Dip coating process for producing electrophotographic composition layer having controlled thickness
View Patent ↗A method for controlling the thickness and uniformity of a dip coated layer, using a coating apparatus in a normal coating environment, includes the following steps: forming under normal coating conditions of ambient temperature and relative humidity a series of coated layers on a metal substrate having a thickness of at least about 500 microns, using variations in coating solution viscosity m, coating substrate withdrawal speed v, capillary number Ca, coating solution surface tension S, and boiling point bp (a correlative of evaporation rate)of the coating solution solvent, a coated layer including at least a portion of uniform thickness T(even) and, optionally, a portion of non-uniform thickness L (uneven); statistically analyzing measurements carried out on the series of coated layers and generating the constants, a, b, c, d, and e for Equations 2, 3, and 4: T (even)= a+b ( m*v ) (Equation 2) L (uneven)= c+d *( v*bp )+ e* ( Ca*bp ) (Equation 3) v (even)=− c/bp *( d+e*m/S ) (Equation 4) using Equation 4, determining the coating speed v(even) producing the maximum thickness of a coated layer having a completely uniform thickness for a given set of coating solution characteristics; and using Equation 2, determining the thickness T(even) of the portion of the coated layer having uniform thickness for a given set of coating solution characteristics and the coating speed determined in step (c).
1. A method for controlling the thickness and uniformity of a dip coated layer using a coating apparatus in a normal coating environment, said method comprising:
(a) under normal coating conditions of ambient temperature and relative humidity, forming on a metal substrate having a thickness of at least about 500 microns a series of coated layers using variations in coating solution viscositym, coating substrate withdrawal speed v, coating solution surface tension S, and boiling point bp of coating solution solvent, at least a portion T(even) of a coated layer being of uniform thickness and, optionally, a portion L(uneven) of said coated layer being of non-uniform thickness;
(b) measuring the thickness of the coated substrate at various positions along the full length of the coated substrate;
(c) generating a plot of the thickness vs. axial position;
(d) measuring the length of the uneven thickness portion of the coated layer L(uneven);
(e) measuring the thickness of the uniform thickness portion of the coated layer T(even), and statistically analyzing the L(uneven) measurements as a function of (m*v), where m is the viscosity in poise and v is the coating withdrawal speed in cm/sec to generate Equation 2,
T (even)= a+b ( m*v ) (Equation 2)
which predicts the thickness T(even), in cm, of the portion of the coated layer having uniform thickness;
(f) statistically analyzing the L(uneven) measurements as a function of (v*bp) and (Ca*bp), where v is the coating speed in cm/sec, bp is the boiling point of the coating solvent, Ca is equal to (m*v)/S, a dimensionless number, where m is the viscosity of the coating solution in poise, v is the coating speed in cm/sec5 and S is the surface tension of the coating solution to generate Equation 3,
L (uneven)= c+d *( v*bp )+ e* ( Ca*bp ) (Equation 3)
which predicts the length L(uneven), in cm, of a sloping portion of the coated layer having non-uniform thickness;
(g) obtaining Equation 4
v (even)=− c/bp *( d+e*m/S ) (Equation 4)
which predicts the substrate withdrawal coating speed v(even) in cm/sec required for the maximum thickness of a coated layer having a completely uniform thickness by setting L(uneven) =0;
(h) using Equation 4, detennining the coating speed v(even) for producing the maximum thickness of a coated layer having completely uniform thickness for a given set of coating solution characteristics; and
(i) using Equation 2, determining the thickness T(even) of the portion of a coated layer having uniform thickness for a given set of coating solution characteristics and the coating speed v(even) determined in step (h); and
(j) using the v(even) and T(even) values determined in (h) and (i) to control the thickness and uniformity of a dip coated layer using a coating apparatus in a normal coating environment.
2. The method of claim 1 wherein the portion of the coated layer of uniform thickness has a thickness of about 5 μm to about 60 μm.
3. The method of claim 2 wherein the portion of the coated layer of uniform thickness has a thickness of about 10 μm to about 40 μm.
4. The method of claim 3 wherein the portion of the coated layer of uniform thickness has a thickness of about 15 μm to about 30 μm.
5. The method of claim 1 wherein the coated layer includes a controlled portion of non-uniform thickness.
6. The method of claim 1 wherein the substrate comprises a drum.
7. The method of claim 6 wherein the drum comprises aluminum.
8. The method of claim 1 wherein the coated layer comprises a charge transport agent.
9. The method of claim 1 wherein the coated layer comprises a charge generation agent.
10. The method of claim 1 wherein the coating solution solvent is selected from the group consisting of toluene, tetrahydrofuran, methylene chloride, acetone, methyl ethyl ketone, methyl acetate, ethyl acetate, and mixtures thereof.
11. The method of claim 10 wherein the coating solution solvent is dichloromethane.
12. The method of claim 1 wherein the coating solution solvent has a boiling point below about 100° C.
13. The method of claim 12 wherein the coating solution solvent has a boiling point below about 60° C.
14. The method of claim 13 wherein the coating solution solvent has a boiling point below about 40° C.