IP Library Granted Patent US 7,820,198
Granted Patent B2
US 7,820,198 · App. 10/967,985 · Granted Oct 26, 2010

Pool chemical tablet

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Quick Facts
Patent No.
US 7,820,198
App. No.
10/967,985
Granted
Oct 26, 2010
Kind
B2
Abstract

One aspect of the present invention is directed to a solid chemical tablet in a shape comprising an elongated cylindrical side surface and an elongated flat side surface or an elongated concave cut side surface. Another aspect of the present invention is directed to a solid chemical tablet comprising a blend of hydrated calcium hypochlorite with magnesium sulfate heptahydrate. This invention further relates to a solid chemical tablet comprising a blend of solid calcium hypochlorite, and one or more solid alkali metal phosphate.

Claims (81)

1. A chemical tablet for use as a sanitizer in pool chemicals and having a distinctive shape for improved user safety, the chemical tablet comprising:

an upper flat surface; and

a lower flat surface,

wherein

the upper flat surface and the lower flat surface are opposite extremities of the tablet and are connected by a first elongated side surface and a second elongated side surface, wherein the second elongated side surface is an elongated flat side surface or an elongated concave cut side surface so that the chemical tablet has a non-cylindrical shape,

the shape renders the chemical tablet readily distinguishable from tablets of differing composition, thereby facilitating user safety,

the chemical tablet further comprises a blend of:

a hydrated calcium hypochlorite; and

a scale inhibiting solid alkali metal phosphate,

the chemical tablet has a single layer bounded by the upper flat surface and the lower flat surface, said blend being disposed throughout said single layer, and

the chemical tablet further comprises a coloring agent.

2. The chemical tablet of claim 1 wherein the coloring agent is ultramarine blue, phthalocyanine blue or phthalocyanine green.

3. The chemical tablet of claim 1 wherein the scale inhibiting solid alkali metal phosphate is present in an amount from about 0.1% to about 4.5% by weight based on the total weight of the tablet.

4. The chemical tablet of claim 3 wherein the scale inhibiting solid alkali metal phosphate is sodium tripolyphosphate.

5. The chemical tablet of claim 1 wherein the upper flat surface and the lower flat surface are connected by a first elongated cylindrical side surface and a second elongated flat side surface, the distance from an apex of the first elongated cylindrical side surface and the second elongated flat side surface is of about 2.37 inches, and a distance from the upper flat surface and the lower flat surface is of about 1.7 inches.

6. The chemical tablet of claim 1 , wherein the second elongated side surface is an elongated concave cut side surface.

7. A chemical tablet for use as a sanitizer in pool chemicals and having a distinctive shape and color for improved user safety, the chemical tablet comprising hydrated calcium hypochlorite, the tablet having a shape comprising

an upper flat surface; and

a lower flat surface,

wherein

the upper flat surface and the lower flat surface are opposite extremities of the tablet and are connected by a first elongated side surface and a second elongated side surface, wherein the second elongated side surface is an elongated flat side surface or an elongated concave cut side surface so that the chemical tablet has a non-cylindrical shape, the chemical tablet thereby rendered readily distinguishable in appearance from tablets of differing composition to facilitate user safety,

the chemical tablet has a single layer bounded by the upper flat surface and the lower flat surface, said hydrated calcium hypochlorite being disposed throughout said single layer, and

the chemical tablet further comprises a coloring agent for providing the chemical tablet with a distinctive color, the coloring agent being ultramarine blue, phthalocyanine blue or phthalocyanine green.

8. The chemical tablet of claim 1 , further comprising a residue dispersing solid alkali metal phosphate.

9. The chemical tablet of claim 8 wherein the residue dispersing solid alkali metal phosphate is present in an amount from 0.1% to about 4.5% by weight based on the total weight of the tablet.

10. The chemical tablet of claim 8 wherein the residue dispersing solid alkali metal phosphate is sodium hexametaphosphate.

