IP Library Granted Patent US 7,419,725
Granted Patent B2
US 7,419,725 · App. 10/980,805 · Granted Sep 2, 2008

Coated article with low-E coating including IR reflecting layer(s) and corresponding method

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Quick Facts
Patent No.
US 7,419,725
App. No.
10/980,805
Granted
Sep 2, 2008
Kind
B2
Abstract

A coated article is provided with a low-emissivity (low-E) layer stack for use in a window unit or the like. The layer stack, or coating, may permit the coated article to achieve one or more of a low solar factor (SF) value, a high selectivity (T vis /SF) value, substantially neutral color at normal and/or off-axis viewing angles, and/or low emissivity. When high selectivity values are achieved, there is provided a high ratio of visible transmission to SF, which is a desirable feature in certain example instances. In certain example embodiments, asymmetric IR reflecting layer thicknesses may be used (e.g., bottom IR reflecting layer thicker than the top IR reflecting layer), and/or different contact layer for the top/bottom IR reflecting layers may be used to help achieve a combination of low SF values, high selectivity, and good coloration at normal and/or off-axis viewing angles.

Claims (89)

1. An insulating glass (IG) window unit including first and second glass substrates, and a coating supported by one of the substrates, the coating comprising:

first and second layers comprising silver with at least one dielectric layer therebetween, the first layer comprising silver being located between the glass substrate supporting the coating and the second layer comprising silver;

wherein a ratio (T first /T second ) of the thickness of the first layer comprising silver to the thickness of the second layer comprising silver is at least 1.05; and

wherein the IG window unit has a selectivity (T vis /SF) of at least 1.75, and/or a solar factor (SF) of no greater than 27.5.

2. The IG window unit of claim 1 , wherein the ratio of the thickness of the first layer comprising silver to the thickness of the second layer comprising silver is at least 1.10.

3. The IG window unit of claim 1 , wherein the ratio of the thickness of the first layer comprising silver to the thickness of the second layer comprising silver is at least 1.15.

4. The IG window unit of claim 1 , wherein the ratio of the thickness of the first layer comprising silver to the thickness of the second layer comprising silver is at least 1.17.

5. The IG window unit of claim 1 , wherein the coating includes only two infrared (IR) reflecting layers comprising silver.

6. The IG window unit of claim 1 , wherein the IG window unit has a selectivity of at least 1.80.

7. The IG window unit of claim 1 , wherein the IG window unit has a selectivity of at least 1.85.

8. The IG window unit of claim 1 , wherein the IG window unit has a selectivity of at least 1.90.

9. The IG window unit of claim 1 , wherein the IG window unit has a selectivity of at least 1.95.

10. The IG window unit of claim 1 , wherein the IG window unit has a SF of no greater than 27.0.

11. The IG window unit of claim 1 , wherein the IG window unit has a SF of no greater than 26.0.

12. The IG window unit of claim 1 , wherein the IG window unit has an outside reflective a* value, at a normal viewing angle, of from −4 to +2.

13. The IG window unit of claim 1 , wherein the IG window unit has an outside reflective a* value, at a normal viewing angle, of from −2.5 to +1.

14. The IG window unit of claim 1 , wherein the coating has a sheet resistance (R s ) of no greater than 3.0 ohms/square.

15. The IG window unit of claim 1 , wherein the coating has a sheet resistance (R s ) of no greater than 2.0 ohms/square.

16. The IG window unit of claim 1 , wherein the glass substrate supporting the coating is not heat treated with the coating thereon.

17. The IG window unit of claim 1 , wherein the IG window unit has a visible transmission of from about 35 to 65%.

18. The IG window unit of claim 1 , wherein the IG unit has an outside a* value which does not change by more than 3.5 given a viewing angle shift from 0 to 45 degrees.

19. The IG window unit of claim 1 , wherein the IG unit has an outside a* value which does not change by more than 2.5 given a viewing angle shift from 0 to 45 degrees.

20. The IG window unit of claim 1 , wherein outside reflective a* and b* of the IG window unit do not change by more than 3.5 given a viewing angle shift from 0 to 45 degrees.

