The present invention relates to jacketed cable especially useful for plenum enclosures of buildings, the jacket of the cable comprising perfluoropolymer, such as tetrafluoroethylene/hexafluoropropylene copolymer, and inorganic char-forming agent, and preferably an additional ingredient, hydrocarbon polymer, the cable passing the NFPA-255 burn test.
1. A plenum cable comprising an extruded jacket comprising melt-fabricable perfluoropolymer and a char effective amount of at least 10 wt % inorganic char-forming agent to enable said cable to pass the NFPA-255 burn test, wherein said jacket is free of plasticizer and added antioxidant and said perfluoropolymer has a melt flow rate of at least 20 g/10 min.
2. The cable of claim 1 containing a plurality of twisted pairs of insulated wires within said jacket.
3. The cable of claim 1 containing insulated coaxial conductors.
4. The cable of claim 1 wherein said jacket contains hydrocarbon polymer and the amount of said hydrocarbon polymer is about 0.1 to 5 wt % based on the combined weight of said perfluoropolymer, said agent, and said hydrocarbon polymer.
5. The cable of claim 1 wherein said char-forming agent is metal oxide.
6. The cable of claim 1 wherein the amount of said char-forming agent is about 20 to 50 wt %.
7. The cable of claim 1 wherein said cable includes a core for data or voice transmission, said jacket covering said core.
8. The cable of claim 1 wherein said jacket exhibits an acid generation of no greater than 5% and an acidity characterized by a pH of at least 2.5.
9. The cable of claim 1 wherein said perfluoropolymer is tetrafluoroethylene/hexafluoropropylene copolymer.
10. A plenum cable comprising an extruded jacket comprising melt-fabricable perfluoropolymer and a char effective amount of at least 10 wt % inorganic char-forming agent, wherein said jacket is free of plasticizer and added antioxidant, wherein said jacket contains an inorganic phosphor in an effective amount to color said jacket when subjected to excitation radiation, said phosphor comprising said char-forming agent and an effective amount of an activator for said char-forming agent to produce the phosphor effect when subjected to said excitation radiation.
11. A plenum cable comprising an extruded jacket comprising meltfabricable perfluoropolymer and a char effective amount of at least 10 wt % inorganic char-forming agent, wherein said jacket is free of plasticizer and added antioxidant and wherein said agent is ZnO, Al2O3, or MgZnO2.
12. The cable of claim 11 wherein said cable is coaxial cable.
13. The cable of claim 11 containing a plurality of twisted pairs of insulated wires within said jacket.
14. A coaxial cable comprising a jacket comprising perfluoropolymer and a char effective amount of inorganic char-forming agent wherein said agent comprises a plurality of char-forming agents, at least one of which is ceramic microspheres wherein from about 5 to 20 wt % of said ceramic microspheres is present in said jacket and about 20 to 40 wt % of another of said char-forming agents is present in said jacket, the total wt % of said char-forming agents being about 10 to 60 wt % of the total weight of said perfluoropolymer and said char-forming agents.
15. A plenum cable comprising an extruded jacket comprising melt-fabricable perfluoropolymer and a char effective amount of at least 10 wt % inorganic char-forming agent, wherein said jacket is free of plasticizer and added antioxidant and wherein said char-forming agent is other than TiO2.