Granted Patent B2

US 7,093,781 · App. 10/973,848 · Granted Aug 22, 2006

Abstract

Claims (49)

1. A process of making powder rubber comprising the steps of

(a) drying preprocessed rubber particles;

(b) precooling said dried rubber particles with an inert gas at a temperature not higher than about 0° F.;

(c) freezing said rubber particles to a temperature below the glass transition temperature by contacting said particles with a cryogenic liquid;

(d) comminuting said cooled rubber particles to a size in the range of crumb or powder rubber;

(e) heating said cold comminuted rubber particles to ambient temperature; and

(f) screening said comminuted rubber particles into desired powder rubber size ranges.

2. A process in accordance with claim 1 wherein said drying step (a) comprises contacting said rubber particles with combustion product gas maintained at a temperature range of between about 100° F. and about 200° F.

3. A process in accordance with claim 1 wherein said freezing step (c) involves contact with a cryogenic liquid.

4. A process in accordance with claim 1 wherein said comminuting step (d) is provided with variable means to accommodate different average particle sized cooled rubber particles.

5. A process in accordance with claim 1 wherein said comminuting step (d) is provided with a cooling agent provided by an inert gas whose source is said cryogenic liquid heated in said cooling step (c).

6. A process in accordance with claim 5 wherein said inert gas cooling agent is at a temperature in the range of between about −90° F. and about −125° F.

7. A process in accordance with claim 1 wherein said comminuting step (d) includes introduction of a cryogenic liquid.

8. A process in accordance with claim 1 wherein said preprocessed rubber particles have an average particle size such that they pass through a U.S. sieve size of ⅜ inch but do not pass through 40 mesh.

9. A process for making powder rubber comprising the steps of:

(a) drying preprocessed rubber particles having a particle size in the range of between about −⅜ inch and about +40 mesh;

(b) precooling said dried rubber particles with a coolant nitrogen gas recycle stream at a temperature in the range of between about 0° F. and about −200° F.;

(c) freezing said precooled rubber particles to below the glass transition temperature of said rubber by contact and exposure to liquid nitrogen wherein said liquid nitrogen is heated to gaseous nitrogen;

(d) comminuting said rubber particles below the glass transition temperature in the presence of said gaseous nitrogen, and a coolant nitrogen gas recycle system;

(e) recycling said nitrogen gas, generated in said freezing step (c), to said precooling step (b) and said comminuting step (d);

(f) warming said comminuting rubber particles to ambient temperature; and

(g) screening said ambient temperature comminuted rubber particles into desired powder rubber size ranges.

10. A process in accordance with claim 9 comprising the step of introducing a source of nitrogen liquid during said comminuting step (d).

11. An apparatus for making powder rubber comprising:

(a) drying means for drying a feedstock of preprocessed rubber particles;

(b) precooling means for precooling said dried rubber particles with inert gas at a temperature no higher than about 0° F.

(c) freezing means for cooling said precooled rubber particles to a temperature below the glass transition temperature;

(d) comminuting means for comminuting said rubber particles below the glass transition temperature to a size in the range of powder rubber;

(e) warming means for warming said comminuted rubber particles to ambient temperature; and

(f) screening means for providing said comminuting rubber particles in fine powder rubber size ranges.

12. An apparatus in accordance with claim 11 wherein said drying means comprises means for heating said feedstock of preprocessed rubber particles with combustion gases at a temperature in the range of between about 100° F. and about 200° F.

13. An apparatus in accordance with claim 11 wherein said comminuting means is provided with means for introduction of an inert gas coolant therein at a temperature in en the range of between about −90° F. and about −125° F.

14. An apparatus in accordance with claim 13 wherein said coolant gas recycle means provides inert gas as the vaporization product of said cryogenic liquid and said inert gas is recycled to said precooling means and said comminuting means from a discharge cyclone disposed downstream of said comminution means.

15. An apparatus in accordance with claim 13 comprising separating means, disposed downstream of said comminuting means and upstream of said heating means, for separating said rubber particle and said inert gas.

16. An apparatus in accordance with claim 11 comprising cooling fluid recycle means including a source of a cryogenic liquid introduced into said freezing means; a conduit for providing transport of said rubber particles between said freezing means and said comminuting means; a conduit for providing transport of said product of said comminuting means to said separating means; and a conduit providing inert gas communication between said separation means to both said precooling means and said comminuting means.

17. An apparatus in accordance with claim 11 wherein said drying means is a fluidized bed dryer heated by combustion gas in the range of between about 100° F. and about 200° F.

18. An apparatus in accordance with claim 11 wherein said precooling means is provided by a vertically disposed vessel provided with baffles into which an inert gas at a temperature in the range of between about 0° F. and about −20° F. is introduced.

19. An apparatus in accordance with claim 11 wherein said warming means is provided by a warmer wherein said comminuted rubber particles are warmed to ambient temperature.

20. An apparatus in accordance with claim 11 wherein said inert gas is gaseous nitrogen.

21. An apparatus in accordance with claim 11 wherein said freezing means includes contact of said precooled rubber particles with uniformly sprayed liquid nitrogen.

22. An apparatus for making powder rubber comprising:

(a) drying means for drying a feedstock of rubber particles in a size range of about −⅜ inch and about +40 mesh;

(b) precooling means for precooling said dried feedstock with a coolant inert gas recycle stream at a temperature in the range of between about 0° F. and about −20° F.;

(c) freezing means for cooling said precooled feedstock to a temperature below the gas transition temperature of said rubber particles by contact and exposure to liquid nitrogen;

(d) comminuting means for comminuting said cooled feedstock to a particle size no greater than about −80 mesh in the presence of a coolant at a temperature in the range of about −90° F. and about −125° F.;

(e) recycling means for recycling said gaseous nitrogen, vaporized from said liquid nitrogen in said freezing means, from said comminuting means back into said precooling means and said comminuting means;

(f) warming said comminuted feedstock exiting said comminuting means; and

(g) screening said comminuted feedstock into desired powder rubber size ranges.

23. An apparatus in accordance with claim 22 including liquid nitrogen introduction means for introducing liquid nitrogen into said comminuting means.

Assignments (8)