Radiation curable ink compositions and applications thereof
View Patent ↗Radiation curable ink compositions that include a curable component having a functionality that is greater than two, is present in the ink composition in an amount greater than 30 percent by weight, and has a molecular weight in the range of about 400 g/mole to about 10,000 g/mole; a component that has a functionality that is less than or equal to 2; and an initiator component. A solvent component, pigment, a surface tension modifier and other materials also can be included. The radiation curable inks are employed in ink jet printers and are particularly suited for use in printing on large-scale substrates. The printed images described herein have good adhesion to polymeric substrates such as styrene-based, polycarbonates, polyolefins, polyethylene terephthalate glycol ester, acrylic and others.
1. A radiation curable ink composition for ink jet printing, comprising:
a) a first curable component that is present in the ink composition in an amount greater than 30 weight percent, has a functionality that is greater than 2 and a molecular weight in the range of from about 400 g/mole to about 10,000 g/mole, wherein the first curable component includes any of: (1) a hyperbranched or a dendridic acrylate oligomer; or (2) a polyester tetraacrylate oligomer;
b) a second curable component that has a functionality that is less than or equal to 2; and
c) an initiator component.
2. The radiation curable ink composition of claim 1 , wherein the ink composition is UV curable.
3. The radiation curable ink composition of claim 1 , wherein the first curable component includes ethoxylated trimethylolpropane triacrylate.
4. The radiation curable ink composition of claim 3 , wherein ethoxylated trimethylolpropane triacrylate is present in the radiation curable ink composition in an amount of at least about 16 weight percent.
5. The radiation curable ink composition of claim 4 , wherein ethoxylated trimethylolpropane triacrylate is present in the radiation curable ink composition in an amount in the range of from about 22 to about 31 weight percent.
6. The radiation curable ink composition of claim 1 , wherein the first curable component includes a hyperbranched or dendridic acrylate oligomer that is present in the radiation curable ink composition in an amount of no more than 9 weight percent.
7. The radiation curable ink composition of claim 1 , wherein the first curable component has a viscosity greater than 50 centipoise at 25° Celsius.
8. The radiation curable ink composition of claim 1 , wherein the second curable component includes at least one monofunctional (meth)acrylate compound and at least one difunctional (meth)acrylate compound.
9. The radiation curable ink composition of claim 1 , wherein the second curable component includes ethoxylated (2) neopentylglycol diacrylate, propoxylated (2) neopentylglycol diacrylate, 1,4-cyclohaxanedimethanol diacrylate, tetrahydrofurfuryl acrylate, isobornyl acrylate, ethoxylated 1,6-hexanediol diacrylate, propoxylated-1,6-hexanediol diacrylate, dipropylene glycol diacrylate or any combination thereof.
10. The radiation curable ink composition of claim 1 , wherein the second curable component is present in the curable ink composition in an amount of less than about 70 weight percent.
11. The radiation curable ink composition of claim 10 , wherein the second curable component is present in the curable ink composition in an amount in the range of from about 45 to about 51 weight percent.
12. The radiation curable ink composition of claim 1 , wherein the record component has a viscosity that is less than 50 centipoise at 25° centigrade.
13. The radiation curable ink composition of claim 1 , wherein the initiator component includes at least one photoinitiator.
14. The radiation curable ink composition of claim 13 , wherein the initiator component includes bensophenone, bensoin ether, acylphosphine, or any combination thereof.
15. The radiation curable ink composition of claim 1 , wherein the initiator component is present in the curable ink composition in an amount in the range of from about 2 to about 20 weight percent.
16. The radiation curable ink composition of claim 15 , wherein the initiator component is present in the curable ink composition in an amount in the range of from about 7 to about 16 weight percent.
17. The radiation curable ink composition of claim 1 , further including a pigment.
18. The radiation curable ink composition of claim 17 , wherein the pigment is present in the radiation curable ink composition in an amount less than 10 weight percent.
