Random propylene copolymers
View Patent ↗Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C 4 –C 10 -1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C 4 –C 10 -1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.
1. A random copolymer of propylene with ethylene,
whose content of comonomers is in the range from 0.75–1.2% by weight, and
whose cold-xylene soluble fraction is from 1.0 to 2.5% by weight.
2. A random copolymer of propylene as claimed in claim 1 , whose Q 5 value is greater than or equal to 200, where Q 5 is given by
Q 5 =1000×μ( T m )/μ( T m −5K)
and μ(T m ) is the elongational viscosity of the random propylene copolymer at the lowest temperature at which the copolymer is fully molten, and μ(Tm−5K) is the elongational viscosity at a temperature which is lower by 5K, and the elongational viscosities are determined 2 seconds after stretching begins at a constant rate (Hencky strain rate) {acute over (ε)} of 0.2 s −1 .
3. A random propylene copolymer as claimed in claim 1 , whose PI (Processability Index) is greater than 18, where the PI is determined from the formula
PI =ln( SH+ 1)×(ln Q 3 +ln Q 5 ),
Q 5 is given by
Q 5 =1000×μ( T m )/μ( T m −5K)
and Q 3 is given by
Q 3 =1000×μ( T m )/μ( T m −3K),
μ(T m ) is the elongational viscosity at the lowest temperature at which the copolymer is fully molten, μ(T m −5K) is the elongational viscosity at a temperature which is lower by 5K and μ(T m −3K) is the elongational viscosity at a temperature which is lower by 3K, and the elongational viscosities are determined 2 seconds after stretching begins at a constant strain rate (Hencky strain rate) {acute over (ε)} of 0.2 s −1 ,
and the factor SH (Strain Hardening) is the ratio of the maximum gradient of the curve of elongational viscosity plotted against time on a double logarithmic scale for temperatures less than T m −5K to the gradient of the elongational viscosity curve 1 second after stretching begins at a constant Hencky strain rate {acute over (ε)} of 0.2 s −1 at a temperature of T m −5K.
4. A film, a fiber or a molding comprising random propylene copolymers as claimed in claim 1 .
5. A biaxially stretched film made from random propylene copolymers as claimed in claim 1 and having a stretching ratio of at least 4:1 in the longitudinal direction and of at least 5:1 in the transverse direction.
6. The random copolymer of claim 2 wherein Q 5 is greater than or equal to 300.