Heat treatable coated article with zirconium silicon oxynitride layer(s) and methods of making same
View Patent ↗A coated article is provided so as to include a solar control coating having an infrared (IR) reflecting layer sandwiched between at least a pair of dielectric layers. The IR reflecting layer may be of or include NbZrO x , NbZr, NiCr, NiCrN x , or the like in certain embodiments of this invention. In particular, a zirconium silicon oxynitride (e.g., ZrSiO x N y ) inclusive layer is provided which unexpectedly improves blocking (reflecting and/or absorption) of UV radiation in a manner which does not significantly degrade other optical properties of a coated article. Moreover, the ZrSiO x N y also has been found to improve (lower) the ΔE* value upon heat treatment, thereby permitting a coated article when heat treated (HT) to more closely match its non-HT counterpart with respect to glass side reflective color after such HT.
1. A coated article including a coating supported by a glass substrate, the coating comprising:
a first dielectric layer comprising silicon nitride;
an infrared (IR) reflecting layer comprising one or more of NbZr and NiCr located on the substrate over and contacting the first dielectric layer comprising silicon nitride;
a second dielectric layer comprising silicon nitride located over and contacting the IR reflecting layer comprising, the IR reflecting layer comprising one or more of (i) an oxide of NbZr, and (ii) NiCr; and
an overcoat layer comprising zirconium silicon oxynitride located on the substrate as an uppermost layer of the coating, wherein the zirconium silicon oxynitride is located over and contacts the second dielectric layer comprising silicon nitride and contains more zirconium than silicon, and wherein a Zr/Si ratio in the layer comprising zirconium silicon oxynitride is from about 5.0 to 20.0.
2. The coated article of claim 1 , wherein the IR reflecting layer comprises one or more of (a) an oxide of niobium zirconium; (b) a nitride of niobium zirconium; (c) a nitride of nickel chromium; and (d) substantially metallic nickel chromium.
3. The coated article of claim 1 , wherein the first dielectric layer is in direct contact with the glass substrate.
4. The coated article of claim 1 , wherein the layer comprising zirconium silicon oxynitride consists essentially of zirconium silicon oxynitride.
5. The coated article of claim 1 , wherein the coated article has a sheet resistance (R s ) of no greater than about 100 ohms/square and a visible transmission of at least about 10%.
6. The coated article of claim 1 , wherein the coating comprises only one IR reflecting layer, and the one IR reflecting layer does not include silver or gold.
7. The coated article of claim 1 , wherein the coated article has a visible transmission of from 8-50%.
8. The coated article of claim 1 , wherein a Zr/Si ratio in the layer comprising zirconium silicon oxynitride is from about 2.0 to 50.0.
9. The coated article of claim 1 , wherein a Zr/Si ratio in the layer comprising zirconium silicon oxynitride is from about 5.0 to 20.0.
10. The coated article of claim 1 , wherein a Zr/Si ratio in the layer comprising zirconium silicon oxynitride is from about 10.0 to 15.0.
11. The coated article of claim 1 , wherein oxygen content of the layer comprising zirconium silicon oxynitride is provided in an amount so that the layer(s) comprising zirconium silicon oxynitride at a wavelength of 550 nm has an extinction coefficient (k) of no greater than about 1.8.
12. The coated article of claim 1 , wherein a ratio of nitrogen/oxygen in the zirconium silicon oxynitride is from about 1 to 25.
13. The coated article of claim 1 , wherein a ratio of nitrogen/oxygen in the zirconium silicon oxynitride is from about 2 to 10.
14. The coated article of claim 1 , wherein the coated article is heat treated, and wherein the coated article has a ΔE* value (glass side reflective) of no greater than 3.0 due to heat treatment.
15. The coated article of claim 1 , wherein the coated article is heat treated, and wherein the coated article has a ΔE* value (glass side reflective) of no greater than 1.5 due to heat treatment.
16. The coated article of claim 1 , wherein the coated article is heat treated, and wherein the coated article has a ΔE* value (glass side reflective) of no greater than 0.8 due to heat treatment.
17. The coated article of claim 1 , wherein the IR reflecting layer comprises an oxide of niobium zirconium, and comprises from 0.05 to 10% oxygen.
18. The coated article of claim 1 , wherein the IR reflecting layer comprises an oxide of niobium zirconium, and wherein the layer comprising the oxide of niobium zirconium comprises (Nb+Zr) x O y , where the ratio y/x (i.e., the ratio of oxygen to Nb+Zr) is from 0.03 to 0.20.
19. The coated article of claim 1 , wherein the coated article is a window.
20. A coated article for use in a window and including a coating supported by a substrate, the coating comprising:
an infrared (IR) reflecting layer; and
a layer comprising zirconium silicon oxynitride located on the substrate over at least the IR reflecting layer, wherein a Zr/Si ratio in the layer comprising zirconium silicon oxynitride is from about 5.0 to 20.0.
21. The coated article of claim 20 , wherein the IR reflecting layer comprises one or more of: (a) an oxide of niobium zirconium; (b) a nitride of niobium zirconium; (c) a nitride of nickel chromium; (d) substantially metallic nickel chromium; and (e) niobium.
22. The coated article of claim 20 , wherein the Zr/Si ratio in the layer comprising zirconium silicon oxynitride is from about 8.0 to 18.0.
23. The coated article of claim 20 , wherein the Zr/Si ratio in the layer comprising zirconium silicon oxynitride is from about 10.0 to 15.0.