on the total weight of the foam composition, is described. The foam composition may include a plasticizer containing less than or equal to about 2 wt % monomeric phthalate, based on the total weight of the plasticizer. The earplugs have slow recovery times from 60 percent compression to 10 percent compression of about 10 to about 60 seconds.
1. An earplug comprising a foam composition, wherein the foam composition consists essentially of about 45 wt % to about 65 wt % of a polyvinyl chloride resins, about 30 wt % to about 50 wt % of a plasticizer, and less than about 5 wt % of monomeric phthalate plasticizer, based on the total weight of the foam composition.
2. The earplug of claim 1 , wherein the foam composition consists essentially of about 45 wt % to about 65 wt % of a polyvinyl chloride resin, about 30 wt % to about 50 wt % of a plasticizer, and less than or equal to about 4 wt % of monomeric phthalate plasticizer, based on the total weight of the foam composition.
3. The earplug of claim 1 , wherein the foam composition consists essentially of about 45 wt % to about 65 wt % of a polyvinyl chloride resin, about 30 wt % to about 50 wt % of a plasticizer, and less than or equal to about 1 wt % of monomeric phthalate plasticizer, based on the total weight of the foam composition.
4. The earplug of claim 1 , wherein the foam composition consists essentially of about 45 wt % to about 65 wt % of a polyvinyl chloride resin, about 30 wt % to about 50 wt % of a plasticizer, and less than or equal to about 0.5 wt % of monomeric phthalate plasticizer, based on the total weight of the foam composition.
5. The earplug of claim 1 , wherein the foam composition has a rate of recovery from 60 percent compression to 10 percent compression of about 10 to about 60 seconds.
6. The earplug of claim 1 , wherein the foam composition has a rate of recovery from 60 percent compression to 10 percent compression of about 15 to about 40 seconds.
7. The earplug of claim 1 , wherein the foam composition comprises a plasticizer comprising less than or equal to about 2 wt % monomeric phthalate plasticizer, based on the total weight of the plasticizer.
8. The earplug of claim 1 , wherein the foam composition further comprises epoxidized soybean oil.
9. The earplug of claim 1 , wherein the foam composition further comprises a chemical foaming agent, a resin stabilizer, a cell stabilizer, or a combination of one or more of the foregoing additives.
10. The earplug of claim 1 , wherein the plasticizer is a polymeric phthalate plasticizer.
11. An earplug comprising a foam composition, wherein the foam composition consists essentially of:
about 45 wt % to about 65 wt % of a polyvinyl chloride resin; and
about 30 wt % to about 50 wt % of a plasticizer, both based on the total weight of the foam composition, wherein the plasticizer comprises less than or equal to about 2 wt % monomeric phthalate plasticizer, based on the total weight of the plasticizer.
12. The earplug of claim 11 , wherein the plasticizer comprises less than or equal to about 1 wt % monomeric phthalate plasticizer, based on the total weight of the plasticizer.
13. The earplug of claim 11 , wherein the foam composition comprises less than or equal to about 1 wt % of monomeric phthalate plasticizer, based on the total weight of the foam composition.
14. The earplug of claim 11 , wherein the foam composition comprises less than or equal to about 0.5 wt % of monomeric phthalate plasticizer, based on the total weight of the foam composition.
15. The earplug of claim 11 , wherein the foam composition further comprises epoxidized soybean oil.
16. The earplug of claim 11 , wherein the foam composition further comprises a chemical foaming agent, a resin stabilizer, a cell stabilizer, or a combination of one or more of the foregoing additives.
17. The earplug of claim 11 , wherein the foam composition has a rate of recovery from 60 percent compression to 10 percent compression of about 10 to about 60 seconds.
18. The earplug of claim 11 , wherein the foam composition has a rate of recovery from 60 percent compression to 10 percent compression of about 15 to about 40 seconds.
19. The earplug of claim 11 , wherein the plasticizer is a polymeric phthalate plasticizer.
20. An earplug comprising a foam composition, wherein the foam composition consists essentially of:
45 wt % to 65 wt % of a polyvinyl chloride resin; and
30 wt % to 50 wt % of a plasticizer, both based on the total weight of the foam composition, wherein the plasticizer comprises less than or equal to 2 wt % monomeric phthalate plasticizer, based on the total weight of the plasticizer.