Process for producing a phosphate of the lanthanoids, and phosphate produced thereby
View Patent ↗A process for producing a phosphate of the lanthanoids is described. The process is based on a two-jet precipitation, starting from separate reservoirs of a rare earth salt solution and a phosphate solution which are introduced simultaneously by separate feedlines into an aqueous acidified initial charge with stirring at a pH of 0≦pH≦1. After the solutions are added, the pH is raised to a pH of >2 to complete the phosphate precipitation.
1. A process for producing a phosphate of the lanthanoids, comprising the steps of:
simultaneously adding by way of separate feedlines a first solution, which contains rare earth salts, and a second solution, which contains phosphate ions, to a vessel containing an aqueous acidified initial charge with stirring at a pH of 0≦pH≦1, so that precipitation of the phosphate occurs at a pH≦1, the two solutions being added sufficiently slowly in an approximately molar ratio of the ions of the phosphate so that the molar ratio deviates by at most 20% as the precipitation occurs; and
concluding the precipitation by raising the pH to a pH of >2.
2. The process as claimed in claim 1 , wherein a precipitation aid in the form of an alkali metal salt or alkaline-earth metal salt is added to the first solution.
3. The process as claimed in claim 2 , wherein the precipitation aid is a nitrate of lithium or magnesium.
4. The process as claimed in claim 1 , wherein the lanthanoid is a single one or a mixture of the elements Y, Sc, La, Ce, Tb, Pr.
5. The process as claimed in claim 4 , wherein the lanthanoid is a mixture of the elements La, Ce, Tb, Pr, wherein the cerium and/or praseodymium content is up to 30 mol %.
6. The process as claimed in claim 1 , wherein the phosphate has the following composition: (La x Ce y Tb z )PO 4 with x+y+z =1 and with 0.3≦x0.8; 0.05≦z≦0.30.
7. The process as claimed in claim 6 , wherein at least one of the following conditions is satisfied:
0.4≦x≦0.7;
0.1≦y≦0.5;
0.1≦z≦0.2.
8. The process as claimed in claim 5 , wherein the cerium content is between 5 and 30 mol % and/or the praseodymium content is between 0.1 and 2 mol %.
9. The process as claimed in claim 1 , wherein at least one of the following further process steps is then carried out: washing, screening, drying, calcining at a temperature of at least 800° C.