Direct epoxidation process using modifiers
View Patent ↗The invention is a process for epoxidizing an olefin with hydrogen and oxygen in the presence of a noble metal-containing titanium or vanadium zeolite and a modifier selected from the group consisting of carbon monoxide, methylacetylene, and propadiene. The process results in significantly reduced alkane by-product formed by the hydrogenation of olefin compared to processes that do not use the carbon monoxide, methylacetylene, and/or propadiene modifier.
1. A process for producing an epoxide comprising reacting an olefin, oxygen, and hydrogen in the presence of a noble metal-containing titanium or vanadium zeolite catalyst and a modifier selected from the group consisting of methylacetylene and propadiene.
2. The method of claim 1 wherein the noble metal-containing titanium or vanadium zeolite catalyst comprises titanium silicalite and palladium.
3. The method of claim 1 wherein the noble metal-containing titanium or vanadium zeolite catalyst comprises titanium silicalite, palladium, and one or more metals selected from the group consisting of gold and platinum.
4. The method of claim 1 wherein the noble metal-containing titanium or vanadium zeolite catalyst comprises a mixture of palladium-containing titanium or vanadium zeolite and palladium-free titanium or vanadium zeolite.
5. The process of claim 1 wherein the olefin is a C 2 –C 6 olefin.
6. The process of claim 1 wherein the olefin is propylene.
7. The process of claim 1 wherein the modifier is a mixture of methylacetylene and propadiene.
8. The process of claim 1 further comprising a solvent selected from the group consisting of oxygenated hydrocarbons, aromatic and aliphatic hydrocarbons, chlorinated aromatic and aliphatic hydrocarbons, supercritical CO 2 , and water.
9. The process of claim 1 further comprising a solvent selected from the group consisting of methanol, ethanol, isopropanol, and tert-butanol, and water.
10. A process for producing propylene oxide comprising reacting propylene, hydrogen and oxygen in a solvent in the presence of a palladium-containing titanium zeolite catalyst and a modifier selected from the group consisting of methylacetylene and propadiene.
11. The method of claim 10 wherein the palladium-containing titanium zeolite catalyst comprises titanium silicalite and palladium.
12. The method of claim 10 wherein the palladium-containing titanium zeolite catalyst comprises titanium silicalite, palladium, and one or more metals selected from the group consisting of gold and platinum.
13. The method of claim 10 wherein the palladium-containing titanium zeolite catalyst comprises a mixture of palladium-containing titanium zeolite and palladium-free titanium zeolite.
14. The process of claim 10 wherein the modifier is a mixture of methylacetylene and propadiene.
15. The process of claim 10 wherein the solvent is selected from the group consisting of oxygenated hydrocarbons, aromatic and aliphatic hydrocarbons, chlorinated aromatic and aliphatic hydrocarbons, supercritical CO 2 , and water.
16. The process of claim 10 wherein the solvent is selected from the group consisting of methanol, ethanol, isopropanol, tert-butanol, and water.