IP Library Granted Patent US 9,560,847
Granted Patent B2
US 9,560,847 · App. 10/990,995 · Granted Feb 7, 2017

Stable matrix emulsion concentrates and stable aqueous and/or organic solvent compositions containing biocides

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Quick Facts
Patent No.
US 9,560,847
App. No.
10/990,995
Granted
Feb 7, 2017
Kind
B2
Abstract

A stable matrix emulsion concentrate of a biocide, e.g. 3-iodopropynyl-2-butyl carbamate (IPBC) and/or a triazole fungicide, and stable aqueous and/or organic solvent formulations thereof, i.e. dilutable in water and/or an organic solvent are provided, which are particularly useful for treating wood products to provide protection against microorganisms and insects.

Claims (18)

1. A stable microemulsion concentrate comprising, by weight,

(a) 1-40% of a biocide selected from iodopropargyl butyl carbamate, or the combination of iodopropargyl butyl carbamate and propiconazole,

(b) a matrix of:

(i) 0-30% of a C 1 -C 4 N-alkyl pyrrolidone,

(ii) 0.5-30% of a C 8 -C 14 N-alkyl pyrrolidone,

(iii) 4-85% of castor oil ethoxylate,

(iv) 0.5-20% of an ethylene oxide/propylene oxide copolymer, and

(v) 0.05-5% of an ethoxylated phosphate ester, and

(c) an organic solvent as diluent wherein said organic solvent is propylene carbonate.

2. A stable microemulsion concentrate according to claim 1 wherein (c) is present in an amount of 10-60% by weight of the diluted concentrate.

3. A stable microemulsion concentrate according to claim 2 wherein (a) is about 15-30%.

4. A stable microemulsion concentrate according to claim 1 wherein (b) (ii) is about 10-20%.

5. A stable microemulsion concentrate according to claim 1 wherein (b) (iii) contains 30 EO units; and (b) (v) contains 9-10 EO units.

6. A concentrate according to claim 1 which includes a quat.

7. A stable microemulsion composition including the microemulsion concentrate of claim 1 and water and/or an organic solvent of dilution.

8. A stable aqueous microemulsion composition according to claim 7 which is diluted with water and/or organic solvent at a concentration of 1 part of emulsion concentrate to 20-1000 parts of water and/or organic solvent of dilution.

9. A composition of claim 7 which includes about 100-5000 ppm of biocide.

10. A composition according to claim 7 which also includes a quat.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Jan 10, 2020
From: THE BANK OF NOVA SCOTIA
To: AVOCA LLC; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES LLC
Reel/Frame 051557/0504 →
SECURITY AGREEMENT Recorded Jul 3, 2017
From: AVOCA, INC.; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES, INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 043084/0753 →
CHANGE OF NAME Recorded Dec 22, 2016
From: ISP INVESTMENTS INC.
To: ISP INVESTMENTS LLC
Reel/Frame 041208/0817 →
RELEASE OF PATENT SECURITY AGREEMENT Recorded Mar 18, 2013
From: THE BANK OF NOVA SCOTIA
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; ISP INVESTMENTS INC.; HERCULES INCORPORATED
Reel/Frame 030025/0320 →
PATENT RELEASE Recorded Sep 19, 2011
From: JPMORGAN CHASE BANK, N.A. (F/K/A THE CHASE MANHATTAN BANK)
To: ISP CAPITAL, INC.; ISP CHEMICAL PRODUCTS, INC.; VERONA, INC.
Reel/Frame 026930/0774 →
SECURITY AGREEMENT Recorded Sep 16, 2011
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; HERCULES INCORPORATED; AQUALON COMPANY; ISP INVESTMENT INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 026918/0052 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 17, 2004
From: NARAYANAN, KOLAZI S.; LIU, XIANBIN; WINKOWSKI, KAEN; PATEL, JAYANTI
To: ISP INVESTMENTS INC.
Reel/Frame 016009/0384 →