21. The IG window unit of claim 1 , wherein the coating comprises at least the following layers from the substrate which supports the coating, outwardly:

a first dielectric layer;

a first contact layer;

said first layer comprising silver;

a second contact layer comprising Ni and/or Cr;

a second dielectric layer;

a third contact layer comprising zinc oxide;

said second layer comprising silver; and

a fourth contact layer; and

an overcoat layer.

22. The IG window unit of claim 21 , wherein the first and second contact layers are metallic, and the third and fourth contact layers each comprise a metal oxide.

23. The IG window unit of claim 21 , wherein one or both of the first and second contact layers is composed of metallic NiCr, and both of the third and fourth contact layers comprise a metal oxide.

24. The IG window unit of claim 23 , wherein the third contact layer comprises zinc oxide, and the fourth contact layer comprises an oxide of Ni and/or Cr.

25. The IG window unit of claim 21 , wherein each of the first and second contact layers are composed of metallic NiCr, the third contact layer comprises zinc oxide, and the fourth contact layer comprises an oxide of NiCr.

26. The IG window unit of claim 21 , wherein the overcoat layer comprises silicon nitride or zirconium oxide.

27. The IG window unit of claim 21 , further comprising a layer comprising tin oxide between the fourth contact layer and the overcoat layer.

28. The IG window unit of claim 21 , wherein the first dielectric layer comprises titanium oxide and/or silicon nitride.

29. The IG window unit of claim 21 , wherein the second dielectric layer comprises tin oxide and/or silicon nitride.

30. An insulating glass (IG) window unit comprising:

first and second glass substrates, and a coating supported by one of the substrates, the coating comprising:

first and second IR reflecting layers with at least one dielectric layer therebetween, the first IR reflecting layer being located between the glass substrate supporting the coating and the second IR reflecting layer;

a first contact layer located under and contacting the first IR reflecting layer, a second contact layer located over and contacting the first IR reflecting layer, a third contact layer located under and contacting the second IR reflecting layer, and a fourth contact layer located over and contacting the second IR reflecting layer;

wherein the third and/or fourth contact layer is more oxidized than is the first and/or second contact layer;

wherein the IG window unit has a selectivity (T vis /SF) of at least 1.75, and/or a solar factor (SF) of no greater than 27.5; and

wherein a ratio (T first /T second ) of the thickness of the first IR reflecting layer to the thickness of the second IR reflecting layer is at least 1.05.

31. The IG window unit of claim 30 , wherein the first and second contact layers are metallic, and the third and fourth contact layers each comprise a metal oxide.

32. The IG window unit of claim 30 , wherein the first and/or second contact layer is composed of NiCr, and the third and/or fourth contact layer is composed of an oxide of NiCr.

33. The IG window unit of claim 30 , wherein a ratio of the thickness of the first IR reflecting layer to the thickness of the second IR reflecting layer is at least 1.15.

34. The IG window unit of claim 30 , wherein each of the first and second IR reflecting layers comprises silver.

35. The IG window unit of claim 30 , wherein the coating includes only two infrared (IR) reflecting layers.

36. The IG window unit of claim 30 , wherein the IG window unit has a selectivity of at least 1.80.

37. The IG window unit of claim 30 , wherein the IG window unit has a selectivity of at least 1.85.

38. The IG window unit of claim 30 , wherein the IG window unit has a selectivity of at least 1.90.

39. The IG window unit of claim 30 , wherein the IG window unit has a SF of no greater than 27.0.

40. The IG window unit of claim 30 , wherein the IG window unit has a SF of no greater than 26.0.

41. The IG window unit of claim 30 , wherein the IG window unit has an outside reflective a* value, at a normal viewing angle, of from −3 to +2.

42. The IG window unit of claim 30 , wherein the IG window unit has an outside reflective a* value, at a normal viewing angle, of from −2.5 to +1.

43. The IG window unit of claim 30 , wherein the coating has a sheet resistance (R s ) of no greater than 3.0 ohms/square.

44. The IG window unit of claim 30 , wherein the glass substrate supporting the coating is not heat treated with the coating thereon.

45. The IG window unit of claim 30 , wherein the IG window unit has a visible transmission of from about 40 to 60%.

46. The IG window unit of claim 30 , wherein the IG unit has an outside a* value which does not change by more than 3.5 given a viewing angle shift from 0 to 45 degrees.

