Polymer/cholesteric liquid crystal dispersion, method of producing the same liquid crystal display element using the same
A polymer/cholesteric liquid crystal dispersion including a cholesteric liquid crystal dispersed in a polymer. A perpendicular aligning component that aligns the cholesteric liquid crystal in a direction perpendicular to the boundary between the cholesteric liquid crystal and the polymer is provided at least one of at the boundary between the cholesteric liquid crystal and the polymer and in the polymer.
1. A cholesteric liquid crystal dispersion comprising a cholesteric liquid crystal dispersed in a polymer, wherein a perpendicular aligning component that aligns the cholesteric liquid crystal in a direction perpendicular to a boundary between the cholesteric liquid crystal and the polymer is provided at least one of at the boundary between the cholesteric liquid crystal and the polymer and in the polymer.
2. The cholesteric liquid crystal dispersion of claim 1 , wherein the perpendicular aligning component comprises at least one selected from the group consisting of a fluorine atom, a silicon atom, an alkyl group and an alkyl halide group.
3. The cholesteric liquid crystal dispersion of claim 1 , wherein the perpendicular aligning component is contained in the at least one of the boundary between the cholesteric liquid crystal and the polymer in an amount of approximately 0.1% by weight or more based on the total weight of the polymer and the perpendicular aligning component.
4. The cholesteric liquid crystal dispersion of claim 2 , wherein the perpendicular aligning component is contained in the at least one of the boundary between the cholesteric liquid crystal and the polymer in an amount of approximately 0.1% by weight or more based on the total weight of the polymer and the perpendicular aligning component.
5. The cholesteric liquid crystal dispersion of claim 4 , wherein the perpendicular aligning component comprises an alkyl fluoride group.
6. The cholesteric liquid crystal dispersion of claim 1 , wherein the perpendicular aligning component is provided in a main chain or a side chain of the polymer.
7. The cholesteric liquid crystal dispersion of claim 1 , wherein the perpendicular aligning component is mixed in the polymer.
8. The cholesteric liquid crystal dispersion of claim 1 , wherein the perpendicular aligning component is a surfactant comprising a hydrophilic group and a hydrophobic group.
9. The cholesteric liquid crystal dispersion of claim 8 , wherein the hydrophobic group comprises at least one selected from an alkyl group and an alkyl halide group.
10. The cholesteric liquid crystal dispersion of claim 9 , wherein the perpendicular aligning component comprises an alkyl fluoride group.
11. The cholesteric liquid crystal dispersion of claim 1 , wherein the cholesteric liquid crystal is microcapsulated by using the polymer as a wall material.
12. The cholesteric liquid crystal dispersion of claim 1 , wherein the polymer is polymerized with a polyvalent isocyanate, and at least one selected from an alkyl group and an alkyl halide group is introduced to the polymer as the perpendicular aligning component.
13. The cholesteric liquid crystal dispersion of claim 12 , wherein the perpendicular aligning component comprises an alkyl fluoride group.
14. The cholesteric liquid crystal dispersion of claim 1 , wherein the polymer is copolymerized with a polyvalent isocyanate and a polyvalent amine, and at least one selected from an alkyl group and an alkyl halide group is introduced to the polymer as the perpendicular aligning component.
15. The cholesteric liquid crystal dispersion of claim 14 , wherein the perpendicular aligning component comprises an alkyl fluoride group.
16. A method of producing a cholesteric liquid crystal dispersion, the method comprising:
dispersing in water a mixed solution of a cholesteric liquid crystal, a polyvalent isocyanate, a perpendicular aligning component precursor comprising, in a molecule, a functional group which causes an addition reaction with the polyvalent isocyanate and at least one selected from an alkyl group and an alkyl halide group; and
polymerizing the polyvalent isocyanate to form a polymer so as to microcapsulate the cholesteric liquid crystal by using the polymer as a wall material.
17. The method of claim 16 , wherein, in the polymerizing of the polyvalent isocyanate, a polyvalent amine is added in the water to cause interfacial polymerization between the polyvalent amine and the polyvalent isocyanate.
18. A liquid crystal display element comprising a pair of electrodes and the cholesteric liquid crystal dispersion of claim 1 sandwiched between the pair of electrodes.