Anionic phthalic acid ester compounds and stain resistant compounds
View Patent ↗This invention relates to compounds of formula: wherein A is an unsaturated alkylene moiety; B the residue of a polyol wherein one hydroxyl moiety is esterified with one carboxyl moiety of the phthalic acid moiety; D is the residue of a polyol wherein one hydroxyl moiety is esterified with another carboxyl moiety of the phthalic acid moiety, and another hydroxyl moiety is esterified with one carboxyl moiety of the unsaturated alkylene moiety; E is the residue of polyol wherein one hydroxyl moiety is esterified with another carboxyl moiety of the unsaturated alkylene moiety; and M is a cation. The compounds can be used alone, or polymerized, or polymerized and combined with other polymers, to form effective stain and soil repellent compositions.
1. A polymer comprising one or more polymerized monomers of formula:
wherein A is an unsaturated alkylene moiety; B is the residue of a substituted or unsubstituted polyol wherein one hydroxyl moiety is esterified with one carboxyl moiety of the phthalic acid moiety; D is the residue of a substituted or unsubstituted polyol wherein one hydroxyl moiety is esterified with another carboxyl moiety of the phthalic acid moiety, and another hydroxyl moiety is esterified with one carboxyl moiety of the unsaturated alkylene moiety; E is the residue of a substituted or unsubstituted polyol wherein one hydroxyl moiety is esterified with another carboxyl moiety of the unsaturated alkylene moiety; and M is a cation.
2. The polymer of claim 1 , wherein said polymer is a copolymer of at least one monomer having the structure shown in formula I and at least one unsaturated carboxylic acid or unsaturated carboxylic acid ester.
3. The polymer of claim 2 , wherein the unsaturated carboxylic acid or unsaturated carboxylic acid ester is selected from the group consisting of (meth)acrylic acid, alkyl (meth)acrylate, aryl (meth)acrylate, itaconic acid, alkyl itaconate, and aryl itaconate.
4. The polymer of claim 3 , wherein said polymer is a copolymer of a monomer of formula II:
and (meth)acrylic acid.
5. The polymer of claim 4 , wherein the molar ratio of methacrylic acid to monomer of formula II ranges from about 0.5:1 to about 1.5:1.
6. A stain resist composition comprising an effective amount of at least one polymer of claim 1 .
7. The stain resist composition of claim 6 , wherein the composition is in the form of an aqueous emulsion.
8. The stain resist composition of claim 6 , further comprising a blend with one or more; phenol formaldehyde condensation polymers, polymethacrylic acid, styrene-maleic acid polymers, or poly(meth)acrylic acid IPN with phenol-formaldehyde condensation polymers.
9. A method of imparting stain resistance to fabric or fiber, comprising contacting the fabric or fiber with the composition of claim 6 .
10. A method of imparting stain resistance to fabric or fiber, comprising contacting the fabric or fiber with the composition of claim 8 .