Polymer ceramic slip and method of manufacturing ceramic green bodies there therefrom
A polymer slip for producing a ceramic body is disclosed. The slip includes a polymer, surfactant, dispersant and about 50-70 volume % ceramic powder. The slip can be set in a closed mold. In another embodiment, the present invention relates to a method of manufacturing a green body. The method includes contacting a ceramic powder with a polymer to form a slip mixture, mixing the slip mixture, injecting the slip mixture in a mold and setting the mixture in the mold at a temperature of about 20-40° C. The slip mixture comprises about 50-65 volume % of the ceramic powder.
1 . A polymer slip for producing a ceramic green body, comprising polymer, surfactant, dispersant and about 50-70 volume % ceramic powder, wherein said slip can be set in a mold.
2 . The slip of claim 1 , wherein said mold is a closed mold.
3 . The slip of claim 1 , wherein said slip can be set in a mold at a temperature of about 20-40° C.
4 . The slip of claim 1 , wherein said slip is solvent free.
5 . The slip of claim 1 , wherein said slip has substantially no shrinkage upon setting.
6 . The slip of claim 5 , wherein said slip has substantially no distortion upon setting.
7 . The slip of claim 1 , wherein said slip can be injection molded at pressures of about 5-100 p.s.i.
8 . The slip of claim 7 , wherein said slip can be injection molded at a temperature of about 20-40° C.
9 . The slip of claim 1 , wherein said slip has viscosity of about 1000-2000 centipoise (cps)
10 . The slip of claim 1 , wherein said slip can be molded to form net shaped green bodies having microsized features.
11 . The slip of claim 10 , wherein said microsized features are rectangular-shaped features and have height of about 325-350 μm, widths of about 35-45 μm and center-to-center spacing between features of about 45-55 μm.
12 . The slip of claim 1 , wherein said polymer is epoxy, polyurethane, polyester or silicone.
13 . The slip of claim 12 , wherein said polymer is a two-part epoxy polymer.
14 . The slip of claim 1 , comprising about 1-5 wt % of said polymer.
15 . The slip of claim 1 , where said ceramic powder is piezoelectric ceramic powder.
16 . The slip of claim 1 , wherein said ceramic powder is selected from the group consisting of lead zirconate titanate (PZT), lead niobium titanate (PNT), lead scandium niobium titanate (PSNT) and mixtures thereof.
17 . The slip of claim 15 , wherein said ceramic powder has mean particle size of about 0.05-6 μm.
18 . A polymer slip for producing a ceramic green body, comprising about 2-5 wt % polymer, about 1-3 wt % dispersant, about 0.1-1.0 wt % surfactant and about 90-95 wt % piezoelectric ceramic powder, wherein said slip can be set in a closed mold at a temperature of about 20-40° C. and said slip has substantially no shrinkage upon setting.
19 . The slip of claim 18 , wherein said ceramic green body is net shaped ceramic green body having microsized features.
20 . The slip of claim 18 , wherein said slip can be injection molded at a temperature of about 20-40° C. and a pressure of about 5-100 p.s.i.
21 . A method of manufacturing a net-shaped ceramic green body having microsized elements, comprising:
contacting a ceramic powder with a polymer and surfactant to form a slip mixture;
mixing said slip mixture;
injecting said slip mixture in a mold; and
setting said mixture in said mold;
wherein said slip mixture comprises about 50-70 volume % of said ceramic powder.
22 . The method of claim 21 , wherein said mold is a closed mold.
23 . The method of claim 21 , wherein said slip mixture has substantially no shrinkage upon setting in said mold.
24 . The method of claim 21 , wherein said slip mixture further comprises dispersant.
25 . The method of claim 21 , wherein said ceramic powder is piezoelectric ceramic powder.
26 . The method of claim 25 , wherein said piezoelectric ceramic powder is selected from the group consisting of lead zirconate titanate (PZT), lead niobium titanate (PNT), lead scandium niobium titanate (PSNT) and mixtures thereof.
27 . The method of claim 25 , wherein said piezoelectric ceramic powder has mean particle size of about 0.05-6 μm.
28 . The method of claim 21 , wherein said injecting step comprises:
injecting said slip mixture in a closed mold at a pressure of about 5-100 p.s.i.
29 . The method of claim 28 , wherein said injecting step further comprises:
injecting said slip mixture in a closed mold at a temperature of about 20-40° C.
30 . The method of claim 21 , wherein said setting step comprises:
setting said mixture in said closed mold at a temperature of about 20-40° C.
31 . The method of claim 21 , wherein said microsized elements are rectangular-shaped features and have height of about 325-350 μm, widths of about 35-45 μm and center-to-center spacing between features of about 45-55 μm.
32 . The method of claim 21 , wherein said microsized elements form a square array of elements having 532 features on the width and length.
33 . The method of claim 21 , wherein said closed mold is a silicone mold.
34 . The method of claim 21 , further comprising after said step of setting said mixture:
curing said mixture in said closed mold at a temperature of about 40-80 oc.
35 . A ceramic green body produced by the process of claim 21 .
36 . The green body of claim 35 , comprising a plurality of sensing elements having height of about 250-350 μm, width of about 40-50 μm and about 10 degrees in pitch.
37 . The green body of claim 36 , wherein said plurality of sensing elements are circular or rectangular sensing elements.
38 . A net-shaped ceramic green body having microsized features comprising surfactant, dispersant, polymer and about 50-70 vol % piezoelectric ceramic powder.
39 . The green body of claim 38 , comprising about 1-5 wt % polymer.
40 . The green body of claim 38 , wherein said polymer is epoxy polymer.
41 . The green body of claim 38 , wherein said microsized features are rectangular or circular sensing elements having height of about 250-350 μm, width of about 40-50 μm and center-to-center distance between the elements of about 50-150 μm.
42 . A two-part ceramic slip, comprising:
a first part comprising about 1-4 wt % epoxy part A, about 1-4 wt. % dispersant, about 0.1-0.3 wt. % surfactant and about 90-95 wt. % piezoelectric ceramic powder; and
a second part comprising about 1-4 wt % epoxy part B, about 1-4 wt. % dispersant, about 0.1-0.4 wt. % surfactant and about 90-95 wt. % piezoelectric ceramic powder;
whereby said first and second parts are stored separately prior to mixing to form a polymer ceramic slip mixture.