47. The IG window unit of claim 30 , wherein the IG unit has an outside a* value which does not change by more than 2.5 given a viewing angle shift from 0 to 45 degrees.

48. A coated article including a coated supported by the glass substrate, the coating comprising

first and second IR reflecting layers with at least one dielectric layer therebetween,

wherein the coated article is characterized by one or both of: a) a selectivity (T vis /SF) of at least 1.80, in combination with a solar factor (SF) of no greater than 27.5; and/or b) a ratio (T first /T second ) of the thickness of the first IR reflecting layer to the thickness of the second IR reflecting layer being at least 1.05; and

wherein a layer sequence comprising first, second and third layers respectively comprising titanium oxide, silicon nitride, and NiCr, is provided between the glass substrate and the lower of the first and second IR reflecting layers.

49. A coated article including a coated supported by the glass substrate, the coating comprising

first and second IR reflecting layers with at least one dielectric layer therebetween,

wherein the coated article is characterized by both of: a) a selectivity (T vis /SF) of at least 1.80, in combination with a solar factor (SF) of no greater than 27.5; and b) a ratio (T first /T second ) of the thickness of the first IR reflecting layer to the thickness of the second IR reflecting layer being at least 1.05.

50. The coated article of claim 49 , wherein the coated article has a visible transmission of from about 40-60%.

51. The coated article of claim 48 , wherein each of the IR reflecting layers comprises silver, and wherein the coating has only two IR reflecting layers comprising silver.

52. The coated article of claim 49 , wherein an outside or glass side reflective a* value of the coated article does not change by more than 3.5 given a viewing angle shift from 0 to 45 degrees.

53. The coated article of claim 48 , wherein the coated article has an outside reflective a* value, at a normal viewing angle, of from −2.5 to +1.

54. An insulating glass (IG) window unit including first and second glass substrates, and a coating supported by one of the substrates, the coating comprising:

first and second layers comprising silver with at least one dielectric layer therebetween, the first layer comprising silver being located between the glass substrate supporting the coating and the second layer comprising silver;

wherein a ratio (T first /T second ) of the thickness of the first layer comprising silver to the thickness of the second layer comprising silver is at least 1.05;

wherein the IG window unit has a visible transmission of from about 35 to 65%; and

wherein the IG window unit has a selectivity (T vis SF) of at least 1.90.

55. The IG window unit of claim 54 , wherein the IG window unit has a selectivity of at least 1.95.

56. An insulating glass (IG) window unit including first and second glass substrates, and a coating supported by one of the substrates, the coating comprising:

first and second layers comprising silver with at least one dielectric layer therebetween, the first layer comprising silver being located between the glass substrate supporting the coating and the second layer comprising silver;

wherein a ratio (T first /T second ) of the thickness of the first layer comprising silver to the thickness of the second layer comprising silver is at least 1.05;

wherein the IG window unit has a visible transmission of from about 35 to 65%; and

wherein the IG window unit has a SF of no greater than 27.0.

57. The IG window unit of claim 56 , wherein the IG window unit has an outside reflective a* value, at a normal viewing angle, of from −2.5 to +1.

58. The IG window unit of claim 21 , wherein one or both of the first and second contact layers is composed of metallic NiCr or a nitride of NiCr.

Assignments (6)
MERGER Recorded May 30, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
To: GUARDIAN EUROPE S.À R.L.
Reel/Frame 046834/0495 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NAME AND ADDRESS OF THE ASSIGNEE PREVIOUSLY RECORDED ON REEL 044900 FRAME 0321. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Feb 28, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
Reel/Frame 045870/0001 →
CHANGE OF NAME Recorded Dec 18, 2017
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À.R.L.
Reel/Frame 044900/0321 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 29, 2017
From: GUARDIAN INDUSTRIES CORP.
To: GUARDIAN GLASS, LLC.
Reel/Frame 044053/0318 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2004
From: NEUMAN, GEORGE
To: GUARDIAN INDUSTRIES CORP.
Reel/Frame 016260/0190 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2004
From: FERREIRA, JOSE; LEMMER, JEAN-MARC
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A. (C.R.V.C.)
Reel/Frame 016260/0193 →