11. A chemical tablet for use as a sanitizer in pool chemicals and having a distinctive shape for improved user safety, the chemical tablet comprising:

an upper flat surface; and

a lower flat surface,

wherein

the upper flat surface and the lower flat surface are connected by a first elongated side surface and a second elongated side surface, wherein the second elongated side surface is an elongated flat side surface or an elongated concave cut side surface so that the chemical tablet has a non-cylindrical shape,

the shape renders the chemical tablet readily distinguishable from tablets of differing composition, thereby facilitating user safety,

the chemical tablet further comprises a blend of:

a hydrated calcium hypochlorite; and

a scale inhibiting solid alkali metal phosphate,

the chemical tablet further comprises a coloring agent, and

the chemical tablet has a dissolving rate in accordance with dimensions thereof.

12. The chemical tablet of claim 11 wherein the chemical tablet has a dissolving rate in accordance with a surface area of the chemical tablet.

13. The chemical tablet of claim 12 wherein the chemical tablet has a dissolving rate in standing water of less than 150 grams per day.

14. A chemical tablet for use as a sanitizer in pool chemicals

consisting essentially of:

a pressed granular mixture of hydrated calcium hypochlorite and an alkali metal phosphate,

the mixture being homogeneous or near homogeneous;

the chemical tablet having an upper flat surface and a lower flat surface, wherein the upper flat surface and the lower flat surface are connected by a first elongated side surface and a second elongated side surface, wherein the second elongated side surface is an elongated flat side surface or an elongated concave cut side surface so that the chemical tablet has a non-cylindrical shape.

15. The chemical tablet of claim 14 , wherein said mixture additionally contains an additive.

16. The chemical tablet of claim 15 , wherein said additive is a coloring agent.

17. A chemical tablet for use as a sanitizer in pool chemicals

consisting essentially of:

a pressed granular mixture of hydrated calcium hypochlorite and an additive, the mixture

being homogeneous or near homogeneous;

the chemical tablet having an upper flat surface and a lower flat surface, wherein the upper flat surface and the lower flat surface are connected by a first elongated side surface and a second elongated side surface, wherein the second elongated side surface is an elongated flat side surface or an elongated concave cut side surface so that the chemical tablet has a non-cylindrical shape.

18. The chemical tablet of claim 17 wherein the additive is an alkali metal phosphate.

19. The chemical tablet of claim 17 wherein the additive contains a coloring agent.

20. The chemical tablet of claim 17 wherein the additive is at least one of sodium tripolyphosphate (STPP) and sodium hexametaphosphate (SHMP).

21. The chemical tablet of claim 17 wherein the additive is a combination of magnesium sulfate heptahydrate and an alkali metal phosphate.

22. A chemical tablet for use as a sanitizer in pool chemicals

consisting essentially of:

a pressed granular mixture of hydrated calcium hypochlorite and an additive, the mixture being homogeneous or near homogeneous; and

a coloring agent,

the chemical tablet having an upper flat surface and a lower flat surface, wherein the upper flat surface and the lower flat surface are connected by a first elongated side surface and a second elongated side surface, wherein the second elongated side surface is an elongated flat side surface or an elongated concave cut side surface so that the chemical tablet has a non-cylindrical shape.

23. The chemical tablet of claim 22 wherein the additive is an alkali metal phosphate.

24. The chemical tablet of claim 22 wherein the additive is at least one of sodium tripolyphosphate (STPP) and sodium hexametaphosphate (SHMP).

25. The chemical tablet of claim 22 wherein the additive is a combination of magnesium sulfate heptahydrate and an alkali metal phosphate.

26. The chemical tablet of claim 1 wherein the upper flat surface is connected to an upper beveled edge.

27. The chemical tablet of claim 26 wherein the distance between the upper beveled edge and an outer edge of the chemical tablet is about 0.25 inches.

28. The chemical tablet of claim 1 wherein the lower flat surface is connected to a lower beveled edge.

29. The chemical tablet of claim 28 wherein the distance between the lower beveled edge and an outer edge of the chemical tablet is about 0.25 inches.

30. The chemical tablet of claim 1 wherein the upper flat surface is connected to an upper beveled edge and the lower flat surface is connected to a lower beveled edge.

31. The chemical tablet of claim 1 wherein a distance from an apex of the first elongated cylindrical side surface and the second elongated flat side surface is about 2.37 inches.

32. The chemical tablet of claim 1 wherein a distance from the upper flat surface and the lower flat surface is at least 1.7 inches.

