Molybdenum metal powder and production thereof
View Patent ↗Molybdenum metal powder, and method for production thereof. Molybdenum metal powder has surface-area-to-mass-ratios in a range of between about 1.0 meters 2 /gram (m 2 /g) and about 3.0 m 2 /g, as determined by BET analysis, in combination with a particle size wherein at least 30% of the particles have a particle size larger than a size +100 standard Tyler mesh sieve. In addition, molybdenum metal powder 10 may be further distinguished by flowability in a range of between about 29 seconds/50 grams (s/50 g) and about 64 s/50 g, as determined by a Hall Flowmeter. A method of producing molybdenum powder may comprise providing a supply of ammonium molybdate, heating the ammonium molybdate at an initial temperature in the presence of a reducing gas to produce an intermediate product, and heating the intermediate product at a final temperature in the presence of the reducing gas, producing molybdenum metal powder.
1. A molybdenum metal powder, comprising:
a surface-area-to-mass-ratio between about 1.0 m 2 /g and about 3.0 m 2 /g, as determined by BET analysis; and
a flowability of between about 58 s/50 g and about 63 s/50 g, as determined by a Hall Flowmeter.
2. The molybdenum metal powder of claim 1 , wherein the surface-area-to-mass-ratio is between about 1.32 m 2 /g and 2.56 m 2 /g, as determined by BET analysis.
3. The molybdenum metal powder of claim 1 , wherein the molybdenum metal powder begins to sinter at about 950° C.
4. The molybdenum metal powder of claim 1 , having a weight percent of oxygen less than about 0.2%.
5. The molybdenum metal powder of claim 1 , wherein at least 30% of the molybdenum metal powder particles have a particle size larger than a size +100 standard Tyler mesh sieve.
6. The molybdenum metal powder of claim 5 , wherein at least 40% of the molybdenum metal powder particles have a particle size larger than a size +100 standard Tyler mesh sieve.
7. The molybdenum metal powder of claim 1 , wherein at least 20% of the molybdenum metal powder particles have a particle size smaller than a size −325 standard Tyler mesh sieve.
8. A method of producing molybdenum metal powder, comprising:
providing a supply of ammonium molybdate;
heating the ammonium molybdate at an initial temperature in the presence of a reducing gas to produce an intermediate product; and
heating the intermediate product at a final temperature in the presence of the reducing gas. creating a molybdenum metal powder having a surface-area-to-mass-ratio between about 1.0 m 2 /g and about 3.0 m 2 /g, as detennined by BET analysis, and flowability between about 58 s/50 g and about 63 s/50 g, as determined by a Hall Flowmeter.
9. The method of claim 8 , wherein the surface-area-to-mass-ratio of the molybdenum metal powder is between about 1.32 m2/g and about 2.56 m2/g, as determined by BET analysis.
10. The method of claim 8 , wherein heating the ammonium molybdate at the initial temperature and heating the intermediate product at the final temperature comprises heating for about two hours.
11. The method of claim 8 , wherein heating the ammonium molybdate at the initial temperature comprises heating at about 600° C.
12. The method of claim 8 , wherein heating the ammonium molybdate at the initial temperature comprises heating for about 40 minutes.
13. The method of claim 8 , wherein heating the intermediate product at the final temperature comprises heating at about 950° C.
14. The method of claim 8 , wherein heating the intermediate product at the final temperature comprises heating for about 40 minutes.
15. The method of claim 8 , further comprising heating the intermediate product at an intermediate temperature before heating the intermediate product at the final temperature.
16. The method of claim 8 , wherein heating the intermediate product at the intermediate temperature comprises heating at about 750° C.
17. A method of producing molybdenum metal powder, comprising:
providing a supply of ammonium molybdate; heating the ammonium molybdate at an initial temperature in the presence of a reducing gas to produce an intermediate product;
heating the intermediate product at an intermediate temperature for about 40 minutes before heating the intermediate product at a final temperature; and
heating the intermediate product at the final temperature in the presence of the reducing gas, creating a molybdenum metal powder having a surface-area-to-mass-ratio between about 1.0 m 2 /g and about 3.0 m 2 /g, as determined by BET analysis, and flowabilitv between about 29 s/50 g and about 64 s/50 g, as determined by a Hall Flowmeter.
18. The method of claim 17 , wherein providing a supply of ammonium molybdate comprises providing a supply of ammonium dimolybdate (ADM).
19. The method of claim 17 , wherein providing a supply of ammonium molybdate comprises providing a supply of ammonium heptamolybdate (AHM).
20. The method of claim 17 , wherein providing a supply of ammonium molybdate comprises providing a supply of ammonium octamolybdate (AOM).