IP Library Granted Patent US 7,867,605
Granted Patent B2
US 7,867,605 · App. 10/991,565 · Granted Jan 11, 2011

Intrusion resistant glass laminates

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Quick Facts
Patent No.
US 7,867,605
App. No.
10/991,565
Granted
Jan 11, 2011
Kind
B2
Abstract

Composite laminate interlayers for adhering a glass laminate comprising two sheets of polyethylene terephthalate (PET) between layers of plasticized polyvinyl butyral (PVB) adhesive layers, wherein the two PET layers provide increased stiffness for the laminate without sacrificing the optical clarity of the laminate.

Claims (30)

1. A composite laminate interlayer for a glass laminate, comprising:

two sheets of biaxially stretched polyethylene terephthalate bonded together with adhesive between two layers of plasticized polyvinyl butyral;

wherein the thickness of each biaxially stretched polyethylene terephthalate sheet is between 0.025 mm and 0.175 mm and the thickness of each plasticized polyvinyl butyral layer is between 0.1 mm and 2 mm; and

wherein the composite interlayer has less optical haze than a composite interlayer formed from a single sheet of polyethylene terephthalate having the same thickness as the two sheets of bonded biaxially stretched polyethylene terephthalate in combination.

2. The interlayer of claim 1 , wherein each biaxially stretched polyethylene terephthalate sheet has a different thickness.

3. The interlayer of claim 1 , wherein each biaxially stretched polyethylene terephthalate sheet has the same thickness.

4. The interlayer of claim 1 , wherein the thickness of each biaxially stretched polyethylene terephthalate sheet is about 0.175 mm.

5. The interlayer of claim 4 , wherein the thickness of said two sheets of biaxially stretched polyethylene terephthalate bonded together with adhesive is about 0.350 mm.

6. The interlayer of claim 1 , wherein the thickness of each plasticized polyvinyl butyral layer is 0.375 mm to 1.5 mm.

7. The interlayer of claim 1 , wherein each of said two sheets of biaxially stretched polyethylene terephthalate has a haze of less than 1%.

8. The interlayer of claim 1 , wherein said sheets of biaxially stretched polyethylene terephthalate are bonded with a pressure sensitive acrylic resin.

9. The interlayer of claim 1 , wherein one of said layers of plasticized polyvinyl butyral has a glass transition temperature of at least 35° C.

10. A glass laminate, comprising, in order:

a first pane of glass;

a first polyvinyl butyral layer;

two sheets of biaxially stretched polyethylene terephthalate bonded together with adhesive;

a second polyvinyl butyral layer; and, a second pane of glass;

wherein the thickness of each biaxially stretched polyethylene terephthalate sheet is between 0.025 mm and 0.175 mm and the thickness of each plasticized polyvinyl butyral layer is between 0.1 mm and 2 mm; and

wherein the composite interlayer has less optical haze than a composite interlayer formed from a single sheet of polyethylene terephthalate having the same thickness as the two sheets of bonded biaxially stretched polyethylene terephthalate in combination.

11. The laminate of claim 10 , wherein each biaxially stretched polyethylene terephthalate sheet has a different thickness.

12. The laminate of claim 10 , wherein each biaxially stretched polyethylene terephthalate sheet has the same thickness.

13. The laminate of claim 10 , wherein the thickness of each biaxially stretched polyethylene terephthalate sheet is about 0.175 mm.

14. The laminate of claim 13 , wherein the thickness of said two sheets of biaxially stretched polyethylene terephthalate bonded together with adhesive is about 0.350 mm.

15. The laminate of claim 10 , wherein the thickness of each plasticized polyvinyl butyral layer is 0.375 mm to 1.5 mm.

16. The laminate of claim 10 , wherein each of said two sheets of biaxially stretched polyethylene terephthalate has a haze of less than 1%.

17. The laminate of claim 10 , wherein said sheets of biaxially stretched polyethylene terephthalate are bonded with a pressure sensitive acrylic resin.

18. The laminate of claim 10 , wherein one of said layers of plasticized polyvinyl butyral has a glass transition temperature of at least 35° C.

19. A composite laminate interlayer for a glass laminate, comprising two sheets of biaxially stretched polyethylene terephthalate bonded together with pressure sensitive acrylic resin between two layers of plasticized polyvinyl butyral;

wherein the thickness of each biaxially stretched polyethylene terephthalate sheet is between 0.025 mm and 0.25 mm, the thickness of each plasticized polyvinyl butyral layer is about 0.76 mm, the total thickness of the two sheets of biaxially stretched polyethylene terephthalate bonded together with pressure sensitive acrylic resin is 0.350 mm; and

wherein the composite interlayer has less optical haze than a composite interlayer formed from a single sheet of polyethylene terephthalate having the same thickness as the two sheets of bonded biaxially stretched polyethylene terephthalate in combination.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Jul 17, 2012
From: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 028563/0241 →
SECURITY AGREEMENT Recorded May 17, 2010
From: SOLUTIA INC.; CP FILMS INC.; FLEXSYS AMERICA L.P.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 024390/0281 →
RELEASE OF TERM LOAN SECURITY INTEREST IN PATENTS - REEL/FRAME 022610/0697 Recorded Mar 30, 2010
From: CITIBANK, N.A.
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 024151/0513 →
RELEASE OF ABL SECURITY INTEREST IN PATENTS - REEL/FRAME 022610/0495 Recorded Mar 30, 2010
From: CITIBANK, N.A.
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 024151/0469 →
ABL PATENT SECURITY AGREEMENT Recorded Apr 29, 2009
From: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
To: CITIBANK, N.A.
Reel/Frame 022610/0495 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Apr 29, 2009
From: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
To: CITIBANK, N.A.
Reel/Frame 022610/0697 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 23, 2006
From: MORAN, JAMES R; LU, JUN
To: SOLUTIA INC.
Reel/Frame 017832/0277 →