IP Library Granted Patent US 7,211,137
Granted Patent B2
US 7,211,137 · App. 10/966,342 · Granted May 1, 2007

Binder composition comprising condensed tannin and furfuryl alcohol and its uses

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Quick Facts
Patent No.
US 7,211,137
App. No.
10/966,342
Granted
May 1, 2007
Kind
B2
Abstract

This invention relates to a binder composition comprising condensed tannin and furfuryl alcohol. The composition can be used to prepare foundry mixes. The foundry mixes are prepared by mixing the composition with an acid or salt of an acid. The foundry mixes are then shaped into molds or cores and cured by heating or by the no-bake process with stronger acid curing catalysts. The molds and cores are used in casting metal articles.

Claims (9)

1. A foundry mix comprising a binder comprising (a) condensed tannin, and (b) furfuryl alcohol, and a major amount of a foundry aggregate.

2. The foundry mix of claim 1 wherein the amount of condensed tannin is from about 1.0 weight percent to about 40 weight percent, based upon the weight percent of the mixture of condensed tannin and furfuryl alcohol.

3. The foundry mix of claim 2 , which further comprises a liquid curing catalyst.

4. The foundry mix of claim 3 wherein the liquid curing catalysts is selected from the group consisting of copper chloride, copper toluene sulphonate, aluminum phenol sulphonate, phenol sulphonic acid, p-toluene sulphonic acid, lactic acid, benzene sulfonic acid, xylene sulfonic acid, sulfuric acid, salts thereof and mixtures thereof.

5. The foundry mix of claim 4 wherein the amount of liquid curing catalyst is from about 1 to 60 weight percent based upon the weight of total binder.

6. The composition of claim 5 wherein the amount of condensed tannin is from about 10 weight percent to about 40 weight percent, based upon the weight percent of the mixture of condensed tannin and furfuryl alcohol.

7. The composition of claim 6 wherein the amount of liquid curing catalyst is from about 15 to 30 weight percent based upon the weight of total binder.

8. The composition of claim 6 wherein the amount of binder is from about 0.5 percent by weight to about 7 percent by weight based upon the weight percent of the aggregate.

9. The composition of claim 2 wherein the condensed tannin is tannin from the Quebracho tree.

Assignments (12)
RELEASE OF SECURITY INTEREST Recorded Nov 4, 2024
From: GLAS TRUST CORPORATION LIMITED
To: ASK CHEMICALS LLC
Reel/Frame 069292/0617 →
CONVERSATION Recorded Mar 30, 2023
From: ASK CHEMICALS L.P.
To: ASK CHEMICALS LLC
Reel/Frame 063196/0385 →
CONVERSION Recorded Oct 15, 2019
From: ASK CHEMICALS LP
To: ASK CHEMICALS LLC
Reel/Frame 050726/0362 →
SECURITY INTEREST Recorded Jun 23, 2017
From: ASK CHEMICALS L.P.
To: HSBC CORPORATE TRUSTEE COMPANY (UK) LIMITED, AS SECURITY AGENT
Reel/Frame 042962/0520 →
RELEASE OF SECURITY INTEREST Recorded May 18, 2017
From: INVESTEC BANK, PLC, AS SECURITY AGENT
To: ASK CHEMICALS LP
Reel/Frame 042498/0029 →
SECURITY AGREEMENT SUPPLEMENT Recorded Oct 9, 2014
From: ASK CHEMICALS LP
To: INVESTEC BANK PLC, AS SECURITY AGENT
Reel/Frame 033944/0454 →
CORRECTIVE ASSIGNMENT TO REMOVE PATENT NUMBER 6763859 PREVIOUSLY RECORDED AT REEL: 025622 FRAME: 0222. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 30, 2014
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
To: ASK CHEMICALS L.P.
Reel/Frame 033063/0840 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENT NUMBER 6763859 PREVIOUSLY RECORDED ON REEL 016408 FRAME 0950. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 9, 2014
From: ASHLAND INC.
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
Reel/Frame 032867/0391 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 12, 2011
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
To: ASK CHEMICALS L.P.
Reel/Frame 025622/0222 →
PARTIAL RELEASE OF PATENT SECURITY AGREEMENT Recorded Dec 2, 2010
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
Reel/Frame 025437/0375 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 5, 2005
From: STANCLIFFE, MARK R; KROKER, JORG
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
Reel/Frame 016850/0496 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 17, 2005
From: ASHLAND INC.
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
Reel/Frame 016408/0950 →