IP Library Granted Patent US 39,676
Granted Patent E1
US 39,676 · App. 10/998,354 · Granted Jun 5, 2007

Flexible thin layer open electrochemical cell

Assignee: Power Paper Ltd.
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Quick Facts
Patent No.
US 39,676
App. No.
10/998,354
Granted
Jun 5, 2007
Kind
E1
Abstract

A flexible thin layer open liquid state electrochemical cell which can be used as a primary or rechargeable power supply for various miniaturized and portable electrically powered devices of compact design. The cell includes a wet electrolyte, yet maintains a fexible, thin and open configuration, thus devoid of accumulation of gases upon storage. The cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, the third layer being disposed between the first and second layers and including a deliquescent material for keeping the open cell wet at all times; an electroactive soluble material for obtaining required ionic conductivity; and, a watersoluble polymer for obtaining a required viscosity for adhering the first and second layers to the third layer. The electrochemical cell of the present invention is preferably produced using a suitable printing technology.

Claims (75)

1. A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layer and including:

(a) a deliquescent material for keeping the open cell wet at all times;

(b) an electroactive soluble material for obtaining required ionic conductivity; and

(c) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer.

2. A cell as in claim 1 , wherein said first layer of insoluble positive pole includes manganese-dioxide powder and said second layer of insoluble negative pole includes zinc powder.

3. A cell as in claim 2 , wherein A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer; wherein said first layer of insoluble negative pole includes zinc powder, said second layer of insoluble positive pole includes manganese - dioxide powder, and said electroactive soluble material is selected from the group consisting of zinc-chloride, zinc-bromide, zinc-fluoride and potassium-hydroxide.

4. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , wherein said first layer of insoluble negative pole includes silver-oxide powder zinc powder and said second layer of insoluble positive pole includes zinc powder silver- oxide powder.

5. A cell as in claim 4 , wherein said electroactive soluble material is potassium-hydroxide.

6. A cell as in claim 1 A flexible thin layer open liquid state electrochemial cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , wherein said first layer of insoluble negative pole includes cadmium powder and said second layer of insoluble positive pole includes nickel-oxide powder.

7. A cell as in claim 6 , wherein said electroactive soluble material is potassium-hydroxide.

8. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , wherein said first layer of insoluble negative pole includes iron powder and said second layer of insoluble positive pole includes nickel-oxide powder.

9. A cell as in claim 8 , wherein said electroactive soluble material is potassium-hydroxide.

10. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , wherein said first layer of insoluble negative pole and said second layer of insoluble positive pole include lead-oxide powder, the cell is charged by voltage applied to said poles.

11. A cell as in claim 10 , wherein said electroactive soluble material is sulfuric-acid.

12. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , wherein said deliquescent material and said electroactive soluble material are the same material.

13. A cell as in claim 12 , wherein said same material is selected from the group consisting of zinc-chloride, zinc-bromide, zinc-fluoride and potassium-hydroxide.

14. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , wherein said deliquescent material is selected from the group consisting of calcium-chloride, calcium-bromide, potassium-biphosphate and potassium-acetate.

15. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , wherein said watersoluble polymer is selected from the group consisting of polyvinylalcohol, polyacrylamide, polyacrylic acid, polyvinylpyrolidone, polyethylenoxide, agar, agarose, starch, hydroxyethylcellulose and combinations and copolymers thereof.

16. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , wherein said watersoluble polymer and said deliquescent material are the same material.

17. A cell as in claim 1 16 , wherein said same material is selected from the group consisting of dextrane, dextranesulfate and combinations and copolymers thereof.

18. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , further comprising terminals, each of said terminals being in electrical contact with one of said first and second pole layers.

19. A cell as in claim 18 , wherein said terminal terminals are made of graphite.

20. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , further comprising at least one conductive layer improving the electronic conductivity of at least one of said first and second pole layers.

21. A cell as in claim 20 , wherein said conductive layer is selected from the group consisting of a graphite paper and carbon cloth.

22. A cell as in claim 1 A flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer , further comprising an external layer selected from the group consisting of an adhesive backing layer, a lamina protective layer and a combination of adhesive backing layer and a lamina protective layer.

23. An electrical power supply comprising two cells as in claim 1 being connected in a head to tail orientation in a bipolar-connection wherein the cells are each a flexible thin layer open liquid state electrochemical cell comprising a first layer of insoluble negative pole, a second layer of insoluble positive pole and a third layer of aqueous electrolyte, said third layer being disposed between said first and second layers and including:

( a ) a deliquescent material for keeping the open cell wet at all times;

( b ) an electroactive soluble material for obtaining required ionic conductivity; and

( c ) a watersoluble polymer for obtaining a required viscosity for adhering said first and second layers to said third layer.

24. An electrical power supply as in claim 23 , wherein said connection is by an adhesive selected from the group consisting of a conductive double sided adhesive tape and a conductive glue layer.

25. An electrical power supply as in claim 24 , wherein said conductive double sided adhesive tape and said conductive glue layer are applied by a printing technology.

26. A method of making a flexible thin layer open liquid state electrochemical cell comprising the steps of:

(a) wetting a porous substance having a first side and a second side with an aqueous solution containing a deliquescent material, an electroactive soluble material and a watersoluble polymer;

(b) applying onto said first side a layer of negative pole; and

(c) applying onto said second side a layer of positive pole.

27. A method as in claim 26 , wherein said wetting is by a dipping technology.

28. A method as in claim 26 , wherein said wetting is by a printing technology.

29. A method as in claim 26 , wherein said layers of negative and positive poles include active insoluble powder materials mixed with said deliquescent material, electroactive soluble material and watersoluble polymer.

30. A method as in claim 26 , wherein said application of said layers of negative and positive poles is by a printing technology.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 28, 2013
From: POWER PAPER LTD
To: POWER FLEX LTD.
Reel/Frame 031691/0307 →
RELEASE OF SECURITY INTEREST Recorded Jun 16, 2013
From: KREOS CAPITAL III LIMITED
To: POWER PAPER LTD. (IN LIQUIDATION)
Reel/Frame 030619/0834 →
SECURITY AGREEMENT Recorded Oct 13, 2009
From: POWER PAPER LTD.
To: KREOS CAPITAL III LIMITED
Reel/Frame 023355/0791 →
Continuity (2)
Reissue 0883137900 · Apr 1, 1997
Continuation 0857519000 · Dec 20, 1995