33. The chemical tablet of claim 1 wherein a distance from an apex of the first elongated cylindrical side surface and a point on the second elongated concave cut side surface is about 2.24 inches.

34. The chemical tablet of claim 1 wherein said chemical tablet dissolves at a rate of about less than 150 grams per day.

35. The chemical tablet of claim 1 wherein the chemical tablet comprises a blend of hydrated calcium hypochlorite with magnesium sulfate heptahydrate, wherein the blend comprises at least about 17% by weight of water based on the total weight of the blend, from about 0.1% to about 10% of lime based on the total weight of the blend, at least 25% by weight of magnesium sulfate heptahydrate and less than about 75% by weight of hydrated calcium hypochlorite.

36. The chemical tablet of claim 35 wherein the coloring agent is ultramarine blue, phthalocyanine blue or phthalocyanine green.

37. The chemical tablet of claim 7 wherein the chemical tablet comprises a blend of hydrated calcium hypochlorite and at least one alkali metal phosphate.

38. The chemical tablet of claim 37 wherein the alkali metal phosphate is sodium tripolyphosphate.

39. The chemical tablet of claim 35 wherein sodium tripolyphosphate is present in an amount from about 0.1% to about 4.5% by weight based on the total weight of the chemical tablet.

40. The chemical tablet of claim 7 wherein the chemical tablet comprises a blend of:

a hydrated calcium hypochlorite;

a scale inhibiting solid alkali metal phosphate; and

a residue dispersing solid alkali metal phosphate.

Assignments (18)
SECURITY INTEREST Recorded Nov 14, 2025
From: CHEM-AQUA, INC.; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; NCH CORPORATION; NCH LIFE SCIENCES LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073570/0838 →
RELEASE OF SECURITY INTEREST Recorded Nov 14, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073564/0864 →
SECURITY AGREEMENT (NOTES) Recorded Oct 10, 2025
From: DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073061/0885 →
RELEASE OF 2023 NOTES PATENT SECURITY INTERESTS Recorded Oct 10, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073074/0198 →
SECURITY AGREEMENT (2024 NOTES) Recorded Jun 24, 2024
From: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 067824/0278 →
2023 NOTES PATENT SECURITY AGREEMENT Recorded Jul 7, 2023
From: BIRKO CORPORATION; SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE GLOBAL CORPORATION
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 064225/0170 →
SECURITY AGREEMENT (NOTES) Recorded Sep 14, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
Reel/Frame 061432/0821 →
NOTES SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 058103/0066 →
ABL PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A.
Reel/Frame 058102/0122 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: GOLDMAN SACHS BANK USA
Reel/Frame 058102/0407 →
RELEASE OF SECURITY INTEREST AT REEL 048676 FRAME 0131 Recorded Nov 9, 2021
From: BANK OF AMERICA, N.A.
To: INNOVATIVE WATER CARE, LLC
Reel/Frame 058081/0970 →
RELEASE OF SECURITY INTEREST AT REEL 048695 FRAME 0069 Recorded Nov 9, 2021
From: BANK OF AMERICA, N.A.
To: INNOVATIVE WATER CARE, LLC
Reel/Frame 058082/0191 →
RELEASE OF SECURITY INTEREST AT REEL 048682 FRAME 0494 Recorded Nov 9, 2021
From: BANK OF AMERICA, N.A.
To: INNOVATIVE WATER CARE, LLC
Reel/Frame 058082/0176 →
SECOND LIEN SECURITY AGREEMENT Recorded Mar 26, 2019
From: INNOVATIVE WATER CARE, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 048695/0069 →
FIRST LIEN SECURITY AGREEMENT Recorded Mar 25, 2019
From: INNOVATIVE WATER CARE, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 048682/0494 →
SECURITY AGREEMENT Recorded Mar 22, 2019
From: INNOVATIVE WATER CARE, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 048676/0131 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 8, 2019
From: ARCH CHEMICALS, INC.
To: INNOVATIVE WATER CARE, LLC
Reel/Frame 048546/0682 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 6, 2004
From: BLANCHETTE, DAVID W.; GINN, G. WARREN
To: ARCH CHEMICALS, INC.
Reel/Frame 015429/0711 →