19. The radiation curable ink composition of claim 1 , further comprising a solvent.
20. The radiation curable ink composition of claim 1 , further comprising a surface tension modifier.
21. The radiation curable ink composition of claim 20 , wherein the surface tension modifier is an organosilicon compound.
22. The radiation curable ink composition of claim 21 , wherein the organosilicon compound is a silicone acrylate.
23. The radiation curable ink composition of claim 22 , wherein the silicone acrylate is present in the radiation curable ink composition in an amount of at least 0.01 weight percent.
24. The radiation curable ink composition of claim 1 , wherein the radiation curable ink composition has a viscosity that is less than 25 centipoise at jet temperature.
25. The radiation curable ink composition of claim 24 , wherein the radiation curable ink composition has a viscosity in the range of from 10 to about 13 centipoise at a temperature in the range of from about 40° C. to about 58° C.
26. The radiation curable ink composition of claim 1 , wherein the radiation curable ink composition has a surface tension that is less than 30 dynes/cm 2 .
27. The radiation curable ink composition of claim 26 , wherein the radiation curable ink composition has a surface tension in the range of from about 25.5 to about 26.5 dynes/cm 2 .
28. A method for inkjet printing on a polymer-based substrate, the method comprising:
a) delivering a curable ink composition from an inkjet printer printhead onto the substrate, wherein the ink composition includes:
i. a first curable component that is present in the ink composition in an amount greater than 30 weight percent, has a functionality that is greater than 2 and a molecular weight in the range of from about 400 g/mole to about 10,000 g/mole, wherein the first curable component includes any of: (1) a hyperbranched or a dendridic acrylate oligomer; or (2) a polyester tetraacrylate oligomer;
ii. a second curable component that has a functionality that is less than or equal to 2; and
iii. an initiator component; and
b) exposing the ink composition to ultraviolet radiation, thereby curing the ink composition on said surface.
29. The method of claim 28 , wherein the ultraviolet radiation is provided by a lamp.
30. The method of claim 28 , wherein the curable ink composition is ejected from the printhead at a jet temperature in the range of from about 40° C. to about 58° C.
31. A printed display sign comprising:
a) a polymer-based substrate; and
b) a printed image adhered to said substrate, wherein the printed image is formed by curing an ink composition that includes:
i. a first curable component that is present in the ink composition in an amount greater than 30 weight percent, has a functionality that is greater than 2 and a molecular weight in the range of from about 400 g/mole to about 10,000 g/mole, wherein the first curable component includes any of: (1) a hyperbranched or a dendridic acrylate oligomer; or (2) a polyester tetraacrylate oligomer;
ii. a second curable component that has a functionality that is less than or equal to 2; and
iii. an initiator component, wherein the adhesion of the printed image to said substrate is at least 95 percent when measured by a standard cross-hatched tape test.
32. A printed display sign comprising:
a) a polymer-based substrate; and
b) a printed image adhered to said substrate, wherein the printed image is formed by curing an ink composition that includes:
i. a first curable component that is present in the ink composition in an amount greater than 30 weight percent, has a functionality that is greater than 2 and a molecular weight in the range of from about 400 g/mole to about 10,000 g/mole, wherein the first curable component includes any of: (1) a hyperbranched or a dendridic acrylate oligomer; or (2) a polyester tetraacrylate oligomer;
ii. a second curable component that has a functionality that is less than or equal to 2; and
iii. an initiator component, wherein the printed image has a hardness of at least HB on the pencil hardness scale.
33. A printed display sign comprising:
a) a polymer-based substrate; and
b) a printed image adhered to said substrate, wherein the printed image is formed by curing an ink composition that includes:
ii. a first curable component that is present in the ink composition in an amount greater than 30 weight percent, has a functionality that is greater than 2 and a molecular weight in the range of from about 400 g/mole to about 10,000 g/mole, wherein the first curable component includes: any of (1) a hyperbranched or a dendridic acrylate oligomer, or (2) a polyester tetraacrylate oligomer;
i. a second curable component that has a functionality that is less than or equal to 2; and
iii. an initiator component, wherein the printed image has a water resistance recover of less than 5 minutes.