Blowing gases in electroblowing process
View Patent ↗The present invention is directed to a method for preparing a nanofiber web by feeding a polymer solution, which has at least one polymer dissolved in at least one flammable solvent to a spinning nozzle, discharging the polymer solution from the spinning nozzle into a blowing gas or gas mixture that will not support combustion, wherein the blowing gas exits a jet at a lower end of the spinning nozzle, to form polymer nanofibers and collecting the polymer nanofibers on a collector under the spinning nozzle, wherein an applied high voltage differential is maintained between the spinneret and the collector.
1. A method for preparing a nanofiber web comprising
feeding a polymer solution, which comprises at least one polymer dissolved in at least one flammable solvent to a spinning nozzle;
discharging the polymer solution from the spinning nozzle, at a polymer solution discharge rate of from 0.1 to 5 mL/min-hole, into a blowing gas mixture, wherein the blowing gas exits a jet at a lower end of the spinning nozzle into a spinning region defined between the spinning nozzle and a collector, and contacts the polymer solution in the spinning region after it exits the spinning nozzle, to form polymer nanofibers, and wherein the blowing gas comprises one or more inert gases that do not support combustion; and
collecting the polymer nanofibers on the collector under the spinning nozzle, wherein an applied high voltage differential is maintained between the spinneret and the collector; and
wherein the concentrations of solvent vapor and oxygen at any point in the spinning region are such that the concentration of solvent vapor does not exceed the lower explosive limit of the solvent in the spinning region at that point.
2. The method of claim 1 , wherein the blowing gas is selected from the group of nitrogen, argon, helium, carbon dioxide, hydrocarbons, halocarbons, halohydrocarbons and mixtures thereof.
3. The method of claim 1 , wherein the polymer is selected from the group of polyimide, nylon, polyaramid, polybenzimidazole, polyetherimide, polyacrylonitrile, poly(ethylene terephthalate), polypropylene, polyaniline, poly(ethylene oxide), poly(ethylene naphthalate), poly(butylene terephthalate), styrene butadiene rubber, polystyrene, poly(vinyl chloride), poly(vinyl alcohol), poly(vinylidene fluoride), poly(vinyl butylene) and copolymer or derivative compounds thereof.
4. The method of claim 3 , wherein the flammable solvent is selected from the group of tetrahydrofuran, N-dimethylformamide, dimethylacetamide, acetone and methyl ethyl ketone.
5. The method of claim 1 , wherein a high voltage is applied to the spinning nozzle and is about 1 to about 300 kV.
6. The method of claim 1 , wherein a high voltage is applied to the collector and is about 1 to about 300 kV.
7. The method of claim 1 , wherein the polymer solution is compressively discharged through the spinning nozzle under a discharge pressure in the range of about 0.01 to about 200 kg/cm 2 .
8. The method of claim 1 , wherein the blowing gas is injected at a flow velocity of about 10 to about 10,000 m/min and a temperature from about ambient to about 300° C.
9. The method of claim 4 , wherein the blowing gas is injected at a temperature from about ambient to about 300° C.
10. The method of claim 1 , wherein the collector has a substrate disposed thereon for collecting the nanofibers deposited in the form of a web on the substrate.
11. The method of claim 2 , wherein the flow velocity of the blowing gas is adjusted to reduce the oxygen concentration in the spinning region surrounding the spinning nozzle/collector system to a level too low to support combustion of said solvent.