Boron-alumina catalyst support
View Patent ↗In one embodiment, an oxidation catalyst comprises a catalytic material disposed on a support. The support comprises boron modified alumina and about 10 wt % to about 50 wt % zeolite, based upon the total weight of the support. The boron is present in a sufficient amount up to less than or equal to about 7 wt %, based upon a total weight of the alumina, to selectively poison a portion of the alumina.
1. An oxidation catalyst, comprising: a catalytic material disposed on a support, wherein the catalytic material is selected from the group consisting of platinum, palladium, iridium, rhodium, ruthenium, alloys thereof, and combinations thereof; wherein the support comprises boron modified alumina and about 10 wt % to about 50 wt % zeolite, based upon the total weight of the support, and wherein the boron is present in a sufficient amount up to less than or equal to about 7 wt %, based upon a total weight of the alumina, to selectively poison a portion of the alumina.
2. The oxidation catalyst of claim 1 , wherein the alumina further comprises about 1 wt % to about 10 wt % silica, based upon the total weight of the alumina and silica.
3. The oxidation catalyst of claim 2 , wherein the alumina comprises about 3 wt % to about 8 wt % silica.
4. The oxidation catalyst of claim 3 , wherein the alumina further comprises about 4 wt % to about 6 wt % silica.
5. The oxidation catalyst of claim 1 , wherein the catalytic metal is present in an amount of about 0.1 wt % to about 10 wt %, the boron modified alumina is present in an amount of about 50 wt % to about 80 wt %, and the zeolite is present in an amount of about 10 wt % to about 50 wt %, based upon the total weight of the oxidation catalyst; and wherein the boron is present in an amount of about 0.1 wt % to about 5 wt % boron.
6. The oxidation catalyst of claim 5 , wherein the catalytic metal is present in an amount of about 1 wt % to about 5 wt %, the boron modified alumina is present in an amount of about 50 wt % to about 75 wt %, and the zeolite is present in an amount of about 25 wt % to about 45 wt %, based upon the total weight of the oxidation catalyst; and wherein the boron is present in an amount of about 0.1 wt % to about 5 wt % boron; and wherein the alumina further comprises about 1 wt % to about 10 wt % silica, based upon the total weight of the alumina and silica.
7. The oxidation catalyst of claim 6 , wherein the catalytic metal is present in an amount of about 1 wt % to about 3 wt %, the boron modified alumina is present in an amount of about 62 wt % to about 74 wt %, and the zeolite is present in an amount of about 25 wt % to about 35 wt %, based upon the total weight of the oxidation catalyst; and wherein the boron is present in an amount of about 0.5 wt % to about 2.5 wt % boron; and wherein the alumina further comprises about 3 wt % to about 8 wt % silica, based upon the total weight of the alumina and silica.
8. The oxidation catalyst of claim 6 , wherein the amount of boron is about 1 wt % to about 2 wt %.
9. The oxidation catalyst of claim 1 , wherein the catalytic material comprises platinum.
10. The oxidation catalyst of claim 1 , wherein the oxidation catalyst is capable of oxidizing an exhaust stream component under compression ignition exhaust conditions.
11. A catalytic device, comprising: a housing disposed around a substrate; a compression ignition oxidation catalyst disposed at the substrate, the compression ignition oxidation catalyst comprising a catalytic material disposed on a support, wherein the catalytic material is selected from the group consisting of platinum, palladium, iridium, rhodium, ruthenium, alloys thereof, and combinations thereof; and wherein the support comprises boron modified alumina and about 10 wt % to about 50 wt % zeolite, based upon the total weight of the support, and wherein the boron is present in a sufficient amount up to less than or equal to about 7 wt %, based upon a total weight of the alumina, to selectively poison a portion of the alumina.
12. The catalytic device of the claim 11 , further comprising a retention material disposed between the housing and the substrate.
13. A method for treating a compression ignition exhaust stream, comprising: introducing the compression ignition exhaust stream to a compression ignition oxidation catalyst; and oxidizing an exhaust stream component; wherein the compression ignition oxidation catalyst comprises a catalytic material disposed on a support, wherein the catalytic material is selected from the group consisting of platinum, palladium, iridium, rhodium, ruthenium, alloys thereof, and combinations thereof; and wherein the support comprises boron modified alumina and about 10 wt % to about 50 wt % zeolite, based upon the total weight of the support, and wherein the boron is present in a sufficient amount up to less than or equal to about 7 wt %, based upon a total weight of the alumina, to selectively poison a portion of the alumina.