Optically clear polycarbonate polyester compositions
View Patent ↗An optically clear thermoplastic resin composition consisting essentially of: structural units derived at least one substituted or unsubstituted polycarbonate, at least greater than 30 weight percent of a substituted or unsubstituted polyester, a modified polycarbonate, an impact modifier having a refractive index in the range between about 1.51 and about 1.56 and an additive is disclosed. The composition possess good optical properties, flow, stability and mechanical property. Also disclosed is a process to prepare these compositions and articles therefrom.
1. A composition consisting essentially of an optically clear thermoplastic resin composition consisting essentially of:
(a) at least one substituted or unsubstituted polycarbonate,
(b) a polyorganosiloxane/polycarbonate block copolymer of the structure XVI:
wherein R 17 , R 18 and R 20 are independently at any occurrence an aliphatic, aromatic or cycloaliphatic radical; E 1 is a member independently selected from the group consisting of hydrogen, lower alkyl, alkoxy, aryl, alkylaryl, halogen radicals and mixtures thereof; A 1 is a hydrocarbon radical; D 1 is a tetravalent hydrocarbon radical Y 1 is a member at each occurrence independently selected from the group consisting of fluorine, bromine, chlorine, iodine, nitro, alkenyl, allyl, alkyl, aryl, aralkyl, alkaryl, cycloalkyl, or OR 2 wherein R 2 is alkyl, aryl, aralkyl, alkaryl, or cycloalkyl; m is zero to the number of replaceable hydrogens on A 1 available for substitution; and q is an integer between 1 and 200,
having polyorganosiloxane domains having an average domain size less than or equal to 45 nanometers;
(c) at least greater than 30 weight percent of a (semi)aliphatic polyester selected from the group consisting of poly(cyclohexane dimethanol cyclohexane dicarboxylate), cyclohexanedimethanol-terephthalic acid-ethylene glycol copolymers and combinations thereof;
(d) an impact modifier having a refractive index in the range between about 1.51 and about 1.56; and
(e) an additive;
wherein the composition has a Notched Izod Impact of at least 55 kJ per m 2 at 0° C. as measured using ISO 180/U method, a Puncture Impact of at least 100 J at −30° C. as measured using ISO 6603 Standard Method, a Melt Volume Rate of at least 11 cm 3 /10 min as measured using ISO Standard 133 Method, a yellowness index of less than about 6 measured in accordance with ASTM D-1003, and a haze value about less than 3 measured in accordance with ASIM D-1003.
2. The composition of claim 1 , wherein the thermoplastic resin composition comprises about 30 to 95 percent by weight of the (semi)aliphatic polyester and about 10 to about 70 percent by weight of the substituted or unsubstituted polycarbonate.
3. The composition of claim 1 , wherein the polyorganosiloxane/polycarbonate block copolymer is present in the range of between about 5 and 70 weight percent based on the total weight of the thermoplastic composition.
4. The composition of claim 1 , wherein the impact modifier is selected from the group consisting of graft or core shell acrylic rubbers, diene rubber, organosiloxane rubber, ethylene propylene diene monomer rubber, styrene-butadiene-styrene rubber, styrene-ethylene-butadiene-styrene rubber, acrylonitrile-butadiene-styrene rubber, methacrylate-butadiene-styrene rubber, and styrene acrylonitrile copolymer.
5. The composition of claim 1 , wherein the impact modifier is at least one selected from the group consisting of MBS core shell polymer and ABS rubber.
6. The composition of claim 1 , wherein the impact modifier is present in an amount between about 0.5 and about 50 weight percent based on the total weight of the thermoplastic composition.
7. The composition of claim 1 , wherein the additive is at least one selected from a group consisting of anti-oxidants, flame retardants, reinforcing materials, colorants, mold release agents, fillers, nucleating agents, UV light stabilizers, heat stabilizers, lubricants, and combinations thereof.
8. The composition of claim 1 , wherein the additive is present in the range of between about 0.1 and 1.5 weight percent based on the total weight of the thermoplastic resin.
9. The composition of claim 1 , wherein the composition has a Notched Izod Impact of at least greater than 65 kJ per m 2 at 23° C. as measured using ISO 180/U method.
10. The composition of claim 1 , wherein the composition has a Notched Izod Impact of at least greater than 55 kJ per m 2 at 0° C. as measured using ISO 180/U method.
11. The composition of claim 1 , wherein the composition has a Puncture Impact of at least greater than 100 J at −30° C. as measured using ISO 6603 Standard Method.
12. The composition of claim 1 , wherein the optically clear resin composition has a Melt Volume Rate of at least greater than 11 cm 3 /10 min as measured using ISO Standard 1133 Method.
13. The composition of claim 1 , wherein the thermoplastic resin composition has a yellowness index of less than about 6 measured in accordance with ASTM E313.
14. The composition of claim 1 , wherein the optically clear resin composition has a haze value about less than 3 measured in accordance with ASTM D-1003.
15. The composition of claim 1 , wherein the optically clear resin composition transmits about greater than 85 percent light in the region of about 250 nm to about 300 nm measured in accordance with ASTM D-1003.
16. An article comprising the composition of claim 1 .
17. The composition of claim 1 , wherein the additive is at least one selected from a group consisting of anti-oxidants, flame retardants, reinforcing materials, colorants, mold release agents, fillers, nucleating agents, UV light stabilizers, heat stabilizers, lubricants, and combinations thereof.
