Coating liquid for recording layer and recording medium
View Patent ↗A coating liquid for a recording layer, containing fumed silica of a bulk density higher than 50 g/l and a specific surface area by the BET method equal to or higher than 250 m 2 /g, and a recording medium having a recording layer prepared with such coating liquid. The recording layer contains a water-soluble resin, which is preferably crosslinked.
1. A recording medium including a substrate and a recording layer, wherein the recording layer comprises a water-soluble polyvinyl alcohol resin and fumed silica having a bulk density of 60 g/l or more and a specific surface area by the BET method equal to or higher than 250 m 2 /g.
2. The recording medium according to claim 1 , wherein the fumed silica has a bulk density within a range of 60 to 80 g/l.
3. The recording medium according to claim 1 , wherein the fumed silica has a specific surface area by the BET method within a range of 300 to 400 m 2 /g.
4. The recording medium according to claim 1 , wherein the recording layer is an ink receptive layer for accepting an ink jet recording ink.
5. The recording medium according to claim 1 , wherein the content of the water-soluble resin in the recording layer is within a range of 9 to 40 mass % with respect to a solid content (by mass) of the recording layer.
6. The recording medium according to claim 1 , wherein the fumed silica (x) and the water-soluble resin (y) have a mass content ratio (PB ratio (x/y)) within a range of 1.5 to 10.
7. The recording medium according to claim 6 , wherein the fumed silica (x) and the water-soluble resin (y) have a mass content ratio (PB ratio (x/y)) within a range of 2 to 5.
8. The recording medium according to claim 1 , wherein the water-soluble resin is crosslinked.
9. The recording medium according to claim 8 , wherein the water-soluble resin is a polyvinyl alcohol resin and is crosslinked with a boron compound.
10. A process for producing the recording medium according to claim 1 , the process comprising:
coating a coating liquid for a recording layer on a substrate to form a coated layer, the coating liquid comprising at least fumed silica having a bulk density of 60 g/l or more and a specific surface area by the BET method of 250 m 2 /g or higher and a water-soluble resin, and
forming a recording layer by hardening through crosslinking of the coated layer,
wherein the hardening through crosslinking is executed by adding a crosslinking agent to the coating liquid for the recording layer and/or to a basic solution having a pH value of 7.1 or higher and by providing the coated layer with the basic solution either
(1) simultaneously with formation of the coated layer formed by coating of the coating liquid for the recording layer; or
(2) in the course of drying of the coated layer formed by coating the coating liquid for the recording layer and before the coated layer shows a decreasing drying rate.
11. The process for producing the recording medium according to claim 10 , wherein the water-soluble resin is a polyvinyl alcohol resin and the crosslinking agent is a boron compound.
12. The process for producing the recording medium according to claim 10 , wherein the recording layer is an ink receptive layer for accepting an ink jet recording ink.