Graft functionalized olefin polymer dispersant and uses thereof
View Patent ↗A novel highly grafted, functionalized olefin polymer is provided comprising the reaction product of a method comprising reacting an acylating agent with a mixture comprising an olefin polymer having a number average molecular weight of between about 5,000 to about 100,000 and a diluent in the presence of a free radical initiator to provide an acylated olefin polymer which is further reacted with a polyamine to provide the grafted functionalized olefin polymer dispersant. Lubricating oil concentrates and compositions containing the highly grafted, functionalized olefin polymer and uses thereof also are provided.
1. A lubricating oil composition comprising:
a major amount of an oil of lubricating viscosity; and
a minor amount of a grafted functionalized olefin polymer prepared by a method comprising reacting an acylating agent with a mixture comprising
an olefin polymer having a number average molecular weight of between about 20,000 to about 100,000 and
a diluent in the presence of a free radical initiator to provide an acylated olefin polymer which is further reacted with a polyamine,
wherein the diluent is selected from the group consisting of alpha-olefin oligomers, highly refined solvent neutral base oil, and combinations thereof.
2. The lubricating oil composition of claim 1 , further comprising at least one additive selected from the group consisting of additional viscosity index improvers, antioxidants, corrosion inhibitors, detergents, dispersants, pour point depressants, antiwear agents, antifoaming agents, demulsifiers and friction modifiers.
3. The lubricating oil composition of claim 1 , wherein the oil of lubricating viscosity is selected from the group consisting of natural oils, synthetic oils and mixtures thereof.
4. A method of lubricating an internal combustion engine wherein said method comprises adding to the crankcase of said internal combustion engine the lubricating oil composition of claim 1 .
5. A method of lubricating a transmission of an internal combustion engine comprising lubricating said transmission with the lubricating oil composition of claim 1 .
6. The lubricating oil composition of claim 1 , wherein the acylating agent is an ethylenically unsaturated carboxylic reactant.
7. The lubricating oil composition of claim 1 , wherein the acylating agent is reacted with the olefin polymer in the absence of solvents selected from open-chain aliphatic hydrocarbons, aromatic hydrocarbons, alicyclic hydrocarbons, and ketones.
8. The lubricating oil composition of claim 1 , wherein the acylating agent is reacted with the olefin polymer in the absence of solvents selected from C 9 or lower alkanes, C 9 or lower alkenes, C 9 or lower alkynes, aromatic hydrocarbons having a benzene nucleus, alicyclic hydrocarbons having a boiling point no greater than that of nonane, and ketones having a boiling point no greater than that of nonane.
9. The lubricating oil composition of claim 1 , wherein the olefin polymer contains termonomer in an amount not exceeding about 0.5 wt.%.
10. The lubricating oil composition of claim 1 , wherein the reaction mixture during the grafting step comprises about 75 to about 100 wt.% of the olefin polymer and up to 25 wt.% of the alpha-olefin oligomer or highly refined solvent neutral base oil.
11. The lubricating oil composition of claim 1 , wherein the olefin polymer comprises a copolymer of ethylene and one or more C 3 -C 23 alpha olefins.
12. The lubricating oil composition of claim 1 , wherein the olefin polymer has a number average molecular weight of between about 5,000 to about 30,000.
13. The lubricating oil composition of claim 1 , wherein the acylated olefin polymer comprises copolymers or terpolymers of ethylene and C 3 to C 23 alpha-olefin and optionally a nonconjugated diene or triene on which has been grafted ethylenically unsaturated carboxylic reactants to a level of 0.3 to 0.75 carboxylic groups per 1000 number average molecular weight units (Mn).