18. The composition as claimed in claim 1 , wherein the substituted or unsubstituted polycarbonate is present in an amount of between 6.1 and 31.1 weight percent based on the total weight of the composition, and wherein the composition has an Izod Notched impact at −25° C. of at least 33.4 kJ/m 2 as measured using the ISO 180/U method.
19. The composition as claimed in claim 1 , wherein the impact modifier is selected from the group consisting of styrene-butadiene-styrene rubber, styrene-ethylene-butadiene-styrene rubber, acrylonitrile-butadiene-styrene rubber, methacrylate-butadiene-styrene rubber, and combinations thereof.
20. The composition as claimed in claim 19 , wherein the composition does not contain impact modifiers selected from the group consisting of organosiloxane rubber, ethylene propylene diene monomer rubber, and styrene acrylonitrile copolymers.
21. The composition of claim 1 , wherein the polyorganosiloxane/polycarbonate block copolymer comprises about 1.0 to about 2.5 percent by weight siloxane content.
22. A composition comprising an optically clear blend of:
(a) a polyorganosiloxane/polycarbonate block copolymer of the structure XVII:
wherein R 19 and R 20 are the same or different, and are aryl, halogenated aryl, aralkyl, alkyl, cycloalkyl, or haloalkyl radicals; R 19 and R 20 can be all the same radical or any two or more of the aforementioned radicals, R 21 is an alkyl, aryl, alkoxy, or aryloxy radical; and y and z are integers between about 1 to 1000, x is an integer between 0 and 199; and
having polyorganosiloxane domains having an average domain size less than or equal to 45 nanometers;
(b) at least greater than 30 weight percent of a (semi)aliphatic polyester selected from the group consisting of poly(cyclohexane dimethanol cyclohexane dicarboxylate), cyclohexanedimethanol-terephthalic acid-ethylene glycol copolymers, polyethylene glycol cyclohexane dimethanol terephthalate, and combinations thereof;
(c) an impact modifier having a refractive index in the range between about 1.51 and about 1.56; and
(d) an additive; and
(e) a substituted or unsubstituted polycarbonate;
wherein the composition has a Notched Izod Impact of at least 55 kJ/m 2 at 0° C. as measured using ISO 180/U method, a Puncture Impact of at least 100 J at −30° C. as measured using ISO 6603 Standard Method, a Melt Volume Rate of at least 11 cm 3 /10 min as measured using ISO Standard 1133 Method, a yellowness index of less than about 6 measured in accordance with ASTM D-1003, and a haze value about less than 3 measured in accordance with ASIM D-1003.
23. The composition as claimed in claim 22 , wherein the substituted or unsubstituted polycarbonate is present in an amount of between 6.1 and 31.1 weight percent based on the total weight of the composition, and wherein the composition has an Izod Notched impact at −25° C. of at least 33.4 kJ/m 2 as measured using the ISO 180/U method.
24. The composition as claimed in claim 22 , wherein the impact modifier is selected from the group consisting of styrene-butadiene-styrene rubber, styrene-ethylene-butadiene-styrene rubber, acrylonitrile-butadiene-styrene rubber, methacrylate-butadiene-styrene rubber, and combinations thereof.
25. The composition of claim 24 , wherein the composition does not contain impact modifiers selected from the group consisting of organosiloxane rubber, ethylene propylene diene monomer rubber, and styrene acrylonitrile copolymers.
26. A composition comprising an optically clear blend of:
(a) from about 10 to about 70 weight percent of a polyorganosiloxane/polycarbonate block copolymer of the structure XVIII:
wherein x is an integer between 0 and 199; and y and z are integers between 1 and 1000;
(b) a substituted or unsubstituted bisphenol A polycarbonate;
(c) from about 31 to about 80 weight percent of a (semi)aliphatic polyester selected from the group consisting of poly(cyclohexane dimethanol cyclohexane dicarboxylate), cyclohexanedimethanol-terephthalic acid-ethylene glycol copolymers, and combinations thereof; and
(d) from about 0.5 to about 50 weight percent of an impact modifier having a refractive index in the range between about 1.51 and about 1.56;
wherein the composition has a Notched Izod Impact of at least 55 kJ per m 2 at 0° C. as measured using ISO 180/U method, a Puncture Impact of at least 100 J at −30° C. as measured using ISO 6603 Standard Method, a Melt Volume Rate of at least 11 cm 3 /10 min as measured using ISO Standard 1133 Method, a yellowness index of less than about 6 measured in accordance with ASTM D-1003, and a haze value about less than 3 measured in accordance with ASTM D-1003.
27. The composition as claimed in claim 26 , wherein the substituted or unsubstituted polycarbonate is present in an amount between 6.1 and 31.1 weight percent based on the total weight of the composition, and wherein the composition has an Izod Notched impact at −25° C. of at least 33 . 4 kJ/m 2 as measured using the ISO 180/U method.
28. The composition as claimed in claim 26 , wherein the impact modifier is selected from the group consisting of styrene-butadiene-styrene rubber, styrene-ethylene-butadiene-styrene rubber, acrylonitrile-butadiene-styrene rubber, methacrylate-butadiene-styrene rubber, and combinations thereof.
29. The composition of claim 28 , wherein the composition does not contain impact modifiers selected from the group consisting of organosiloxane rubber, ethylene propylene diene monomer rubber, and styrene acrylonitrile copolymers.