Organic electroluminescent device using mixture of phosphorescent material as light-emitting substance
View Patent ↗An organic EL device which includes a first electrode, a hole transport layer, a light-emitting layer, and the second electrode, wherein the light-emitting layer includes a mixed light-emitting film of a host substance, which is capable of transferring an energy to another light-emitting polymer by absorbing the energy, and a phosphorescent dopant which is capable of emitting light using a triplet state after absorbing the energy received. Accordingly, the light-emitting layer can be patterned, and a color purity and light-emitting characteristics of a full color organic polymer EL device, produced through a laser induced termal imaging operating, can be improved.
1. A method for fabricating an organic electroluminescent device, the method comprising:
providing a substrate;
forming a first electrode on the substrate;
forming a hole transport layer over the first electrode;
forming a light-emitting layer by Laser Induced Thermal Imaging (LITI) on the hole transport layer; and
forming a second electrode over the light-emitting layer,
wherein the light-emitting layer comprises a host substance and a phosphorescent dopant.
2. The method according to claim 1 , wherein the phosphorescent dopant is a low molecular weight material or a high molecular weight material that enables phosphorescent light emission in a triplet and is a complex of an organic metal selected from the group consisting of Ir, Pt, Eu and Tb.
3. The method according to claim 1 , wherein the phosphorescent dopant is tris(2-phenylpyrridine)iridium (IrPPy).
4. The method according to claim 1 , wherein the phosphorescent dopant is 10% or less by weight of the light-emitting layer.
5. The method according to claim 1 , further comprising forming a hole inhibition layer and/or an electron transport layer.
6. The method according to claim 1 , wherein the host substance is a mixture of a matrix material selected from the group consisting of an optically inactive high molecular weight material, a high molecular weight material having an electric charge transport capability and a low molecular weight material with a film-forming ability with a spin-coating process and a low molecular weight electric charge transporter with hole transport capability or a low molecular weight molecular charge transporter with electron transport capability.
7. The method according to claim 6 , wherein the low molecular weight material with a film forming ability using a spin-coating process is selected from the group consisting of carbazole, arylamine, hydrazone, stilbene, starburst based low molecular weight materials which are spin-coatable to give uniform films.
8. The method according to claim 6 , wherein the optically inactive high molecular weight material is selected from the group consisting of polystyrene, poly(styrene-butadione) copolymer, polymethylmethacrylate, polyalphamethylstyrene, styrene-methylmethacrylate copolymer, polybutadiene, polycarbonate, polyethyleneterephthalate, polyestersulfonate, polysulfonate, polyarylate, unsaturated polyamide, transparent fluorocarbon resin and transparent acryl based resin.
9. The method according to claim 6 , wherein the high molecular weight material having electric charge transport capability is a high molecular weight material selected from the group consisting of carbazole, arylamine, perylene, and pyrrol based materials.
10. The method according to claim 6 , wherein the low molecular weight electric charge transporter with hole transport capability is comprised of a carbazole, arylamine, hydrazone, stilbene, or a starburst based material, and the low molecular weight electric charge transporter with electron transport capability is an oxadiazole, starburst based material.
11. The method according to claim 10 , wherein the carbazole based low molecular weight material is 4,4′-N,N′-dicarbazole-biphenyl (CBP) and the oxadiazole based low molecular weight material is 2-(4-biphenylyl)-5-(4-tert-butylphenyl) 1,3 , 4-oxadiazole (PBD).
12. The method according to claim 6 , wherein the low molecular weight electric charge transporter is 50% to 75% by weight of the total of the host substance.
13. The method according to claim 8 , wherein the phosphorescent dopant is a low molecular weight material or a high molecular weight material capable of phosphorescent light emission in the triplet state as an organic metal complex of Ir or Pt.
14. The method according to claim 9 , wherein the phosphorescent dopant is a low molecular weight material or a high molecular weight material capable of phosphorescent light emission in the triplet state as an organic metal complex of Ir or Pt.
15. The method according to claim 13 , wherein the phosphorescent dopant is tris (2-phenylpyrridine) iridium (IrPPy).
16. The method according to claim 13 , wherein the phosphorescent dopant is 10% or less by weight of the light-emitting layer.
17. The method according to claim 1 , wherein the matrix comprises an optically inactive polymer.
18. A method for fabricating an organic electroluminescent device, the method comprising:
providing a substrate;
forming a first electrode on the substrate;
forming a hole transport layer over the first electrode;
forming a light-emitting layer by Laser Induced Thermal Imaging (LITI) on the hole transport layer; and
forming a second electrode over the light-emitting layer,
wherein the light-emitting layer comprises a host substance and a phosphorescent dopant, and the host substance comprises a matrix and a low molecular weight electric charge transporter.
19. The method according to claim 18 , wherein the matrix comprises a coating property to form a film, and the low molecular electric charge transporter is mixed into the matrix so as not to significantly drop an adhesion force of the matrix between a substrate and the film.
20. The method according to claim 18 , wherein an adhesive force between parts of the film is relatively weakened so as to improve transfer characteristics of the film from one substrate to another, while electrical characteristics of the organic electroluminescent device are not dropped.
21. The method according to claim 18 , wherein the phosphorescent dopant is 10% or less by weight of the light-emitting film layer.
22. The method according to claim 19 , wherein the low molecular weight electric charge transporter is 50% to 75% by weight of the host substance.
23. The method according to claim 18 , wherein the matrix is poly(vinyl carbazole).
24. A method for fabricating an organic electroluminescent device, the method comprising:
forming a first electrode on a substrate;
forming a hole transport layer over the first electrode;
forming a light-emitting layer by a Laser Induced Thermal Imaging (LITI) method on the hole transport layer; and
forming a second electrode over the light-emitting layer,
wherein the light-emitting layer comprises a host substance and a phosphorescent dopant, wherein the host substance comprises a matrix and a low molecular weight electric charge transporter and wherein the matrix is an optically inactive high molecular weight material selected from the group consisting of polystyrene, poly(styrene-butadione) copolymer, polymethylmethacrylate, polyalphamethylstyrene, styrene-methylmethacrylate copolymer, polybutadiene, polycarbonate, polyethyleneterephthalate, polyestersulfonate, polysulfonate, polyarylate, unsaturated polyamide, transparent fluorocarbon resin and transparent acryl based resin.