Pigment dispersion, precursor of ink for UV-curing type ink-jet recording, method of ink-jet recording, printed matter, and method of manufacturing pigment dispersion
View Patent ↗There is provided a pigment dispersion comprising at least one resin-coated pigment comprising a resin and a pigment, and having an average particle diameter of 250 nm or less, and a dispersion medium containing as a major component a cation polymeric compound having a viscosity of 30 mPa.s or less at a temperature of 25° C. and a boiling point of 150° C. or more at 1 atm. The pigment is incorporated in the pigment dispersion at a ratio ranging from 3 to 41% by weight based on a total weight of the dispersion medium, and the resin is incorporated in the resin-coated pigment at a ratio ranging from 5 to 37% by weight based on the weight of the pigment.
1. A UV curing type liquid ink precursor comprising:
a pigment dispersion which comprises a resin-coated pigment comprising a resin and a pigment, and having an average particle diameter of 250 nm or less; and a dispersion medium having a viscosity of 30 mPa.s or less at a temperature of 25° C. and a boiling point of 150° C. or more at 1 atm, the dispersion medium containing as a major component a cation polymeric compound and containing at least one selected from the group consisting of limonene diepoxide, neopentyl glycol diglycidyl ether, di[1-ethyl(3-oxetanyl)]methyl ether and cyclohexane vinyl ether; and
a photo-acid generating agent;
wherein a mixing ratio of the pigment is confined within the range of 3 to 41% by weight based on a total weight of the dispersion medium, and a ratio of the resin in the resin-coated pigment is confined within the range of 5 to 37% by weight based on the weight of the pigment.
2. An ink-jet recording method comprising a step of using an ink containing a UV curing type liquid ink precursor which is claimed in claim 1 .
3. A printed matter comprising an image formed of cured ink containing a UV curing type liquid ink precursor which is claimed in claim 1 .
4. A method of manufacturing a pigment dispersion comprising:
subjecting a pigment to surface treatment to provide the pigment with a functional group to obtain a surface-modified pigment;
either coating the surface-modified pigment with a resin at a ratio of 5 to 37% by weight based on the weight of the surface-modified pigment and then dispersing the resin-coated pigment in a preliminary dispersion medium at a ratio ranging from 10% by weight to 41% by weight based on a total weight of the preliminary dispersion medium to obtain a dispersion precursor which is dispersed in the preliminary dispersion medium having a boiling point not more than 140° C. at 1 atm; or adding 10% to 41% by weight (based on a total weight of a preliminary dispersion medium) of the surface-modified pigment and 5 to 37% by weight (based on the surface-modified pigment) of the resin to the preliminary dispersion medium having a boiling point not more than 140° C. at 1 atm to obtain a dispersion precursor where the resin-coated pigment composed of the surface-modified pigment and the resin is dispersed in the preliminary dispersion medium;
adding a main dispersion medium having a viscosity of 30 mPa.s or less at a temperature of 25° C. and a boiling point of 150° C. or more at 1 atm to the dispersion precursor and mixing them to obtain a mixture; and
subjecting the mixture to distillation at a temperature of not higher than 70° C. and under a reduced pressure to remove the preliminary dispersion medium to obtain the pigment dispersion where the resin-coated pigment is dispersed in the main dispersion medium.
5. The method according to claim 4 , wherein the pigment dispersion contains aggregated particles having a particle diameter of 1 μm or more, the method further comprising removing the preliminary dispersion medium by distillation and subjecting the aggregated particles to centrifugal separation for a period ranging from 5 minutes to 3 hours while applying a gravity of 2500 G to 70000 G to the aggregated particles.