Process for preparing adhesive using planetary extruder
View Patent ↗A process for preparing a pressure sensitive adhesive using a modified planetary roller extruder is described. The process in accordance with one aspect of the invention includes introducing primary raw materials including a non-thermoplastic elastomer into a feeding section of the modified planetary roller extruder, conveying the raw materials from the feeding section to a compounding section of the modified planetary roller extruder, continuously mixing the primary raw materials in the compounding section to produce a homogeneous adhesive composition. The adhesive composition may be applied to a web-form material. The compounding section of the modified planetary roller extruder includes a main spindle surrounded by and intermeshed with a plurality of planetary spindles at least one of which is a double transversal mixing spindle having a plurality of back-cut helical flights.
1. A process for preparing an adhesive, the process comprising the steps of:
a.) introducing primary raw materials comprising a non-thermoplastic elastomer into a feeding section of a planetary roller extruder;
b.) conveying the primary raw materials from the feeding section to a compounding section of the planetary roller extruder;
c.) mixing the primary raw materials in the compounding section, wherein the compounding section comprises a main spindle surrounded by and intermeshed with a plurality of planetary spindles wherein at least one of the planetary spindles is a double transversal mixing spindle comprising a plurality of back-cut helical flights;
d.) producing a homogeneous adhesive composition; and
e.) applying the adhesive composition to a web-form material.
2. The process of claim 1 wherein the compounding section comprises from 3 to 24 planetary spindles.
3. The process of claim 1 wherein the compounding section further comprises planetary spindles having full helical flights.
4. The process of claim 3 wherein the double transversal mixing spindles account for more than 20 percent of the total number of planetary spindles in the compounding section.
5. The process of claim 4 wherein the compounding section comprises twice as many double transversal spindles as spindles having full helical flights.
6. The process of claim 1 further comprising adding secondary raw materials to the compounding section.
7. The process of claim 6 wherein the secondary raw materials comprise solid raw materials selected from the group consisting of thermoplastic elastomers, tackifying resins, extenders, activators, crosslinkers, colorants, and mixtures thereof.
8. The process of claim 6 wherein the secondary raw materials comprise liquid raw materials selected from the group consisting of liquid elastomers, molten resins, oils, solvents and mixtures thereof.
9. The process of claim 8 wherein the solvent is selected from the group consisting of acetone, toluene, hexane, heptane, and mixtures thereof.
10. The process of claim 1 wherein the compounding section comprises a plurality of roller barrel sections.
11. The process of claim 10 wherein each barrel section comprises a double transversal spindle.
12. The process of claim 1 wherein the primary raw materials comprise natural rubber and tackifying resin.
13. The process of claim 11 wherein the primary raw materials further comprise an activator selected from the group consisting of zinc oxide, magnesium oxide and combinations thereof and an extender selected from the group consisting of clays, calcium carbonate, talc, aluminum hydrates and combinations thereof.
14. The process of claim 1 wherein the elastomer is masticated such that M w is reduced to less than 1,000,000 as measured by GPC.
15. The process of claim 1 wherein the non-thermoplastic elastomer is selected from the group consisting of natural rubber, synthetic polyisoprene, styrene butadiene rubber, butyl rubber, polyisobutylene rubber, and combinations thereof.
16. The process of claim 1 wherein the step of applying the adhesive composition to a web-form material comprises a coating process selected from the group consisting of slot-die coating, reverse roll, roll-over-roll coating and knife-over-roll coating.
17. The process of claim 16 wherein the coating process comprises slot-die coating using a rotating lip die or a fixed lip contact die.
18. The process of claim 1 further comprising:
f.) crosslinking the adhesive composition.
19. The process of claim 18 wherein step f comprises crosslinking the adhesive composition using a process selected from the group consisting of EB crosslinking, UV crosslinking, thermal and/or chemical crosslinking and combinations thereof.
20. The process of claim 1 wherein the non-thermoplastic elastomer has an initial molecular weight (M w(initial) ) befor processing and a final molecular weight (M w(final) ) after processing and said non-thermoplastic elastomer exibits a % reuction in M w of more than about 50% as caculated in accordance with Formular I:
%Reduction=( M w(initial) −M w(final) ) /M w(initial) ×100 (I).
21. A process for producing an adhesive composition comprising:
a.) continuously metering into a planetary roller extruder primary raw materials of an adhesive composition comprising a non-thermoplastic elastomer and a tackifying resin;
b.) continuously mixing the primary raw materials in a compounding section of the planetary roller extruder to form a homogeneous adhesive composition wherein the compounding section comprises a main spindle surrounded by and intermeshed with a plurality of planetary spindles wherein at least one of the planetary spindles is a double transversal mixing spindle comprising a plurality of back-cut helical flights; and
c.) continuously discharging the homogeneous adhesive composition from the extruder.
22. The process of claim 21 wherein the non-thermoplastic elastomer is selected from the group consisting of natural rubber, synthetic polyisoprene, styrene butadiene rubber, butyl rubber, polyisobutylene rubber, and combinations thereof.
23. The process of claim 22 wherein the non-thermoplastic elastomer comprises pre-masticated natural rubber.
24. The process of claim 21 wherein the compounding sections comprises a plurality of roller barrel sections.
25. The process of claim 24 wherein each roller barrel section comprises at least one double transversal mixing spindle.
26. The process of claim 21 further comprising adding solvent to the raw materials in the compounding section.
27. The process of claim 21 further comprising:
d.) applying the adhesive composition to a web-form material.
28. The process of claim 27 wherein the adhesive composition is applied to the web-form material using a coating process selected from the group consisting of slot-die coating, reverse roll, roll-over-roll coating and knife-over-roll coating.
29. The process of claim 27 wherein the web-form material selected from the group consisting of paper, polyethylene, polypropylene, polyester, polyvinylchloride and combinations thereof.
30. The process of claim 29 further comprising crossliniking the adhesive composition.
31. The process of claim 21 further comprising adding secondary raw materials to the compounding section.
32. The process of claim 31 wherein the secondary raw materials comprise solid materials.
33. The process of claim 32 wherein the solid materials are selected from the group consisting of thermoplastic elastomers, resins, extenders, activators, anti-degradents, crosslinkers and mixtures thereof.
34. The process of claim 32 wherein the compounding section further comprises a twin screw dosing unit and the solid materials are added to the compounding section via the twin screw dosing unit.